Direct Epoxidation of Propylene over Stabilized Cu+ Surface Sites on Ti Modified Cu2O
Abstract
Direct propylene epoxidation by O2 is a challenging reaction because of the strong tendency for complete combustion. Results from the current study demonstrate the feasibility to tune the epoxidation selectivity by generating highly dispersed and stabilized Cu+ active sites in a TiCuOx mixed oxide. The TiCuOx surface anchors the key surface intermediate, oxametallacycle, leading to higher selectivity for epoxidation of propylene.
- Authors:
-
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Univ. of Delaware, Newark, DE (United States)
- Peter the Great St. Petersburg Polytechnic Univ. (Russia)
- Brookhaven National Lab. (BNL), Upton, NY (United States); Columbia Univ., New York, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1214529
- Report Number(s):
- BNL-108339-2015-JA
Journal ID: ISSN 1521-3773; KC0302010
- Grant/Contract Number:
- DE-SC00112704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Angewandte Chemie International Edition (Online)
- Additional Journal Information:
- Journal Name: Angewandte Chemie International Edition (Online); Journal Volume: 54; Journal ID: ISSN 1521-3773
- Publisher:
- Gesselschaft Deutscher Chemiker
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Yang, X., Kattel, S., Xiong, K., Mudiyanselage, K., Rykov, S., Senanayake, S. D., Rodriguez, J. A., Liu, P., Stacchiola, D. J., and Chen, J. G. Direct Epoxidation of Propylene over Stabilized Cu+ Surface Sites on Ti Modified Cu2O. United States: N. p., 2015.
Web. doi:10.1002/anie.201504538.
Yang, X., Kattel, S., Xiong, K., Mudiyanselage, K., Rykov, S., Senanayake, S. D., Rodriguez, J. A., Liu, P., Stacchiola, D. J., & Chen, J. G. Direct Epoxidation of Propylene over Stabilized Cu+ Surface Sites on Ti Modified Cu2O. United States. https://doi.org/10.1002/anie.201504538
Yang, X., Kattel, S., Xiong, K., Mudiyanselage, K., Rykov, S., Senanayake, S. D., Rodriguez, J. A., Liu, P., Stacchiola, D. J., and Chen, J. G. Fri .
"Direct Epoxidation of Propylene over Stabilized Cu+ Surface Sites on Ti Modified Cu2O". United States. https://doi.org/10.1002/anie.201504538. https://www.osti.gov/servlets/purl/1214529.
@article{osti_1214529,
title = {Direct Epoxidation of Propylene over Stabilized Cu+ Surface Sites on Ti Modified Cu2O},
author = {Yang, X. and Kattel, S. and Xiong, K. and Mudiyanselage, K. and Rykov, S. and Senanayake, S. D. and Rodriguez, J. A. and Liu, P. and Stacchiola, D. J. and Chen, J. G.},
abstractNote = {Direct propylene epoxidation by O2 is a challenging reaction because of the strong tendency for complete combustion. Results from the current study demonstrate the feasibility to tune the epoxidation selectivity by generating highly dispersed and stabilized Cu+ active sites in a TiCuOx mixed oxide. The TiCuOx surface anchors the key surface intermediate, oxametallacycle, leading to higher selectivity for epoxidation of propylene.},
doi = {10.1002/anie.201504538},
journal = {Angewandte Chemie International Edition (Online)},
number = ,
volume = 54,
place = {United States},
year = {Fri Jul 17 00:00:00 EDT 2015},
month = {Fri Jul 17 00:00:00 EDT 2015}
}
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Works referenced in this record:
Promoters in heterogeneous catalysis: The role of Cl on ethylene epoxidation over Ag
journal, April 2014
- Rocha, Tulio C. R.; Hävecker, Michael; Knop-Gericke, Axel
- Journal of Catalysis, Vol. 312
Ethylene Epoxidation on Ag: Identification of the Crucial Surface Intermediate by Experimental and Theoretical Investigation of its Electronic Structure
journal, May 2004
- Linic, Suljo; Piao, Hong; Adib, Kaveh
- Angewandte Chemie International Edition, Vol. 43, Issue 22
Increased Silver Activity for Direct Propylene Epoxidation via Subnanometer Size Effects
journal, April 2010
- Lei, Y.; Mehmood, F.; Lee, S.
- Science, Vol. 328, Issue 5975, p. 224-228
High Catalytic Performance of MoO 3 -Bi 2 SiO 5 /SiO 2 for the Gas-Phase Epoxidation of Propylene by Molecular Oxygen
journal, February 2014
- Pang, Yijun; Chen, Xiaohui; Xu, Chengzhi
- ChemCatChem, Vol. 6, Issue 3
Trimethylamine as a Gas-Phase Promoter: Highly Efficient Epoxidation of Propylene over Supported Gold Catalysts
journal, January 2006
- Chowdhury, Biswajit; Bravo-Suárez, Juan. J.; Daté, Masakazu
- Angewandte Chemie International Edition, Vol. 45, Issue 3
Stabilization of Catalytically Active Cu + Surface Sites on Titanium-Copper Mixed-Oxide Films
journal, April 2014
- Baber, Ashleigh E.; Yang, Xiaofang; Kim, Hyun You
- Angewandte Chemie, Vol. 126, Issue 21
Chemical Structures and Performance of Perovskite Oxides
journal, July 2001
- Pena, M.; Fierro, J.
- Chemical Reviews, Vol. 101, Issue 7, p. 1981-2018
Selective Propene Epoxidation on Immobilized Au 6–10 Clusters: The Effect of Hydrogen and Water on Activity and Selectivity
journal, January 2009
- Lee, Sungsik; Molina, Luis M.; López, María J.
- Angewandte Chemie, Vol. 121, Issue 8
Low-Basicity Oxygen Atoms: A Key in the Search for Propylene Epoxidation Catalysts
journal, March 2007
- Torres, Daniel; Lopez, Nuria; Illas, Francesc
- Angewandte Chemie, Vol. 119, Issue 12
Oxametallacycle formation via ring-opening of 1-epoxy-3-butene on Ag(110): a combined experimental/theoretical approach
journal, December 2000
- Medlin, J. Will; Barteau, Mark A.; Vohs, John M.
- Journal of Molecular Catalysis A: Chemical, Vol. 163, Issue 1-2
Crystal-Plane-Controlled Selectivity of Cu 2 O Catalysts in Propylene Oxidation with Molecular Oxygen
journal, April 2014
- Hua, Qing; Cao, Tian; Gu, Xiang-Kui
- Angewandte Chemie International Edition, Vol. 53, Issue 19
Ethylene Epoxidation on Ag: Identification of the Crucial Surface Intermediate by Experimental and Theoretical Investigation of its Electronic Structure
journal, May 2004
- Linic, Suljo; Piao, Hong; Adib, Kaveh
- Angewandte Chemie, Vol. 116, Issue 22
Effects of added 3d transition-metals on Ag-based catalysts for direct epoxidation of propylene by oxygen
journal, October 2005
- Takahashi, Atsushi; Hamakawa, Noriyasu; Nakamura, Isao
- Applied Catalysis A: General, Vol. 294, Issue 1
The Production of Propene Oxide: Catalytic Processes and Recent Developments
journal, May 2006
- Nijhuis, T. Alexander; Makkee, Michiel; Moulijn, Jacob A.
- Industrial & Engineering Chemistry Research, Vol. 45, Issue 10
The Formation of Epoxides from Reactions of Oxametallacycles on Ag(110): A Density Functional Theory Study
journal, October 2001
- Medlin, J. Will; Barteau, Mark A.
- The Journal of Physical Chemistry B, Vol. 105, Issue 41
Catalytic epoxidation of propene with H2O–O 2 reactants on Au/TiO 2
journal, January 2009
- Ojeda, Manuel; Iglesia, Enrique
- Chem. Commun., Issue 3
Trimethylamine as a Gas-Phase Promoter: Highly Efficient Epoxidation of Propylene over Supported Gold Catalysts
journal, January 2006
- Chowdhury, Biswajit; Bravo-Suárez, Juan. J.; Daté, Masakazu
- Angewandte Chemie, Vol. 118, Issue 3
Copper as a selective catalyst for the epoxidation of propene
journal, December 2005
- Vaughan, O.; Kyriakou, G.; Macleod, N.
- Journal of Catalysis, Vol. 236, Issue 2
Stabilization of Catalytically Active Cu + Surface Sites on Titanium-Copper Mixed-Oxide Films
journal, April 2014
- Baber, Ashleigh E.; Yang, Xiaofang; Kim, Hyun You
- Angewandte Chemie International Edition, Vol. 53, Issue 21
Selective Propene Epoxidation on Immobilized Au 6-10 Clusters: The Effect of Hydrogen and Water on Activity and Selectivity
journal, February 2009
- Lee, Sungsik; Molina, Luis M.; López, María J.
- Angewandte Chemie International Edition, Vol. 48, Issue 8
Catalysis Science of Bulk Mixed Oxides
journal, April 2012
- Wachs, Israel E.; Routray, Kamalakanta
- ACS Catalysis, Vol. 2, Issue 6
Tuning Selectivity in Propylene Epoxidation by Plasmon Mediated Photo-Switching of Cu Oxidation State
journal, March 2013
- Marimuthu, A.; Zhang, J.; Linic, S.
- Science, Vol. 339, Issue 6127, p. 1590-1593
Low-Basicity Oxygen Atoms: A Key in the Search for Propylene Epoxidation Catalysts
journal, March 2007
- Torres, Daniel; Lopez, Nuria; Illas, Francesc
- Angewandte Chemie International Edition, Vol. 46, Issue 12
Reaction-Controlled Phase-Transfer Catalysis for Propylene Epoxidation to Propylene Oxide
journal, May 2001
- Zuwei, X.
- Science, Vol. 292, Issue 5519
Crystal-Plane-Controlled Selectivity of Cu 2 O Catalysts in Propylene Oxidation with Molecular Oxygen
journal, April 2014
- Hua, Qing; Cao, Tian; Gu, Xiang-Kui
- Angewandte Chemie, Vol. 126, Issue 19
In Situ Imaging of Cu 2 O under Reducing Conditions: Formation of Metallic Fronts by Mass Transfer
journal, October 2013
- Baber, Ashleigh E.; Xu, Fang; Dvorak, Filip
- Journal of the American Chemical Society, Vol. 135, Issue 45
Autocatalytic Reduction of a Cu 2 O/Cu(111) Surface by CO: STM, XPS, and DFT Studies
journal, July 2010
- Yang, Fan; Choi, YongMan; Liu, Ping
- The Journal of Physical Chemistry C, Vol. 114, Issue 40
Selective Vapor-Phase Epoxidation of Propylene over Au/TiO2Catalysts in the Presence of Oxygen and Hydrogen
journal, September 1998
- Hayashi, Toshio; Tanaka, Koji; Haruta, Masatake
- Journal of Catalysis, Vol. 178, Issue 2
Works referencing / citing this record:
Correlation between Copper Oxide Particle Size and Selectivity towards Propylene Oxide in Selective Oxidation of Propene
journal, November 2018
- Diekmann, Marek; Koch, Gregor; König, Michaela
- ChemCatChem, Vol. 10, Issue 23
Surface chemistry of group IB metals and related oxides
journal, January 2017
- Huang, Weixin; Sun, Guanghui; Cao, Tian
- Chemical Society Reviews, Vol. 46, Issue 7
Tuning the Catalytic Performance of Novel Composites Based on ZIF-8 and Nafen through Dimensional and Concentration Effects in the Synthesis of Propylene Glycol Methyl Ether: Tuning the Catalytic Performance of Novel Composites Based on ZIF-8 and Nafen through Dimensional and Concentration Effects in the Synthesis of Propyl
journal, June 2019
- Timofeeva, Maria N.; Paukshtis, Evgeniy A.; Panchenko, Valentina N.
- European Journal of Organic Chemistry, Vol. 2019, Issue 26
A density functional theory study of propylene epoxidation mechanism on Ag 2 O(001) surface
journal, January 2018
- Tezsevin, I.; van Santen, R. A.; Onal, I.
- Physical Chemistry Chemical Physics, Vol. 20, Issue 41
The oxidation of copper catalysts during ethylene epoxidation
journal, January 2015
- Greiner, M. T.; Jones, T. E.; Johnson, B. E.
- Physical Chemistry Chemical Physics, Vol. 17, Issue 38
Über den Technologiewandel in der Propylenoxid-Herstellung: Vom Chlor zum Sauerstoff
journal, March 2017
- Bernhard, Maik; Anton, Johan; Schmidt, Franz
- Chemie in unserer Zeit, Vol. 51, Issue 3
Enhanced hydrogenation of ethyl-levulinate to γ-valerolactone over Ni δ O x stabilized Cu + surface sites
journal, January 2016
- Zhu, Junhua; Tang, Yi; Tang, Kangjian
- RSC Advances, Vol. 6, Issue 90