Expanding the Chemistry of Actinide Metallocene Bromides. Synthesis, Properties and Molecular Structures of the Tetravalent and Trivalent Uranium Bromide Complexes: (C5Me4R)2UBr2, (C5Me4R)2U(O-2,6-iPr2C6H3)(Br), and [K(THF)][(C5Me4R)2UBr2] (R = Me, Et)
Abstract
The organometallic uranium species (C5Me4R)2UBr2 (R = Me, Et) were obtained by treating their chloride analogues (C5Me4R)2UCl2 (R = Me, Et) with Me3SiBr. Treatment of (C5Me4R)2UCl2 and (C5Me4R)2UBr2 (R = Me, Et) with K(O-2,6-iPr2C6H3) afforded the halide aryloxide mixed-ligand complexes (C5Me4R)2U(O-2,6-iPr2C6H3)(X) (R = Me, Et; X = Cl, Br). Complexes (C5Me4R)2U(O-2,6-iPr2C6H3)(Br) (R = Me, Et) can also be synthesized by treating (C5Me4R)2U(O-2,6-iPr2C6H3)(Cl) (R = Me, Et) with Me3SiBr, respectively. Reduction of (C5Me4R)2UCl2 and (C5Me4R)2UBr2 (R = Me, Et) with KC8 led to isolation of uranium(III) “ate” species [K(THF)][(C5Me5)2UX2] (X = Cl, Br) and [K(THF)0.5][(C5Me4Et)2UX2] (X = Cl, Br), which can be converted to the neutral complexes (C5Me4R)2U[N(SiMe3)2] (R = Me, Et). Analyses by nuclear magnetic resonance spectroscopy, X-ray crystallography, and elemental analysis are also presented.
- Authors:
-
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Chemistry Division
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Materials Physics and Applications Division
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States). Materials Science and Technology Division
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE Laboratory Directed Research and Development (LDRD) Program; USDOE Office of Science (SC), Workforce Development for Teachers and Scientists (WDTS); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Heavy Element Chemistry Program; USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5). Fuel Cycle Research and Development Program
- OSTI Identifier:
- 1335598
- Report Number(s):
- LA-UR-15-27740
Journal ID: ISSN 2304-6740
- Grant/Contract Number:
- AC52-06NA25396; AC05-06OR23100
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganics
- Additional Journal Information:
- Journal Volume: 4; Journal Issue: 1; Journal ID: ISSN 2304-6740
- Publisher:
- MDPI
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; trivalent and tetravalent uranium; bromide; organometallic
Citation Formats
Lichtscheidl, Alejandro Gaston, Pagano, Justin K., Scott, Brian Lindley, Nelson, Andrew Thomas, and Kiplinger, Jaqueline Loetsch. Expanding the Chemistry of Actinide Metallocene Bromides. Synthesis, Properties and Molecular Structures of the Tetravalent and Trivalent Uranium Bromide Complexes: (C5Me4R)2UBr2, (C5Me4R)2U(O-2,6-iPr2C6H3)(Br), and [K(THF)][(C5Me4R)2UBr2] (R = Me, Et). United States: N. p., 2016.
Web. doi:10.3390/inorganics4010001.
Lichtscheidl, Alejandro Gaston, Pagano, Justin K., Scott, Brian Lindley, Nelson, Andrew Thomas, & Kiplinger, Jaqueline Loetsch. Expanding the Chemistry of Actinide Metallocene Bromides. Synthesis, Properties and Molecular Structures of the Tetravalent and Trivalent Uranium Bromide Complexes: (C5Me4R)2UBr2, (C5Me4R)2U(O-2,6-iPr2C6H3)(Br), and [K(THF)][(C5Me4R)2UBr2] (R = Me, Et). United States. https://doi.org/10.3390/inorganics4010001
Lichtscheidl, Alejandro Gaston, Pagano, Justin K., Scott, Brian Lindley, Nelson, Andrew Thomas, and Kiplinger, Jaqueline Loetsch. Wed .
"Expanding the Chemistry of Actinide Metallocene Bromides. Synthesis, Properties and Molecular Structures of the Tetravalent and Trivalent Uranium Bromide Complexes: (C5Me4R)2UBr2, (C5Me4R)2U(O-2,6-iPr2C6H3)(Br), and [K(THF)][(C5Me4R)2UBr2] (R = Me, Et)". United States. https://doi.org/10.3390/inorganics4010001. https://www.osti.gov/servlets/purl/1335598.
@article{osti_1335598,
title = {Expanding the Chemistry of Actinide Metallocene Bromides. Synthesis, Properties and Molecular Structures of the Tetravalent and Trivalent Uranium Bromide Complexes: (C5Me4R)2UBr2, (C5Me4R)2U(O-2,6-iPr2C6H3)(Br), and [K(THF)][(C5Me4R)2UBr2] (R = Me, Et)},
author = {Lichtscheidl, Alejandro Gaston and Pagano, Justin K. and Scott, Brian Lindley and Nelson, Andrew Thomas and Kiplinger, Jaqueline Loetsch},
abstractNote = {The organometallic uranium species (C5Me4R)2UBr2 (R = Me, Et) were obtained by treating their chloride analogues (C5Me4R)2UCl2 (R = Me, Et) with Me3SiBr. Treatment of (C5Me4R)2UCl2 and (C5Me4R)2UBr2 (R = Me, Et) with K(O-2,6-iPr2C6H3) afforded the halide aryloxide mixed-ligand complexes (C5Me4R)2U(O-2,6-iPr2C6H3)(X) (R = Me, Et; X = Cl, Br). Complexes (C5Me4R)2U(O-2,6-iPr2C6H3)(Br) (R = Me, Et) can also be synthesized by treating (C5Me4R)2U(O-2,6-iPr2C6H3)(Cl) (R = Me, Et) with Me3SiBr, respectively. Reduction of (C5Me4R)2UCl2 and (C5Me4R)2UBr2 (R = Me, Et) with KC8 led to isolation of uranium(III) “ate” species [K(THF)][(C5Me5)2UX2] (X = Cl, Br) and [K(THF)0.5][(C5Me4Et)2UX2] (X = Cl, Br), which can be converted to the neutral complexes (C5Me4R)2U[N(SiMe3)2] (R = Me, Et). Analyses by nuclear magnetic resonance spectroscopy, X-ray crystallography, and elemental analysis are also presented.},
doi = {10.3390/inorganics4010001},
journal = {Inorganics},
number = 1,
volume = 4,
place = {United States},
year = {Wed Jan 06 00:00:00 EST 2016},
month = {Wed Jan 06 00:00:00 EST 2016}
}
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Works referenced in this record:
Structural Diversity in Paddlewheel Dirhodium(II) Compounds through Ionic Interactions: Electronic and Redox Properties
journal, October 2013
- Amo-Ochoa, Pilar; Jiménez-Aparicio, Reyes; Perles, Josefina
- Crystal Growth & Design, Vol. 13, Issue 11
UI 4 (1,4-dioxane) 2 , [UCl 4 (1,4-dioxane)] 2 , and UI 3 (1,4-dioxane) 1.5 : Stable and Versatile Starting Materials for Low- and High-Valent Uranium Chemistry
journal, April 2011
- Monreal, Marisa J.; Thomson, Robert K.; Cantat, Thibault
- Organometallics, Vol. 30, Issue 7
Potassium N -bromo-4-chlorobenzenesulfonamidate monohydrate
journal, June 2011
- Gowda, B. Thimme; Foro, Sabine; Shakuntala, K.
- Acta Crystallographica Section E Structure Reports Online, Vol. 67, Issue 7
Unusual Luminescence Spectra and Decay Dynamics in Crystalline Supramolecular [(A18C6) 4 MBr 4 ][TlBr 4 ] 2 (A = Rb, K; M = 3d Element) Complexes
journal, November 1997
- Fender, Nicolette S.; Fronczek, Frank R.; John, Vijay
- Inorganic Chemistry, Vol. 36, Issue 24
Synthesis and Structure of the Bis(tetramethylcyclopentadienyl)uranium Metallocenes (C 5 Me 4 H) 2 UMe 2 , (C 5 Me 4 H) 2 UMeCl, [(C 5 Me 4 H) 2 U][(μ-η 6 :η 1 -Ph)(μ-η 1 :η 1 -Ph)BPh 2 ], and [(C 5 Me 4 )SiMe 2 (CH 2 CHCH 2 )] 2 UI(THF)
journal, September 2005
- Evans, William J.; Kozimor, Stosh A.; Hillman, Wes R.
- Organometallics, Vol. 24, Issue 19
Crystal structure and spectroscopic properties of (NH4[UBr2(CH3CN)2(H2O)5]Br2
journal, July 1993
- Zych, E.; Starynowicz, P.; Lis, T.
- Polyhedron, Vol. 12, Issue 13
Synthesis and properties of a new class of highly reactive trivalent actinide organometallic compounds. Derivatives of bis(pentamethylcyclopentadienyl)uranium(III)
journal, January 1982
- Fagan, Paul J.; Manriquez, Juan M.; Marks, Tobin J.
- Organometallics, Vol. 1, Issue 1
Coordination Trends in Alkali Metal Crown Ether Uranyl Halide Complexes: The Series [A(Crown)] 2 [UO 2 X 4 ] Where A = Li, Na, K and X = Cl, Br
journal, July 2001
- Danis, Janet A.; Lin, Mavis R.; Scott, Brian L.
- Inorganic Chemistry, Vol. 40, Issue 14
The crystal structures of hexahalouranates. I. Bis(triphenylethylphosphonium) hexachlorouranate(IV) and bis(triphenylethylphosphonium) hexabromouranate(IV)
journal, April 1978
- Caira, M. R.; de Wet, J. F.; du Preez, J. G. H.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 34, Issue 4
Isolation of Stable Organodysprosium(II) Complexes by Chemical Reduction of Dysprosium(III) Precursors
journal, February 2007
- Jaroschik, Florian; Nief, François; Le Goff, Xavier-Frédéric
- Organometallics, Vol. 26, Issue 5
Bis[η5-bis(trimethylsilyl)cyclopentadienyl]bromouranium(III) bis(tert-butyl isocyanide)
journal, August 1989
- Beshouri, S. M.; Zalkin, A.
- Acta Crystallographica Section C Crystal Structure Communications, Vol. 45, Issue 8
C−H and C−S Bond Cleavage in Uranium(III) Thiolato Complexes
journal, August 2001
- Arliguie, Thérèse; Lescop, Christophe; Ventelon, Lionel
- Organometallics, Vol. 20, Issue 17
NMR Chemical Shifts of Trace Impurities: Common Laboratory Solvents, Organics, and Gases in Deuterated Solvents Relevant to the Organometallic Chemist
journal, May 2010
- Fulmer, Gregory R.; Miller, Alexander J. M.; Sherden, Nathaniel H.
- Organometallics, Vol. 29, Issue 9
Synthesis, Characterization, and Organometallic Derivatives of Diamidosilyl Ether Thorium(IV) and Uranium(IV) Halide Complexes
journal, April 2004
- Jantunen, Kimberly C.; Batchelor, Raymond J.; Leznoff, Daniel B.
- Organometallics, Vol. 23, Issue 9
Azidocryptands–synthesis, structure, and complexation properties
journal, January 2005
- Tönshoff, Christina; Merz, Klaus; Bucher, Götz
- Org. Biomol. Chem., Vol. 3, Issue 2
Multiple Syntheses of (C 5 Me 5 ) 3 U
journal, March 2002
- Evans, William J.; Nyce, Gregory W.; Forrestal, Kevin J.
- Organometallics, Vol. 21, Issue 6
Synthesis, spectroscopic properties and crystal structures of [ML 2 Cl 2 ][M = Th or U; L =η-C 5 H 3 (SiMe 3 ) 2 -1,3] and [UL 2 X 2 ](X = Br, I or BH 4 )
journal, January 1995
- Blake, Paul C.; Lappert, Michael F.; Taylor, Richard G.
- J. Chem. Soc., Dalton Trans., Issue 20
η2-Sulfenamido complexes of uranium †
journal, January 2000
- Danopoulos, Andreas A.; Hankin, Danielle M.; Cafferkey, Sean M.
- Journal of the Chemical Society, Dalton Transactions, Issue 10
Synthesis, structure, spectroscopy and redox energetics of a series of uranium(IV) mixed-ligand metallocene complexes
journal, June 2010
- Thomson, Robert K.; Scott, Brian L.; Morris, David E.
- Comptes Rendus Chimie, Vol. 13, Issue 6-7
Bis(pentamethylcyclopentadienyl) U(III) oxide and U(IV) oxide carbene complexes
journal, November 2004
- Evans, William J.; Kozimor, Stosh A.; Ziller, Joseph W.
- Polyhedron, Vol. 23, Issue 17
Uncovering alternate reaction pathways to access uranium(IV) mixed-ligand aryloxide–chloride and alkoxide–chloride metallocene complexes: Synthesis and molecular structures of (C5Me5)2U(O-2,6-iPr2C6H3)(Cl) and (C5Me5)2U(O–tBu)(Cl)
journal, April 2011
- Thomson, Robert K.; Graves, Christopher R.; Scott, Brian L.
- Inorganica Chimica Acta, Vol. 369, Issue 1
Lanthanide(III)/Actinide(III) Differentiation in the Cerium and Uranium Complexes [M(C5Me5)2(L)]0,+ (L=2,2′-Bipyridine, 2,2′:6′,2′′-Terpyridine): Structural, Magnetic, and Reactivity Studies
journal, November 2005
- Mehdoui, Thouraya; Berthet, Jean-Claude; Thuéry, Pierre
- Chemistry - A European Journal, Vol. 11, Issue 23
Structure of tris(1–3-η-indenyl)uranium bromide
journal, February 1987
- Spirlet, M. R.; Rebizant, J.; Goffart, J.
- Acta Crystallographica Section C Crystal Structure Communications, Vol. 43, Issue 2
The remarkable efficiency of N-heterocyclic carbenes in lanthanide(iii)/actinide(iii) differentiation
journal, January 2005
- Mehdoui, Thouraya; Berthet, Jean-Claude; Thuéry, Pierre
- Chemical Communications, Issue 22
Metals Intercalated in Graphite. I. Reduction and Oxidation
journal, September 1972
- Lalancette, J. -M.; Rollin, G.; Dumas, P.
- Canadian Journal of Chemistry, Vol. 50, Issue 18
On the chemistry of gallium
journal, April 2001
- Linti, Gerald; Li, Guangming; Pritzkow, Heinz
- Journal of Organometallic Chemistry, Vol. 626, Issue 1-2
Structure of tris(cyclopentadienyl)uranium bromide
journal, May 1989
- Spirlet, M. R.; Rebizant, J.; Apostolidis, C.
- Acta Crystallographica Section C Crystal Structure Communications, Vol. 45, Issue 5
Analysis of Uranium Azide and Nitride Complexes by Atmospheric Pressure Chemical Ionization Mass Spectrometry
journal, September 2007
- Evans, William J.; Miller, Kevin A.; Ziller, Joseph W.
- Inorganic Chemistry, Vol. 46, Issue 19
A Mild Protocol To Generate Uranium(IV) Mixed-Ligand Metallocene Complexes using Copper(I) Iodide
journal, October 2008
- Graves, Christopher R.; Schelter, Eric J.; Cantat, Thibault
- Organometallics, Vol. 27, Issue 20
Bis(cyclopentadienyl) actinide(IV) compounds. I. The structure of dichlorobis(pentamethyl-η5-cyclopentadienyl)uranium(IV) and dichlorobis(pentamethyl-η5-cyclopentadienyl)thorium(IV)
journal, December 1992
- Spirlet, M. R.; Rebizant, J.; Apostolidis, C.
- Acta Crystallographica Section C Crystal Structure Communications, Vol. 48, Issue 12
Methyl Displacements from Cyclopentadienyl Ring Planes in Sterically Crowded (C 5 Me 5 ) 3 M Complexes
journal, October 2005
- Evans, William J.; Kozimor, Stosh A.; Ziller, Joseph W.
- Inorganic Chemistry, Vol. 44, Issue 22
The first cationic indenyl-f-metal complexes with pentagonal bipyramidal geometry. Crystal structures of [C9H7UBr2(CH3CN)4]+2 [UBr6]2− and [{C9H7UBr(CH3CN)4}2O]2+ [UBr62−
journal, June 1986
- Beeckman, W.; Goffart, J.; Rebizant, J.
- Journal of Organometallic Chemistry, Vol. 307, Issue 1
Structure and bonding in octahedral uranium( IV ) complexes of the type UX 4 ·2L (X = halogen, L = unidentate, neutral oxygen donor). Part 1. The crystal structures of tetrabromobis(NN′-dimethyl-NN′-diphenylurea)uranium( IV ) and α- and β-tetrachlorobis(NN′-dimethyl-NN′-diphenylurea)uranium( IV )
journal, January 1986
- de Wet, J. Ferdinand; Caira, Mino R.
- J. Chem. Soc., Dalton Trans., Issue 10
Stabilisation of tetrabromo- and tetrachlorosemiquinone (bromanil and chloranil) anion radicals in crystals
journal, January 2011
- Molčanov, Krešimir; Kojić-Prodić, Biserka; Babić, Darko
- CrystEngComm, Vol. 13, Issue 16
Some oxygen-donor complexes of cyclopentadienyluranium(IV) halides
journal, January 1978
- Bagnall, Kenneth W.; Edwards, John; Tempest, Andrew C.
- Journal of the Chemical Society, Dalton Transactions, Issue 4
Mixed Valency in a Uranium Multimetallic Complex
journal, April 2008
- Schelter, Eric J.; Wu, Ruilian; Scott, Brian L.
- Angewandte Chemie International Edition, Vol. 47, Issue 16
On the indenyl compounds of actinide elements Part I: Triindenylthorium bromide and triindenyluranium bromide
journal, September 1975
- Goffart, J.; Fuger, J.; Gilbert, B.
- Inorganic and Nuclear Chemistry Letters, Vol. 11, Issue 9
Noble Reactions for the Actinides: Safe Gold-Based Access to Organouranium and Azido Complexes
journal, April 2009
- Thomson, Robert K.; Graves, Christopher R.; Scott, Brian L.
- European Journal of Inorganic Chemistry, Vol. 2009, Issue 11
Organometallic uranium(iv) fluoride complexes: preparation using protonolysis chemistry and reactivity with trimethylsilyl reagents
journal, January 2010
- Thomson, Robert K.; Graves, Christopher R.; Scott, Brian L.
- Dalton Transactions, Vol. 39, Issue 29
Transport of Alkali Halides through a Liquid Organic Membrane Containing a Ditopic Salt-Binding Receptor
journal, September 2004
- Mahoney, Joseph M.; Nawaratna, Gayathri U.; Beatty, Alicia M.
- Inorganic Chemistry, Vol. 43, Issue 19
Straightforward and efficient oxidation of tris(aryloxide) and tris(amide) uranium(III) complexes using copper(I) halide reagents
journal, November 2011
- Thomson, Robert K.; Graves, Christopher R.; Scott, Brian L.
- Inorganic Chemistry Communications, Vol. 14, Issue 11
Two anionic [CuI6X7]nn− (X=Br and I) chain-based organic–inorganic hybrid solids with N-substituted benzotriazole ligands
journal, May 2010
- Gao, Xia; Zhai, Quan-Guo; Li, Shu-Ni
- Journal of Solid State Chemistry, Vol. 183, Issue 5
Structural Evaluation and Solution Integrity of Alkali Metal Salt Complexes of the Manganese 12-Metallacrown-4 (12-MC-4) Structural Type
journal, January 1996
- Gibney, Brian R.; Wang, Hsin; Kampf, Jeff W.
- Inorganic Chemistry, Vol. 35, Issue 21
Uranium azide photolysis results in C–H bond activation and provides evidence for a terminal uranium nitride
journal, July 2010
- Thomson, Robert K.; Cantat, Thibault; Scott, Brian L.
- Nature Chemistry, Vol. 2, Issue 9
Reactions of potassium-graphite
journal, March 1978
- Bergbreiter, David E.; Killough, James M.
- Journal of the American Chemical Society, Vol. 100, Issue 7
The distinct affinity of cyclopentadienyl ligands towards trivalent uranium over lanthanide ions. Evidence for cooperative ligation and back-bonding in the actinide complexes
journal, January 2005
- Mehdoui, Thouraya; Berthet, Jean-Claude; Thuéry, Pierre
- Dalton Trans., Issue 7
Some aspects of the coordination and organometallic chemistry of thorium and uranium (MIII, MIV, UV) in +3 and +4 oxidation states
journal, December 1987
- Blake, Paul C.; Lappert, Michael F.; Taylor, Richard G.
- Inorganica Chimica Acta, Vol. 139, Issue 1-2
An Unprecedented Type of Linear Metallocene with an f-Element
journal, February 2006
- Maynadié,, Jérôme; Berthet, Jean-Claude; Thuéry, Pierre
- Journal of the American Chemical Society, Vol. 128, Issue 4
Controlled Chemical Reduction of Uranyl Salts into UX4(MeCN)4 (X = Cl, Br, I) with Me3SiX Reagents
journal, September 2007
- Berthet, Jean-Claude; Siffredi, Gérald; Thuéry, Pierre
- European Journal of Inorganic Chemistry, Vol. 2007, Issue 25
Mesityltrifluorogallate. Die Kristallstrukturen von Cs[MesGaF3] und K[MesInBr3]
journal, November 1993
- Neum�ller, Bernhard; Gahlmann, Frank
- Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 619, Issue 11
The Chemistry of Uranium. Part 34. Structural and Thermal Properties of UX4L2 Complexes (X Cl and Br; L = N,N,N′,N′-Tetramethylurea)
journal, December 1986
- Du preez, Jan G. H.; Zeelie, Ben; Casellato, U.
- Inorganica Chimica Acta, Vol. 122, Issue 1
Structure, Reactivity, and Density Functional Theory Analysis of the Six-Electron Reductant, [(C 5 Me 5 ) 2 U] 2 (μ - η 6 :η 6 -C 6 H 6 ), Synthesized via a New Mode of (C 5 Me 5 ) 3 M Reactivity
journal, November 2004
- Evans, William J.; Kozimor, Stosh A.; Ziller, Joseph W.
- Journal of the American Chemical Society, Vol. 126, Issue 44
Reactivity of Methyl Groups in Actinide Metallocene Amidinate and Triazenido Complexes with Silver and Copper Salts
journal, January 2010
- Evans, William J.; Walensky, Justin R.; Ziller, Joseph W.
- Organometallics, Vol. 29, Issue 1
Reactivity of UH3 with mild oxidants
journal, January 2008
- Schnaars, David D.; Wu, Guang; Hayton, Trevor W.
- Dalton Transactions, Issue 44
The chemistry of uranium. Part 41. Complexes of uranium tetrahalide, with emphasis on iodide, and triphenylphosphine oxide, tris(dimethylamino)phosphine oxide or tris(pyrrolidinyl)phosphine oxide. Crystal structure of tetrabromobis[tris(pyrrolidinyl)phosphine oxide]uranium(IV)
journal, November 1991
- du Preez, Jan G. H.; Rohwer, Hans E.; van Brecht, Bernardus J. A. M.
- Inorganica Chimica Acta, Vol. 189, Issue 1
Triphenylphosphine oxide complexes of actinide tetrahalides. Crystal and molecular structure of trans-tetrabromobis(triphenylphosphine oxide)uranium(IV)
journal, January 1983
- Bombieri, Gabriella; Benetollo, Franco; Bagnall, Kenneth W.
- Journal of the Chemical Society, Dalton Transactions, Issue 2
Electrochemical Properties of Bis(dicarbollide)uranium Dibromide
journal, July 1998
- de Rege, Francis M.; Smith, Wayne H.; Scott, Brian L.
- Inorganic Chemistry, Vol. 37, Issue 15
Synthesis and crystal structure of [U(η-C5Me5)2(OC4H8)2][BPh4], the first cationic cyclopentadienyl compound of uranium(III)
journal, April 1997
- Boisson, Christophe; Berthet, Jean Claude; Ephritikhine, Michel
- Journal of Organometallic Chemistry, Vol. 533, Issue 1-2
(C 5 Me 5 ) 2 UCl·tetrahydrofuran. Oxidative-addition and related reactions
journal, January 1981
- Finke, Richard G.; Hirose, Yoshiki; Gaughan, Glen
- J. Chem. Soc., Chem. Commun., Issue 5
Uranium (IV) substituted poly(pyrazol-1-yl) borate complexes
journal, July 1976
- Bagnall, K. W.; Edwards, J.
- Journal of the Less Common Metals, Vol. 48, Issue 1
How Much Steric Crowding Is Possible in Tris(η5-pentamethylcyclopentadienyl) Complexes? Synthesis and Structure of (C 5 Me 5 ) 3 UCl and (C 5 Me 5 ) 3 UF 1
journal, December 2000
- Evans, William J.; Nyce, Gregory W.; Johnston, Matthew A.
- Journal of the American Chemical Society, Vol. 122, Issue 48
Structure and bonding in octahedral uranium( IV ) complexes of the type UX 4 ·2L (X = halogen, L = unidentate, neutral oxygen donor). Part 2. The crystal structures of tetrachlorobis[tris(pyrrolidinyl)phosphine oxide]-, tetrachlorobis(di-isobutyl sulphoxide)-, and tetrabromobis(triphenylarsine oxide)-uranium( IV )
journal, January 1986
- de Wet, J. Ferdinand; Caira, Mino R.
- J. Chem. Soc., Dalton Trans., Issue 10
A Chiral-Anion Generator: Application to Catalytic Desilylative Kinetic Resolution of Silyl-Protected Secondary Alcohols
journal, October 2010
- Yan, Hailong; Jang, Hyeong Bin; Lee, Ji-Woong
- Angewandte Chemie International Edition, Vol. 49, Issue 47
Reaction Chemistry of the U 3+ Metallocene Amidinate (C 5 Me 5 ) 2 [ i PrNC(Me)N i Pr]U Including the Isolation of a Uranium Complex of a Monodentate Acetate
journal, February 2010
- Evans, William J.; Walensky, Justin R.; Ziller, Joseph W.
- Inorganic Chemistry, Vol. 49, Issue 4
Anionic tricyclopentadienyluranium(III) complexes. Crystal structure of [Cp3UClUCp3][Na(18-crown-6)(THF)2] (Cp = η-C5H5, THF = tetrahydrofuran)
journal, December 1989
- LeMaréchal, Jean François; Villiers, Claude; Charpin, Pierrette
- Journal of Organometallic Chemistry, Vol. 379, Issue 3
Solution Structure and Behavior of Dimeric Uranium(III) Metallocene Halides
journal, March 1999
- Lukens, Wayne W.; Beshouri, Sharon M.; Stuart, Anthony L.
- Organometallics, Vol. 18, Issue 7
Syntheses, structures and magnetic properties of two heterometallic carbonates: K2Li[Cu(H2O)2Ru2(CO3)4X2]·5H2O (X = Cl, Br)
journal, January 2013
- Jia, Yan-Yan; Liu, Bin; Liu, Xue-Mei
- CrystEngComm, Vol. 15, Issue 39
The chemistry of uranium. Part 42. Cationic uranium(IV) complexes UX2L4Y2(X = Cl, Br or I; Y = ClO4 or BPh4; L = bulky strong neutral O-donor ligand) and [U(ClO4)4(OAsPh3)4]: crystal structures of [UX2L4][BPh4]2(L = tris(pyrrolidine-1-yl)phosphine oxide, X = Br or I)
journal, January 1991
- du Preez, Jan G. H.; Gouws, Leon; Rohwer, Hans
- Journal of the Chemical Society, Dalton Transactions, Issue 10
On the indenyl compounds of actinide elements
journal, January 1980
- Goffart, J.; Piret-Meunier, J.; Duyckaerts, G.
- Inorganic and Nuclear Chemistry Letters, Vol. 16, Issue 4
From Bent to Linear Uranium Metallocenes: Influence of Counterion, Solvent, and Metal Ion Oxidation State
journal, November 2006
- Maynadié,, Jérôme; Berthet, Jean-Claude; Thuéry, Pierre
- Organometallics, Vol. 25, Issue 23
Structure and stereochemistry in 'f-block' complexes of high coordination number. VI. Crystallographic characterizations of Bis[(1 ,1-dimethyl-3-oxobutyl)triphenyl-phosphonium] hexabromouranate(IV) and Tetrabromobis[ethane-1,2-diylbis(diphenylarsine) oxide]uranium(IV)
journal, January 1983
- Kepert, Dl; Patrick, Jm; White, Ah
- Australian Journal of Chemistry, Vol. 36, Issue 3
Organometallic Uranium(V)−Imido Halide Complexes: From Synthesis to Electronic Structure and Bonding
journal, April 2008
- Graves, Christopher R.; Yang, Ping; Kozimor, Stosh A.
- Journal of the American Chemical Society, Vol. 130, Issue 15
Preparation and Reactions of Base-Free Bis(1,2,4-tri- tert -butylcyclopentadienyl)uranium Oxide, Cp‘ 2 UO
journal, August 2005
- Zi, Guofu; Jia, Li; Werkema, Evan L.
- Organometallics, Vol. 24, Issue 17
Synthesis and properties of bis(pentamethylcyclopentadienyl) actinide hydrocarbyls and hydrides. A new class of highly reactive f-element organometallic compounds
journal, November 1981
- Fagan, Paul J.; Manriquez, Juan M.; Maatta, Eric A.
- Journal of the American Chemical Society, Vol. 103, Issue 22
A complete series of uranocene( III ) halides [{UCp″ 2 X} n ][X = F, Cl, Br, or I; Cp″=η-C 5 H 3 (SiMe 3 ) 2 ]; single-crystal X-ray structure determinations of the chloride and bromide (n= 2 for X – =µ-Cl – or µ-Br – )
journal, January 1986
- Blake, Paul C.; Lappert, Michael F.; Taylor, Richard G.
- J. Chem. Soc., Chem. Commun., Issue 17
Preparation, Solution Behavior, and Solid-State Structures of (1,3-R 2 C 5 H 3 ) 2 UX 2 , Where R Is CMe 3 or SiMe 3 and X Is a One-Electron Ligand
journal, March 1999
- Lukens, Wayne W.; Beshouri, Sharon M.; Blosch, Laura L.
- Organometallics, Vol. 18, Issue 7
New actinide hydrogen transition metal compounds. Synthesis of [K(C 12 H 24 O 6 )][(η-C 5 Me 5 ) 2 (Cl)UH 6 Re(PPh 3 ) 2 ] and the crystal structure of its benzene solvate
journal, January 1994
- Cendrowski-Guillaume, Sophie M.; Lance, Monique; Nierlich, Martine
- J. Chem. Soc., Chem. Commun., Issue 14
Reactivity of (C 5 Me 5 ) 2 UMe 2 and (C 5 Me 5 ) 2 UMeCl toward Group 13 Alkyls
journal, February 2009
- Dietrich, H. Martin; Ziller, Joseph W.; Anwander, Reiner
- Organometallics, Vol. 28, Issue 4
A white phosphorescent coordination polymer with Cu 2 I 2 alternating units linked by benzo-18-crown-6
journal, January 2014
- Wu, Fengshou; Tong, Hongbo; Li, Zaoying
- Dalton Trans., Vol. 43, Issue 33
Pentamethylcyclopentadienyl organoactinides. Trivalent uranium organometallic chemistry and the unusual structure of bis(pentamethylcyclopentadienyl)uranium monochloride
journal, August 1979
- Manriquez, Juan M.; Fagan, Paul J.; Marks, Tobin J.
- Journal of the American Chemical Society, Vol. 101, Issue 17
Lanthanide(III)/Actinide(III) Differentiation in Mixed Cyclopentadienyl/Dithiolene Compounds from X-ray Diffraction and Density Functional Theory Analysis
journal, October 2005
- Roger, Mathieu; Belkhiri, Lotfi; Thuéry, Pierre
- Organometallics, Vol. 24, Issue 21
The chemistry of uranium. Part 23. Isomorphous tetrachlorobis(hexamethylphosphoramide)uranium(IV) and tetrabromobis(hexamethylphosphoramide)uranium(IV)
journal, January 1978
- du Preez, J. G. H.; Gellatly, B. J.; Jackson, G.
- Inorganica Chimica Acta, Vol. 27
New Dicarbollide Complexes of Uranium
journal, January 1996
- Rabinovich, Daniel; Haswell, Chereé M.; Scott, Brian L.
- Inorganic Chemistry, Vol. 35, Issue 6
1,4-Dicyanobenzene as a Scaffold for the Preparation of Bimetallic Actinide Complexes Exhibiting Metal-Metal Communication
journal, September 2008
- Schelter, Eric J.; Veauthier, Jacqueline M.; Graves, Christopher R.
- Chemistry - A European Journal, Vol. 14, Issue 26
Mixed Valency in a Uranium Multimetallic Complex
journal, April 2008
- Schelter, Eric J.; Wu, Ruilian; Scott, Brian L.
- Angewandte Chemie, Vol. 120, Issue 16
A Chiral-Anion Generator: Application to Catalytic Desilylative Kinetic Resolution of Silyl-Protected Secondary Alcohols
journal, October 2010
- Yan, Hailong; Jang, Hyeong Bin; Lee, Ji-Woong
- Angewandte Chemie, Vol. 122, Issue 47
Controlled Chemical Reduction of Uranyl Salts into UX4(MeCN)4 (X: Cl, Br, I) with Me3SiX Reagents.
journal, November 2007
- Berthet, Jean-Claude; Siffredi, Gerald; Thuery, Pierre
- ChemInform, Vol. 38, Issue 46
Works referencing / citing this record:
Synthesis of Actinide Fluoride Complexes Using Trimethyltin Fluoride as a Mild and Selective Fluorinating Reagent: Synthesis of Actinide Fluoride Complexes Using Trimethyltin Fluoride as a Mild and Selective Fluorinating Reagent
journal, December 2017
- Kagan, Benjamin D.; Lichtscheidl, Alejandro G.; Erickson, Karla A.
- European Journal of Inorganic Chemistry, Vol. 2018, Issue 11
Synthesis of Actinide Fluoride Complexes Using Trimethyltin Fluoride as a Mild and Selective Fluorinating Reagent
journal, February 2018
- Kagan, Benjamin D.; Lichtscheidl, Alejandro G.; Erickson, Karla A.
- European Journal of Inorganic Chemistry, Vol. 2018, Issue 11