Quasi one-dimensional band dispersion and surface metallization in long-range ordered polymeric wires
Abstract
We study the electronic structure of an ordered array of poly(para-phenylene) chains produced by surface-catalyzed dehalogenative polymerization of 1,4-dibromobenzene on copper (110). The quantization of unoccupied molecular states is measured as a function of oligomer length by scanning tunnelling spectroscopy, with Fermi level crossings observed for chains longer than ten phenyl rings. Angle-resolved photoelectron spectroscopy reveals a quasi-one-dimensional valence band as well as a direct gap of 1.15 eV, as the conduction band is partially filled through adsorption on the surface. Tight-binding modelling and ab initio density functional theory calculations lead to a full description of the organic band-structure, including the k-dispersion, the gap size and electron charge transfer mechanisms, highlighting a strong substrate-molecule interaction that drives the system into a metallic behaviour. In summary, we have fully characterized the band structure of a carbon-based conducting wire. This model system may be considered as a fingerprint of -conjugation of surface organic frameworks.
- Authors:
-
- Univ. de Lorraine/CNRS, Nancy (France)
- Institut National de la Recherche Scientifique (INRS), Varennes, QC (Canada); Institut de Recherches sur la Catalyse et l'Environnement de Lyon, Villeurbanne (France)
- Institut National de la Recherche Scientifique (INRS), Varennes, QC (Canada)
- Institut National de la Recherche Scientifique (INRS), Varennes, QC (Canada); Queensland Univ. of Technology, Queensland (Australia)
- Institut National de la Recherche Scientifique (INRS), Varennes, QC (Canada); Univ. of Electronic Science and Technology of China, Chengdu (China)
- Instituto di Struttura della Materia, Roma (Italy)
- L'Orme des Merisiers, Gif sur Yvette (France)
- Rensselaer Polytechnic Inst., Troy, NY (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Rensselaer Polytechnic Inst., Troy, NY (United States)
- McGill Univ., Montreal QC (Canada)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1237642
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Nature Communications
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 26; Journal ID: ISSN 2041-1723
- Publisher:
- Nature Publishing Group
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 36 MATERIALS SCIENCE; physical sciences; material science; condensed matter
Citation Formats
Vasseur, Guillaume, Fagot-Revurat, Yannick, Sicot, Muriel, Kierren, Bertrand, Moreau, Luc, Malterre, Daniel, Cardenas, Luis, Galeotti, Gianluca, Lipton-Duffin, Josh, Rosei, Frederico, Giovannantonio, Marco Di, Giorgio, Contini, Fèvre, Patrick Le, Bertran, François, Liang, Liangbo, Meunier, Vincent, and Perepichka, Dmitrii F. Quasi one-dimensional band dispersion and surface metallization in long-range ordered polymeric wires. United States: N. p., 2016.
Web. doi:10.1038/ncomms10235.
Vasseur, Guillaume, Fagot-Revurat, Yannick, Sicot, Muriel, Kierren, Bertrand, Moreau, Luc, Malterre, Daniel, Cardenas, Luis, Galeotti, Gianluca, Lipton-Duffin, Josh, Rosei, Frederico, Giovannantonio, Marco Di, Giorgio, Contini, Fèvre, Patrick Le, Bertran, François, Liang, Liangbo, Meunier, Vincent, & Perepichka, Dmitrii F. Quasi one-dimensional band dispersion and surface metallization in long-range ordered polymeric wires. United States. https://doi.org/10.1038/ncomms10235
Vasseur, Guillaume, Fagot-Revurat, Yannick, Sicot, Muriel, Kierren, Bertrand, Moreau, Luc, Malterre, Daniel, Cardenas, Luis, Galeotti, Gianluca, Lipton-Duffin, Josh, Rosei, Frederico, Giovannantonio, Marco Di, Giorgio, Contini, Fèvre, Patrick Le, Bertran, François, Liang, Liangbo, Meunier, Vincent, and Perepichka, Dmitrii F. Mon .
"Quasi one-dimensional band dispersion and surface metallization in long-range ordered polymeric wires". United States. https://doi.org/10.1038/ncomms10235. https://www.osti.gov/servlets/purl/1237642.
@article{osti_1237642,
title = {Quasi one-dimensional band dispersion and surface metallization in long-range ordered polymeric wires},
author = {Vasseur, Guillaume and Fagot-Revurat, Yannick and Sicot, Muriel and Kierren, Bertrand and Moreau, Luc and Malterre, Daniel and Cardenas, Luis and Galeotti, Gianluca and Lipton-Duffin, Josh and Rosei, Frederico and Giovannantonio, Marco Di and Giorgio, Contini and Fèvre, Patrick Le and Bertran, François and Liang, Liangbo and Meunier, Vincent and Perepichka, Dmitrii F.},
abstractNote = {We study the electronic structure of an ordered array of poly(para-phenylene) chains produced by surface-catalyzed dehalogenative polymerization of 1,4-dibromobenzene on copper (110). The quantization of unoccupied molecular states is measured as a function of oligomer length by scanning tunnelling spectroscopy, with Fermi level crossings observed for chains longer than ten phenyl rings. Angle-resolved photoelectron spectroscopy reveals a quasi-one-dimensional valence band as well as a direct gap of 1.15 eV, as the conduction band is partially filled through adsorption on the surface. Tight-binding modelling and ab initio density functional theory calculations lead to a full description of the organic band-structure, including the k-dispersion, the gap size and electron charge transfer mechanisms, highlighting a strong substrate-molecule interaction that drives the system into a metallic behaviour. In summary, we have fully characterized the band structure of a carbon-based conducting wire. This model system may be considered as a fingerprint of -conjugation of surface organic frameworks.},
doi = {10.1038/ncomms10235},
journal = {Nature Communications},
number = 26,
volume = 7,
place = {United States},
year = {Mon Jan 04 00:00:00 EST 2016},
month = {Mon Jan 04 00:00:00 EST 2016}
}
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Works referenced in this record:
Mechanisms of the Ullmann coupling reaction in adsorbed monolayers
journal, August 1993
- Xi, Ming; Bent, Brian E.
- Journal of the American Chemical Society, Vol. 115, Issue 16
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Development and character of gap states on alkali doping of molecular films
journal, February 2014
- Reinisch, E. M.; Ules, T.; Puschnig, P.
- New Journal of Physics, Vol. 16, Issue 2
Mechanisms of Halogen-Based Covalent Self-Assembly on Metal Surfaces
journal, April 2013
- Björk, Jonas; Hanke, Felix; Stafström, Sven
- Journal of the American Chemical Society, Vol. 135, Issue 15
Molecules–Oligomers–Nanowires–Graphene Nanoribbons: A Bottom-Up Stepwise On-Surface Covalent Synthesis Preserving Long-Range Order
journal, January 2015
- Basagni, Andrea; Sedona, Francesco; Pignedoli, Carlo A.
- Journal of the American Chemical Society, Vol. 137, Issue 5
Covalent networks through on-surface chemistry in ultra-high vacuum: state-of-the-art and recent developments
journal, January 2011
- Franc, Grégory; Gourdon, André
- Physical Chemistry Chemical Physics, Vol. 13, Issue 32
Coherent electron–nuclear coupling in oligothiophene molecular wires
journal, October 2010
- Repp, Jascha; Liljeroth, Peter; Meyer, Gerhard
- Nature Physics, Vol. 6, Issue 12
Comment on “Insight into Organometallic Intermediate and Its Evolution to Covalent Bonding in Surface-Confined Ullmann Polymerization”
journal, March 2014
- Song, Fei
- ACS Nano, Vol. 8, Issue 3
Van der Waals density functionals applied to solids
journal, May 2011
- Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos
- Physical Review B, Vol. 83, Issue 19
Two-dimensional charge transport in self-organized, high-mobility conjugated polymers
journal, October 1999
- Sirringhaus, H.; Brown, P. J.; Friend, R. H.
- Nature, Vol. 401, Issue 6754, p. 685-688
Porous graphenes: two-dimensional polymer synthesis with atomic precision
journal, January 2009
- Bieri, Marco; Treier, Matthias; Cai, Jinming
- Chemical Communications, Issue 45
Reconstruction of Molecular Orbital Densities from Photoemission Data
journal, September 2009
- Puschnig, P.; Berkebile, S.; Fleming, A. J.
- Science, Vol. 326, Issue 5953
Graphene nanoribbon heterojunctions
journal, September 2014
- Cai, Jinming; Pignedoli, Carlo A.; Talirz, Leopold
- Nature Nanotechnology, Vol. 9, Issue 11
Laminated fabrication of polymeric photovoltaic diodes
journal, September 1998
- Granström, M.; Petritsch, K.; Arias, A. C.
- Nature, Vol. 395, Issue 6699
Quasiparticle Energies and Band Gaps in Graphene Nanoribbons
journal, November 2007
- Yang, Li; Park, Cheol-Hwan; Son, Young-Woo
- Physical Review Letters, Vol. 99, Issue 18
On-surface polymerization on a semiconducting oxide: aryl halide coupling controlled by surface hydroxyl groups on rutile TiO 2 (011)
journal, January 2015
- Kolmer, Marek; Zuzak, Rafal; Ahmad Zebari, Amir A.
- Chemical Communications, Vol. 51, Issue 56
Theory of the scanning tunneling microscope
journal, January 1985
- Tersoff, J.; Hamann, D. R.
- Physical Review B, Vol. 31, Issue 2
Ueber Synthesen in der Biphenylreihe
journal, May 1901
- Ullmann, F.; Bielecki, Jean
- Berichte der deutschen chemischen Gesellschaft, Vol. 34, Issue 2
Synthesis of Extended Graphdiyne Wires by Vicinal Surface Templating
journal, March 2014
- Cirera, Borja; Zhang, Yi-Qi; Björk, Jonas
- Nano Letters, Vol. 14, Issue 4
Band gap engineering for poly( p -phenylene) and poly( p -phenylene vinylene) copolymers using the tight-binding approach : Band GAP Engineering for PPP and PPV
journal, January 2005
- Giro, R.; Caldas, M. J.; Galvão, D. S.
- International Journal of Quantum Chemistry, Vol. 103, Issue 5
Resolving Band-Structure Evolution and Defect-Induced States of Single Conjugated Oligomers by Scanning Tunneling Microscopy and Tight-Binding Calculations
journal, May 2011
- Wang, Shiyong; Wang, Weihua; Lin, Nian
- Physical Review Letters, Vol. 106, Issue 20
On-surface Ullmann polymerization via intermediate organometallic networks on Ag(111)
journal, January 2014
- Eichhorn, Johanna; Strunskus, Thomas; Rastgoo-Lahrood, Atena
- Chem. Commun., Vol. 50, Issue 57
Synthesis and electronic structure of a two dimensional π-conjugated polythiophene
journal, January 2013
- Cardenas, Luis; Gutzler, Rico; Lipton-Duffin, Josh
- Chemical Science, Vol. 4, Issue 8
Intra- and Intermolecular Band Dispersion in an Organic Crystal
journal, July 2007
- Koller, G.; Berkebile, S.; Oehzelt, M.
- Science, Vol. 317, Issue 5836
Evolution of the electronic structure in a conjugated polymer series: polyacetylene, poly(p-phenylene), and poly(p-phenylenevinylene)
journal, July 1993
- Logdlund, M.; Salaneck, W. R.; Meyers, F.
- Macromolecules, Vol. 26, Issue 15
Controlling on-surface polymerization by hierarchical and substrate-directed growth
journal, January 2012
- Lafferentz, L.; Eberhardt, V.; Dri, C.
- Nature Chemistry, Vol. 4, Issue 3
Polymerization of Polyanthrylene on a Titanium Dioxide (011)-(2×1) Surface
journal, August 2013
- Kolmer, Marek; Ahmad Zebari, Amir A.; Prauzner-Bechcicki, Jakub S.
- Angewandte Chemie International Edition, Vol. 52, Issue 39
Reply to “Comment on ‘Insight into Organometallic Intermediate and Its Evolution to Covalent Bonding in Surface-Confined Ullmann Polymerization’”
journal, March 2014
- Di Giovannantonio, Marco; El Garah, Mohamed; Lipton-Duffin, Josh
- ACS Nano, Vol. 8, Issue 3
Energy Gaps in Graphene Nanoribbons
journal, November 2006
- Son, Young-Woo; Cohen, Marvin L.; Louie, Steven G.
- Physical Review Letters, Vol. 97, Issue 21
Adsorption of Large Hydrocarbons on Coinage Metals: A van der Waals Density Functional Study
journal, July 2014
- Björk, Jonas; Stafström, Sven
- ChemPhysChem, Vol. 15, Issue 13
Renormalization of Molecular Electronic Levels at Metal-Molecule Interfaces
journal, November 2006
- Neaton, J. B.; Hybertsen, Mark S.; Louie, Steven G.
- Physical Review Letters, Vol. 97, Issue 21
Improving the performance of doped π-conjugated polymers for use in organic light-emitting diodes
journal, June 2000
- Gross, Markus; Müller, David C.; Nothofer, Heinz-Georg
- Nature, Vol. 405, Issue 6787
Electronic surface potential from angle-resolved photoemission
journal, March 2014
- Vasseur, G.; Fagot-Revurat, Y.; Kierren, B.
- Physical Review B, Vol. 89, Issue 12
Electronic structure and electrical properties of interfaces between metals and ?-conjugated molecular films
journal, October 2003
- Kahn, Antoine; Koch, Norbert; Gao, Weiying
- Journal of Polymer Science Part B: Polymer Physics, Vol. 41, Issue 21
Synthesis of Polyphenylene Molecular Wires by Surface-Confined Polymerization
journal, March 2009
- Lipton-Duffin, J. A.; Ivasenko, O.; Perepichka, D. F.
- Small, Vol. 5, Issue 5
Electroluminescence in conjugated polymers
journal, January 1999
- Friend, R. H.; Gymer, R. W.; Holmes, A. B.
- Nature, Vol. 397, Issue 6715
Energy levels at interfaces between metals and conjugated organic molecules
journal, April 2008
- Koch, Norbert
- Journal of Physics: Condensed Matter, Vol. 20, Issue 18
Organic Electronic Devices and Their Functional Interfaces
journal, July 2007
- Koch, Norbert
- ChemPhysChem, Vol. 8, Issue 10
Energy-Level Alignment at Organic/Metal and Organic/Organic Interfaces
journal, April 2009
- Braun, Slawomir; Salaneck, William R.; Fahlman, Mats
- Advanced Materials, Vol. 21, Issue 14-15, p. 1450-1472
A wide-bandgap metal–semiconductor–metal nanostructure made entirely from graphene
journal, November 2012
- Hicks, J.; Tejeda, A.; Taleb-Ibrahimi, A.
- Nature Physics, Vol. 9, Issue 1
Substrate-mediated band-dispersion of adsorbate molecular states
journal, February 2013
- Wießner, M.; Ziroff, J.; Forster, F.
- Nature Communications, Vol. 4, Issue 1
Charged and metallic molecular monolayers through surface-induced aromatic stabilization
journal, February 2013
- Heimel, G.; Duhm, S.; Salzmann, I.
- Nature Chemistry, Vol. 5, Issue 3
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996
- Kresse, G.; Furthmüller, J.
- Physical Review B, Vol. 54, Issue 16, p. 11169-11186
Single Layer of Polymeric Fe-Phthalocyanine: An Organometallic Sheet on Metal and Thin Insulating Film
journal, February 2011
- Abel, Mathieu; Clair, Sylvain; Ourdjini, Oualid
- Journal of the American Chemical Society, Vol. 133, Issue 5
Atomically precise bottom-up fabrication of graphene nanoribbons
journal, July 2010
- Cai, Jinming; Ruffieux, Pascal; Jaafar, Rached
- Nature, Vol. 466, Issue 7305
Complete determination of molecular orbitals by measurement of phase symmetry and electron density
journal, June 2014
- Wießner, M.; Hauschild, D.; Sauer, C.
- Nature Communications, Vol. 5, Issue 1
Steering On-Surface Polymerization with Metal-Directed Template
journal, February 2013
- Lin, Tao; Shang, Xue Song; Adisoejoso, Jinne
- Journal of the American Chemical Society, Vol. 135, Issue 9
Electronic band dispersion of graphene nanoribbons via Fourier-transformed scanning tunneling spectroscopy
journal, January 2015
- Söde, Hajo; Talirz, Leopold; Gröning, Oliver
- Physical Review B, Vol. 91, Issue 4
CHEMISTRY: Extending Polymer Conjugation into the Second Dimension
journal, January 2009
- Perepichka, D. F.; Rosei, F.
- Science, Vol. 323, Issue 5911
Van der Waals Density Functional for General Geometries
journal, June 2004
- Dion, M.; Rydberg, H.; Schröder, E.
- Physical Review Letters, Vol. 92, Issue 24
Termini of Bottom-Up Fabricated Graphene Nanoribbons
journal, January 2013
- Talirz, Leopold; Söde, Hajo; Cai, Jinming
- Journal of the American Chemical Society, Vol. 135, Issue 6
Detection of individual gas molecules adsorbed on graphene
journal, July 2007
- Schedin, F.; Geim, A. K.; Morozov, S. V.
- Nature Materials, Vol. 6, Issue 9, p. 652-655
Reconstruction-induced multiple gaps in the weak coupling limit: The surface bands of Au(111) vicinal surfaces
journal, August 2006
- Didiot, C.; Fagot-Revurat, Y.; Pons, S.
- Physical Review B, Vol. 74, Issue 8
Electronic Structure of Atomically Precise Graphene Nanoribbons
journal, July 2012
- Ruffieux, Pascal; Cai, Jinming; Plumb, Nicholas C.
- ACS Nano, Vol. 6, Issue 8
Nano-architectures by covalent assembly of molecular building blocks
journal, October 2007
- Grill, Leonhard; Dyer, Matthew; Lafferentz, Leif
- Nature Nanotechnology, Vol. 2, Issue 11
Theoretical study of the adsorption of benzene on coinage metals
journal, January 2014
- Reckien, Werner; Eggers, Melanie; Bredow, Thomas
- Beilstein Journal of Organic Chemistry, Vol. 10
Combined Photoemission and Scanning Tunneling Microscopy Study of the Surface-Assisted Ullmann Coupling Reaction
journal, March 2014
- Chen, Min; Xiao, Jie; Steinrück, Hans-Peter
- The Journal of Physical Chemistry C, Vol. 118, Issue 13
Step-by-step growth of epitaxially aligned polythiophene by surface-confined reaction
journal, June 2010
- Lipton-Duffin, J. A.; Miwa, J. A.; Kondratenko, M.
- Proceedings of the National Academy of Sciences, Vol. 107, Issue 25
Insight into Organometallic Intermediate and Its Evolution to Covalent Bonding in Surface-Confined Ullmann Polymerization
journal, August 2013
- Di Giovannantonio, Marco; El Garah, Mohamed; Lipton-Duffin, Josh
- ACS Nano, Vol. 7, Issue 9
Effect of Substrate Chemistry on the Bottom-Up Fabrication of Graphene Nanoribbons: Combined Core-Level Spectroscopy and STM Study
journal, May 2014
- Simonov, Konstantin A.; Vinogradov, Nikolay A.; Vinogradov, Alexander S.
- The Journal of Physical Chemistry C, Vol. 118, Issue 23
Polymerization of Polyanthrylene on a Titanium Dioxide (011)-(2×1) Surface
journal, August 2013
- Kolmer, Marek; Ahmad Zebari, Amir A.; Prauzner-Bechcicki, Jakub S.
- Angewandte Chemie, Vol. 125, Issue 39
Atomically precise bottom-up fabrication of graphene nanoribbons
text, January 2010
- Cai, J. M.; Ruffieux, P.; Jaafar, R.
- Nature Publishing Group
Electronic band dispersion of graphene nanoribbons via Fourier-transformed scanning tunneling spectroscopy
text, January 2015
- Ruffieux, Pascal; Söde, Hajo; Müllen, Klaus
- American Physical Society
Van der Waals density functionals applied to solids
text, January 2011
- Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos
- arXiv
A wide band gap metal-semiconductor-metal nanostructure made entirely from graphene
text, January 2012
- Hicks, J.; Tejeda, A.; Taleb-Ibrahimi, A.
- arXiv
Electronic Band Dispersion of Graphene Nanoribbons via Fourier-Transformed Scanning Tunneling Spectroscopy
text, January 2014
- Söde, Hajo; Talirz, Leopold; Gröning, Oliver
- arXiv
Detection of Individual Gas Molecules Absorbed on Graphene
text, January 2006
- Schedin, F.; Geim, A. K.; Morozov, S. V.
- arXiv
Adsorption of Large Hydrocarbons on Coinage Metals: A van der Waals Density Functional Study
journal, July 2014
- Björk, Jonas; Stafström, Sven
- ChemPhysChem, Vol. 15, Issue 13
Synthesis of Polyphenylene Molecular Wires by Surface-Confined Polymerization
journal, March 2009
- Lipton-Duffin, J. A.; Ivasenko, O.; Perepichka, D. F.
- Small, Vol. 5, Issue 5
Single Layer of Polymeric Fe-Phthalocyanine: An Organometallic Sheet on Metal and Thin Insulating Film
journal, February 2011
- Abel, Mathieu; Clair, Sylvain; Ourdjini, Oualid
- Journal of the American Chemical Society, Vol. 133, Issue 5
Termini of Bottom-Up Fabricated Graphene Nanoribbons
journal, January 2013
- Talirz, Leopold; Söde, Hajo; Cai, Jinming
- Journal of the American Chemical Society, Vol. 135, Issue 6
Steering On-Surface Polymerization with Metal-Directed Template
journal, February 2013
- Lin, Tao; Shang, Xue Song; Adisoejoso, Jinne
- Journal of the American Chemical Society, Vol. 135, Issue 9
Molecules–Oligomers–Nanowires–Graphene Nanoribbons: A Bottom-Up Stepwise On-Surface Covalent Synthesis Preserving Long-Range Order
journal, January 2015
- Basagni, Andrea; Sedona, Francesco; Pignedoli, Carlo A.
- Journal of the American Chemical Society, Vol. 137, Issue 5
Insight into Organometallic Intermediate and Its Evolution to Covalent Bonding in Surface-Confined Ullmann Polymerization
journal, August 2013
- Di Giovannantonio, Marco; El Garah, Mohamed; Lipton-Duffin, Josh
- ACS Nano, Vol. 7, Issue 9
Improving the performance of doped π-conjugated polymers for use in organic light-emitting diodes
journal, June 2000
- Gross, Markus; Müller, David C.; Nothofer, Heinz-Georg
- Nature, Vol. 405, Issue 6787
Charged and metallic molecular monolayers through surface-induced aromatic stabilization
journal, February 2013
- Heimel, G.; Duhm, S.; Salzmann, I.
- Nature Chemistry, Vol. 5, Issue 3
Substrate-mediated band-dispersion of adsorbate molecular states
journal, February 2013
- Wießner, M.; Ziroff, J.; Forster, F.
- Nature Communications, Vol. 4, Issue 1
Complete determination of molecular orbitals by measurement of phase symmetry and electron density
journal, June 2014
- Wießner, M.; Hauschild, D.; Sauer, C.
- Nature Communications, Vol. 5, Issue 1
Detection of individual gas molecules adsorbed on graphene
journal, July 2007
- Schedin, F.; Geim, A. K.; Morozov, S. V.
- Nature Materials, Vol. 6, Issue 9, p. 652-655
Coherent electron–nuclear coupling in oligothiophene molecular wires
journal, October 2010
- Repp, Jascha; Liljeroth, Peter; Meyer, Gerhard
- Nature Physics, Vol. 6, Issue 12
Ullmann-type coupling of brominated tetrathienoanthracene on copper and silver
journal, January 2014
- Gutzler, Rico; Cardenas, Luis; Lipton-Duffin, Josh
- Nanoscale, Vol. 6, Issue 5
Step-by-step growth of epitaxially aligned polythiophene by surface-confined reaction
journal, June 2010
- Lipton-Duffin, J. A.; Miwa, J. A.; Kondratenko, M.
- Proceedings of the National Academy of Sciences, Vol. 107, Issue 25
Tight-binding description of graphene
journal, July 2002
- Reich, S.; Maultzsch, J.; Thomsen, C.
- Physical Review B, Vol. 66, Issue 3
Intra- and Intermolecular Band Dispersion in an Organic Crystal
journal, July 2007
- Koller, G.; Berkebile, S.; Oehzelt, M.
- Science, Vol. 317, Issue 5836
Reconstruction of Molecular Orbital Densities from Photoemission Data
journal, September 2009
- Puschnig, P.; Berkebile, S.; Fleming, A. J.
- Science, Vol. 326, Issue 5953
Theoretical study of the adsorption of benzene on coinage metals
journal, January 2014
- Reckien, Werner; Eggers, Melanie; Bredow, Thomas
- Beilstein Journal of Organic Chemistry, Vol. 10
Energy Gaps in Graphene Nanoribbons
text, January 2006
- Son, Young-Woo; Cohen, Marvin L.; Louie, Steven G.
- arXiv
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Photochemistry Highlights on On‐Surface Synthesis
journal, June 2019
- Palmino, F.; Loppacher, C.; Chérioux, F.
- ChemPhysChem, Vol. 20, Issue 18
Functionalized Graphdiyne Nanowires: On-Surface Synthesis and Assessment of Band Structure, Flexibility, and Information Storage Potential
journal, February 2018
- Klappenberger, Florian; Hellwig, Raphael; Du, Ping
- Small, Vol. 14, Issue 14
Bloch Oscillations in Fibonacci lattices: polaron formation
journal, March 2019
- de Brito, Paulo Eduardo; Enders, Bernhard Georg; Ribeiro, Luiz Antonio
- Journal of Molecular Modeling, Vol. 25, Issue 4
On-surface synthesis of aligned functional nanoribbons monitored by scanning tunnelling microscopy and vibrational spectroscopy
journal, April 2017
- Kalashnyk, Nataliya; Mouhat, Kawtar; Oh, Jihun
- Nature Communications, Vol. 8, Issue 1
Hierarchical on-surface synthesis and electronic structure of carbonyl-functionalized one- and two-dimensional covalent nanoarchitectures
journal, March 2017
- Steiner, Christian; Gebhardt, Julian; Ammon, Maximilian
- Nature Communications, Vol. 8, Issue 1
Strain-induced skeletal rearrangement of a polycyclic aromatic hydrocarbon on a copper surface
journal, July 2017
- Shiotari, Akitoshi; Nakae, Takahiro; Iwata, Kota
- Nature Communications, Vol. 8, Issue 1
Covalent on-surface polymerization
journal, January 2020
- Grill, Leonhard; Hecht, Stefan
- Nature Chemistry, Vol. 12, Issue 2
The role of halogens in on-surface Ullmann polymerization
journal, January 2017
- Galeotti, Gianluca; Di Giovannantonio, Marco; Lipton-Duffin, Josh
- Faraday Discussions, Vol. 204
Surface-mediated assembly, polymerization and degradation of thiophene-based monomers
journal, January 2019
- Galeotti, G.; De Marchi, F.; Taerum, T.
- Chemical Science, Vol. 10, Issue 19
An unexpected organometallic intermediate in surface-confined Ullmann coupling
journal, January 2019
- Galeotti, Gianluca; Di Giovannantonio, Marco; Cupo, Andrew
- Nanoscale, Vol. 11, Issue 16
Reversibility and intermediate steps as key tools for the growth of extended ordered polymers via on-surface synthesis
journal, February 2018
- Di Giovannantonio, Marco; Contini, Giorgio
- Journal of Physics: Condensed Matter, Vol. 30, Issue 9
Finding the hidden valence band of N = 7 armchair graphene nanoribbons with angle-resolved photoemission spectroscopy
journal, April 2018
- Senkovskiy, Boris V.; Usachov, Dmitry Yu; Fedorov, Alexander V.
- 2D Materials, Vol. 5, Issue 3
Diacetylene Linked Anthracene Oligomers Synthesized by One-Shot Homocoupling of Trimethylsilyl on Cu(111)
journal, July 2018
- Kawai, Shigeki; Krejčí, Ondrěj; Foster, Adam S.
- ACS Nano, Vol. 12, Issue 8
Controlling a Chemical Coupling Reaction on a Surface: Tools and Strategies for On-Surface Synthesis
journal, March 2019
- Clair, Sylvain; de Oteyza, Dimas G.
- Chemical Reviews, Vol. 119, Issue 7
Π Band Dispersion along Conjugated Organic Nanowires Synthesized on a Metal Oxide Semiconductor
journal, April 2016
- Vasseur, Guillaume; Abadia, Mikel; Miccio, Luis A.
- Journal of the American Chemical Society, Vol. 138, Issue 17
Hierarchical on-surface synthesis and electronic structure of carbonyl-functionalized one- and two-dimensional covalent nanoarchitectures
journal, March 2017
- Steiner, Christian; Gebhardt, Julian; Ammon, Maximilian
- Nature Communications, Vol. 8, Issue 1
Strain-induced skeletal rearrangement of a polycyclic aromatic hydrocarbon on a copper surface
journal, July 2017
- Shiotari, Akitoshi; Nakae, Takahiro; Iwata, Kota
- Nature Communications, Vol. 8, Issue 1
Tunable Band Alignment with Unperturbed Carrier Mobility of On-Surface Synthesized Organic Semiconducting Wires
text, January 2016
- Basagni, Andrea; Vasseur, Guillaume; Pignedoli, Carlo A.
- arXiv