A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction
Abstract
With the advent of efficient high-bandgap metal-halide perovskite photovoltaics, an opportunity exists to make perovskite/silicon tandem solar cells. We fabricate a monolithic tandem by developing a silicon-based interband tunnel junction that facilitates majority-carrier charge recombination between the perovskite and silicon sub-cells. We demonstrate a 1 cm2 2-terminal monolithic perovskite/silicon multijunction solar cell with a VOC as high as 1.65 V. As a result, we achieve a stable 13.7% power conversion efficiency with the perovskite as the current-limiting sub-cell, and identify key challenges for this device architecture to reach efficiencies over 25%.
- Authors:
-
[1];
[2];
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Stanford Univ., Stanford, CA (United States)
- Publication Date:
- Research Org.:
- Stanford Univ., CA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
- OSTI Identifier:
- 1237897
- Alternate Identifier(s):
- OSTI ID: 1226722
- Grant/Contract Number:
- EE0006707; EE0004946
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Applied Physics Letters
- Additional Journal Information:
- Journal Volume: 106; Journal Issue: 12; Journal ID: ISSN 0003-6951
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 14 SOLAR ENERGY; 36 MATERIALS SCIENCE; dielectric oxides; tunnel junctions; doping; heterojunctions; multijunction solar cells
Citation Formats
Mailoa, Jonathan P., Bailie, Colin D., Johlin, Eric C., Hoke, Eric T., Akey, Austin J., Nguyen, William H., McGehee, Michael D., and Buonassisi, Tonio. A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction. United States: N. p., 2015.
Web. doi:10.1063/1.4914179.
Mailoa, Jonathan P., Bailie, Colin D., Johlin, Eric C., Hoke, Eric T., Akey, Austin J., Nguyen, William H., McGehee, Michael D., & Buonassisi, Tonio. A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction. United States. https://doi.org/10.1063/1.4914179
Mailoa, Jonathan P., Bailie, Colin D., Johlin, Eric C., Hoke, Eric T., Akey, Austin J., Nguyen, William H., McGehee, Michael D., and Buonassisi, Tonio. Tue .
"A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction". United States. https://doi.org/10.1063/1.4914179. https://www.osti.gov/servlets/purl/1237897.
@article{osti_1237897,
title = {A 2-terminal perovskite/silicon multijunction solar cell enabled by a silicon tunnel junction},
author = {Mailoa, Jonathan P. and Bailie, Colin D. and Johlin, Eric C. and Hoke, Eric T. and Akey, Austin J. and Nguyen, William H. and McGehee, Michael D. and Buonassisi, Tonio},
abstractNote = {With the advent of efficient high-bandgap metal-halide perovskite photovoltaics, an opportunity exists to make perovskite/silicon tandem solar cells. We fabricate a monolithic tandem by developing a silicon-based interband tunnel junction that facilitates majority-carrier charge recombination between the perovskite and silicon sub-cells. We demonstrate a 1 cm2 2-terminal monolithic perovskite/silicon multijunction solar cell with a VOC as high as 1.65 V. As a result, we achieve a stable 13.7% power conversion efficiency with the perovskite as the current-limiting sub-cell, and identify key challenges for this device architecture to reach efficiencies over 25%.},
doi = {10.1063/1.4914179},
journal = {Applied Physics Letters},
number = 12,
volume = 106,
place = {United States},
year = {Tue Mar 24 00:00:00 EDT 2015},
month = {Tue Mar 24 00:00:00 EDT 2015}
}
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