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Title: Electron-beam-evaporated thin films of hafnium dioxide for fabricating electronic devices

Abstract

Thin films of hafnium dioxide (HfO2) are widely used as the gate oxide in fabricating integrated circuits because of their high dielectric constants. In this paper, the authors report the growth of thin films of HfO2 using e-beam evaporation, and the fabrication of complementary metal-oxide semiconductor (CMOS) integrated circuits using this HfO2 thin film as the gate oxide. The authors analyzed the thin films using high-resolution transmission electron microscopy and electron diffraction, thereby demonstrating that the e-beam-evaporation-grown HfO2 film has a polycrystalline structure and forms an excellent interface with silicon. Accordingly, we fabricated 31-stage CMOS ring oscillator to test the quality of the HfO2 thin film as the gate oxide, and obtained excellent rail-to-rail oscillation waveforms from it, denoting that the HfO2 thin film functioned very well as the gate oxide.

Authors:
 [1];  [2]
  1. Alabama A&M Univ., Normal, AL (United States)
  2. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Laboratory (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1224764
Report Number(s):
BNL-108477-2015-JA
Journal ID: ISSN 2166-2746; JVTBD9; KC0403020
Grant/Contract Number:  
SC00112704
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Vacuum Science and Technology B
Additional Journal Information:
Journal Volume: 33; Journal Issue: 4; Journal ID: ISSN 2166-2746
Publisher:
American Vacuum Society/AIP
Country of Publication:
United States
Language:
English
Subject:
42 ENGINEERING; hafnium dioxide (HfO2) thin films; complementary metal-oxide semiconductor (CMOS) electronic circuits; silicon ring oscillator; Center for Functional Nanomaterials

Citation Formats

Xiao, Zhigang, and Kisslinger, Kim. Electron-beam-evaporated thin films of hafnium dioxide for fabricating electronic devices. United States: N. p., 2015. Web. doi:10.1116/1.4922627.
Xiao, Zhigang, & Kisslinger, Kim. Electron-beam-evaporated thin films of hafnium dioxide for fabricating electronic devices. United States. https://doi.org/10.1116/1.4922627
Xiao, Zhigang, and Kisslinger, Kim. Wed . "Electron-beam-evaporated thin films of hafnium dioxide for fabricating electronic devices". United States. https://doi.org/10.1116/1.4922627. https://www.osti.gov/servlets/purl/1224764.
@article{osti_1224764,
title = {Electron-beam-evaporated thin films of hafnium dioxide for fabricating electronic devices},
author = {Xiao, Zhigang and Kisslinger, Kim},
abstractNote = {Thin films of hafnium dioxide (HfO2) are widely used as the gate oxide in fabricating integrated circuits because of their high dielectric constants. In this paper, the authors report the growth of thin films of HfO2 using e-beam evaporation, and the fabrication of complementary metal-oxide semiconductor (CMOS) integrated circuits using this HfO2 thin film as the gate oxide. The authors analyzed the thin films using high-resolution transmission electron microscopy and electron diffraction, thereby demonstrating that the e-beam-evaporation-grown HfO2 film has a polycrystalline structure and forms an excellent interface with silicon. Accordingly, we fabricated 31-stage CMOS ring oscillator to test the quality of the HfO2 thin film as the gate oxide, and obtained excellent rail-to-rail oscillation waveforms from it, denoting that the HfO2 thin film functioned very well as the gate oxide.},
doi = {10.1116/1.4922627},
journal = {Journal of Vacuum Science and Technology B},
number = 4,
volume = 33,
place = {United States},
year = {Wed Jun 17 00:00:00 EDT 2015},
month = {Wed Jun 17 00:00:00 EDT 2015}
}

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Works referenced in this record:

Beyond the conventional transistor
journal, March 2002

  • Wong, H. -S. P.
  • IBM Journal of Research and Development, Vol. 46, Issue 2.3
  • DOI: 10.1147/rd.462.0133

High dielectric constant gate oxides for metal oxide Si transistors
journal, December 2005


High-K materials and metal gates for CMOS applications
journal, February 2015


Cramming More Components Onto Integrated Circuits
journal, January 1998


Characterization of hafnium oxide thin films prepared by electron beam evaporation
journal, March 2004

  • Al-Kuhaili, M. F.; Durrani, S. M. A.; Khawaja, E. E.
  • Journal of Physics D: Applied Physics, Vol. 37, Issue 8
  • DOI: 10.1088/0022-3727/37/8/015

Atomic layer deposition of hafnium oxide dielectrics on silicon and germanium substrates
journal, July 2007

  • McNeill, D. W.; Bhattacharya, S.; Wadsworth, H.
  • Journal of Materials Science: Materials in Electronics, Vol. 19, Issue 2
  • DOI: 10.1007/s10854-007-9337-y

Atomic layer deposition of hafnium oxide and hafnium silicate thin films using liquid precursors and ozone
journal, July 2004

  • Senzaki, Yoshihide; Park, Seung; Chatham, Hood
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 22, Issue 4
  • DOI: 10.1116/1.1761186

ALD of Hafnium Oxide Thin Films from Tetrakis(ethylmethylamino)hafnium and Ozone
journal, January 2005

  • Liu, Xinye; Ramanathan, Sasangan; Longdergan, Ana
  • Journal of The Electrochemical Society, Vol. 152, Issue 3
  • DOI: 10.1149/1.1859631

Atomic Layer Deposition of Hafnium and Zirconium Oxides Using Metal Amide Precursors
journal, October 2002

  • Hausmann, Dennis M.; Kim, Esther; Becker, Jill
  • Chemistry of Materials, Vol. 14, Issue 10
  • DOI: 10.1021/cm020357x

Crystal structure and band gap determination of HfO2 thin films
journal, March 2007

  • Cheynet, Marie C.; Pokrant, Simone; Tichelaar, Frans D.
  • Journal of Applied Physics, Vol. 101, Issue 5
  • DOI: 10.1063/1.2697551

Textured crystallization of ultrathin hafnium oxide films on silicon substrate
journal, April 2007

  • Bohra, Fakhruddin; Jiang, Bin; Zuo, Jian-Min
  • Applied Physics Letters, Vol. 90, Issue 16
  • DOI: 10.1063/1.2724925

Effects of crystallization on the electrical properties of ultrathin HfO2 dielectrics grown by atomic layer deposition
journal, January 2003

  • Kim, Hyoungsub; McIntyre, Paul C.; Saraswat, Krishna C.
  • Applied Physics Letters, Vol. 82, Issue 1
  • DOI: 10.1063/1.1533117

High performance ring oscillators from 10-nm wide silicon nanowire field-effect transistors
journal, June 2011


Integrated Circuits Based on Bilayer MoS2 Transistors
journal, January 2012

  • Wang, Han; Yu, Lili; Lee, Yi-Hsien
  • Nano Letters, Vol. 12, Issue 9, p. 4674-4680
  • DOI: 10.1021/nl302015v

Works referencing / citing this record: