Controlled Pd(0)/t Bu3P Catalyzed Suzuki Cross-Coupling Polymerization of AB-Type Monomers with ArPd(t Bu3P)X or Pd2(dba)3/t Bu3P/ArX as the Initiator
Abstract
The synthesis of well-defined and functionalized conjugated polymers, which are essential in the development of efficient organic electronics, through Suzuki cross-coupling polymerizations has been a challenging task. We developed controlled Pd(0)/t-Bu3P-catalyzed Suzuki cross-coupling polymerizations of AB-type monomers via the chain-growth mechanism with a series of in situ generated ArPd(t-Bu3P)X (X = I, Br, Cl) complexes as initiators. Among them, the combinations of Pd2(dba)3/t-Bu3P/p-BrC6H4I, Pd2(dba)3/t-Bu3P/p-BrC6H4CH2OH and Pd2(dba)3/t-Bu3P/p-PhCOC6H4Br were identified as highly robust initiator systems, resulting in polymers with predictable molecular weight and narrow polydispersity (PDI~1.13-1.20). In addition, Pd2(dba)3/t-Bu3P/p-BrC6H4CH2OH and Pd2(dba)3/t-Bu3P/p-PhCOC6H4Br initiator systems afforded functional polymers with >95% fidelity. Our results paved the road to access well-defined conjugated polymers, including conjugated polymers with complex polymer architectures such as block copolymers and branch copolymers.
- Authors:
-
- College of Staten Island, Staten Island, NY (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences (CNMS)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1185617
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Macromolecules
- Additional Journal Information:
- Journal Volume: 48; Journal Issue: 4; Journal ID: ISSN 0024-9297
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Zhang, Honghai, Xing, Chun-Hui, Hu, Qiao-Sheng, and Hong, Kunlun. Controlled Pd(0)/t Bu3P Catalyzed Suzuki Cross-Coupling Polymerization of AB-Type Monomers with ArPd(t Bu3P)X or Pd2(dba)3/t Bu3P/ArX as the Initiator. United States: N. p., 2015.
Web. doi:10.1021/ma502521u.
Zhang, Honghai, Xing, Chun-Hui, Hu, Qiao-Sheng, & Hong, Kunlun. Controlled Pd(0)/t Bu3P Catalyzed Suzuki Cross-Coupling Polymerization of AB-Type Monomers with ArPd(t Bu3P)X or Pd2(dba)3/t Bu3P/ArX as the Initiator. United States. https://doi.org/10.1021/ma502521u
Zhang, Honghai, Xing, Chun-Hui, Hu, Qiao-Sheng, and Hong, Kunlun. Thu .
"Controlled Pd(0)/t Bu3P Catalyzed Suzuki Cross-Coupling Polymerization of AB-Type Monomers with ArPd(t Bu3P)X or Pd2(dba)3/t Bu3P/ArX as the Initiator". United States. https://doi.org/10.1021/ma502521u. https://www.osti.gov/servlets/purl/1185617.
@article{osti_1185617,
title = {Controlled Pd(0)/t Bu3P Catalyzed Suzuki Cross-Coupling Polymerization of AB-Type Monomers with ArPd(t Bu3P)X or Pd2(dba)3/t Bu3P/ArX as the Initiator},
author = {Zhang, Honghai and Xing, Chun-Hui and Hu, Qiao-Sheng and Hong, Kunlun},
abstractNote = {The synthesis of well-defined and functionalized conjugated polymers, which are essential in the development of efficient organic electronics, through Suzuki cross-coupling polymerizations has been a challenging task. We developed controlled Pd(0)/t-Bu3P-catalyzed Suzuki cross-coupling polymerizations of AB-type monomers via the chain-growth mechanism with a series of in situ generated ArPd(t-Bu3P)X (X = I, Br, Cl) complexes as initiators. Among them, the combinations of Pd2(dba)3/t-Bu3P/p-BrC6H4I, Pd2(dba)3/t-Bu3P/p-BrC6H4CH2OH and Pd2(dba)3/t-Bu3P/p-PhCOC6H4Br were identified as highly robust initiator systems, resulting in polymers with predictable molecular weight and narrow polydispersity (PDI~1.13-1.20). In addition, Pd2(dba)3/t-Bu3P/p-BrC6H4CH2OH and Pd2(dba)3/t-Bu3P/p-PhCOC6H4Br initiator systems afforded functional polymers with >95% fidelity. Our results paved the road to access well-defined conjugated polymers, including conjugated polymers with complex polymer architectures such as block copolymers and branch copolymers.},
doi = {10.1021/ma502521u},
journal = {Macromolecules},
number = 4,
volume = 48,
place = {United States},
year = {Thu Feb 05 00:00:00 EST 2015},
month = {Thu Feb 05 00:00:00 EST 2015}
}
Web of Science
Works referenced in this record:
Palladium-Catalyzed Cross-Coupling Reactions of Organoboron Compounds
journal, November 1995
- Miyaura, Norio.; Suzuki, Akira.
- Chemical Reviews, Vol. 95, Issue 7
Recent advances in the cross-coupling reactions of organoboron derivatives with organic electrophiles, 1995–1998
journal, March 1999
- Suzuki, Akira
- Journal of Organometallic Chemistry, Vol. 576, Issue 1-2
Palladium-Catalyzed Coupling Reactions of Aryl Chlorides
journal, November 2002
- Littke, Adam F.; Fu, Gregory C.
- Angewandte Chemie International Edition, Vol. 41, Issue 22
Carbon−Carbon Coupling Reactions Catalyzed by Heterogeneous Palladium Catalysts
journal, January 2007
- Yin, ; Liebscher, Jürgen
- Chemical Reviews, Vol. 107, Issue 1
Potassium Organotrifluoroborates: New Perspectives in Organic Synthesis
journal, December 2007
- Darses, Sylvain; Genet, Jean-Pierre
- Chemical Reviews, Vol. 108, Issue 1
Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands
journal, November 2008
- Martin, Ruben; Buchwald, Stephen L.
- Accounts of Chemical Research, Vol. 41, Issue 11
N-Heterocyclic Carbenes in Late Transition Metal Catalysis
journal, August 2009
- Díez-González, Silvia; Marion, Nicolas; Nolan, Steven P.
- Chemical Reviews, Vol. 109, Issue 8
The tenth anniversary of Suzuki polycondensation (SPC): Highlight
journal, March 2001
- Schlüter, A. D.
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 39, Issue 10
Nontraditional Step-Growth Polymerization: Transition Metal Coupling
book, April 2003
- Hu, Qiao-Sheng
- Synthetic Methods in Step-Growth Polymers
Suzuki Polycondensation: Polyarylenes à la Carte
journal, May 2009
- Sakamoto, Junji; Rehahn, Matthias; Wegner, Gerhard
- Macromolecular Rapid Communications, Vol. 30, Issue 9-10
Optically Active Polymer and Dendrimer Synthesis and their Use in Asymmetric Catalysis
book, June 2011
- Hu, Qiao-Sheng; Pu, Lin
- Polymeric Chiral Catalyst Design and Chiral Polymer Synthesis
Synthesis of Light-Emitting Conjugated Polymers for Applications in Electroluminescent Devices
journal, March 2009
- Grimsdale, Andrew C.; Leok Chan, Khai; Martin, Rainer E.
- Chemical Reviews, Vol. 109, Issue 3
Synthesis of Conjugated Polymers for Organic Solar Cell Applications
journal, November 2009
- Cheng, Yen-Ju; Yang, Sheng-Hsiung; Hsu, Chain-Shu
- Chemical Reviews, Vol. 109, Issue 11
Molecular and Supramolecular Architectures of Organic Semiconductors for Field-Effect Transistor Devices and Sensors: A Synthetic Chemical Perspective
journal, December 2010
- Operamolla, Alessandra; Farinola, Gianluca M.
- European Journal of Organic Chemistry, Vol. 2011, Issue 3
Integrated Materials Design of Organic Semiconductors for Field-Effect Transistors
journal, April 2013
- Mei, Jianguo; Diao, Ying; Appleton, Anthony L.
- Journal of the American Chemical Society, Vol. 135, Issue 18
Copper(I)-Catalyzed Atom Transfer Radical Polymerization
journal, October 1999
- Patten, Timothy E.; Matyjaszewski, Krzysztof
- Accounts of Chemical Research, Vol. 32, Issue 10
Atom Transfer Radical Polymerization
journal, September 2001
- Matyjaszewski, Krzysztof; Xia, Jianhui
- Chemical Reviews, Vol. 101, Issue 9
“Green” Atom Transfer Radical Polymerization: From Process Design to Preparation of Well-Defined Environmentally Friendly Polymeric Materials
journal, June 2007
- Tsarevsky, Nicolay V.; Matyjaszewski, Krzysztof
- Chemical Reviews, Vol. 107, Issue 6
Atom Transfer Radical Polymerization (ATRP): Current Status and Future Perspectives
journal, April 2012
- Matyjaszewski, Krzysztof
- Macromolecules, Vol. 45, Issue 10, p. 4015-4039
Application of “Transfer-Free” Suzuki Coupling Protocols toward the Synthesis of “Unambiguously Linear” Poly( p -phenylenes)
journal, April 1998
- Goodson, Felix E.; Wallow, Thomas I.; Novak, Bruce M.
- Macromolecules, Vol. 31, Issue 7
Macromolecular Effect: Synthesis of a Ferrocenylmethylphosphine-Containing Polymer as Highly Efficient Ligands for Room-Temperature Palladium(0)-Catalyzed Suzuki Cross-Coupling Reactions of Aryl Chlorides
journal, March 2003
- Hu, Qiao-Sheng; Lu, Yong; Tang, Zhen-Yu
- Journal of the American Chemical Society, Vol. 125, Issue 10
Preparation of poly(fluorene)s usingtrans-bis(dicyclohexylamine)palladium diacetate as a catalyst: Scope and limitations
journal, January 2006
- Kappaun, Stefan; Zelzer, Mischa; Bartl, Karin
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 44, Issue 6
Alternating Block Copolymers Consisting of Oligo(phenylene) and Oligo(ethylene glycol) Units of Defined Length: Synthesis, Thermal Characterization, and Light-Emitting Properties
journal, February 2008
- Hargadon, Matthew T.; Davey, Evan A.; McIntyre, Tia B.
- Macromolecules, Vol. 41, Issue 3
Synthesis and Electroluminescence of New Polyfluorene Copolymers with Phenothiazine Derivative. Their Application in White-Light-Emitting Diodes
journal, April 2008
- Park, Moo-Jin; Lee, Jonghee; Park, Jong-Hwa
- Macromolecules, Vol. 41, Issue 9
Effect of Reaction Parameters on the Molecular Weights of Polymers Formed in a Suzuki Polycondensation
journal, October 2008
- Murage, Joy; Eddy, Jennifer W.; Zimbalist, Jennifer R.
- Macromolecules, Vol. 41, Issue 20
t -Bu 3 P-Coordinated 2-Phenylaniline-Based Palladacycle Complex as a Precatalyst for the Suzuki Cross-Coupling Polymerization of Aryl Dibromides with Aryldiboronic Acids
journal, December 2012
- Zhang, Hong-Hai; Xing, Chun-Hui; Tsemo, Georges Bouobda
- ACS Macro Letters, Vol. 2, Issue 1
Preferential Oxidative Addition in Palladium(0)-Catalyzed Suzuki Cross-Coupling Reactions of Dihaloarenes with Arylboronic Acids
journal, July 2005
- Dong, Cheng-Guo; Hu, Qiao-Sheng
- Journal of the American Chemical Society, Vol. 127, Issue 28
Converting Step-Growth to Chain-Growth Condensation Polymerization
journal, June 2007
- Yokoyama, Akihiro; Yokozawa, Tsutomu
- Macromolecules, Vol. 40, Issue 12
Chain-Growth Condensation Polymerization for the Synthesis of Well-Defined Condensation Polymers and π-Conjugated Polymers
journal, September 2009
- Yokozawa, Tsutomu; Yokoyama, Akihiro
- Chemical Reviews, Vol. 109, Issue 11
Precision Synthesis of n-Type π-Conjugated Polymers in Catalyst-Transfer Condensation Polymerization
journal, June 2012
- Yokozawa, Tsutomu; Nanashima, Yutaka; Ohta, Yoshihiro
- ACS Macro Letters, Vol. 1, Issue 7
Conjugated Polymer Synthesis via Catalyst-Transfer Polycondensation (CTP): Mechanism, Scope, and Applications
journal, September 2013
- Bryan, Zachary J.; McNeil, Anne J.
- Macromolecules, Vol. 46, Issue 21
Chain-Growth Polymerization for the Synthesis of Polyfluorene via Suzuki−Miyaura Coupling Reaction from an Externally Added Initiator Unit
journal, June 2007
- Yokoyama, Akihiro; Suzuki, Hirofumi; Kubota, Yasuhiro
- Journal of the American Chemical Society, Vol. 129, Issue 23
Catalyst-Transfer Suzuki−Miyaura Coupling Polymerization for Precision Synthesis of Poly( p -phenylene)
journal, August 2010
- Yokozawa, Tsutomu; Kohno, Haruhiko; Ohta, Yoshihiro
- Macromolecules, Vol. 43, Issue 17
Precision Synthesis of Poly(3-hexylthiophene) from Catalyst-Transfer Suzuki−Miyaura Coupling Polymerization: Precision Synthesis of Poly(3-hexylthiophene) from Catalyst-Transfer …
journal, April 2011
- Yokozawa, Tsutomu; Suzuki, Ryosuke; Nojima, Masataka
- Macromolecular Rapid Communications, Vol. 32, Issue 11
Chain-Growth Suzuki Polymerization of n-Type Fluorene Copolymers
journal, November 2011
- Elmalem, Einat; Kiriy, Anton; Huck, Wilhelm T. S.
- Macromolecules, Vol. 44, Issue 22
Grafting of Polyfluorene by Surface-Initiated Suzuki Polycondensation
journal, March 2009
- Beryozkina, Tetyana; Boyko, Ksenia; Khanduyeva, Natalya
- Angewandte Chemie International Edition, Vol. 48, Issue 15
In Situ Hetero End-Functionalized Polythiophene and Subsequent “Click” Chemistry With DNA
journal, February 2012
- Lee, Jungkyu K.; Ko, Sangwon; Bao, Zhenan
- Macromolecular Rapid Communications, Vol. 33, Issue 10
Synthesis and Photophysics of Fully π-Conjugated Heterobis-Functionalized Polymeric Molecular Wires via Suzuki Chain-Growth Polymerization
journal, October 2012
- Elmalem, Einat; Biedermann, Frank; Johnson, Kerr
- Journal of the American Chemical Society, Vol. 134, Issue 42
Enhanced Brightness Emission-Tuned Nanoparticles from Heterodifunctional Polyfluorene Building Blocks
journal, January 2013
- Fischer, Christoph S.; Baier, Moritz C.; Mecking, Stefan
- Journal of the American Chemical Society, Vol. 135, Issue 3
Controlled Catalyst Transfer Polycondensation and Surface-Initiated Polymerization of a p -Phenyleneethynylene-Based Monomer
journal, March 2013
- Kang, Songsu; Ono, Robert J.; Bielawski, Christopher W.
- Journal of the American Chemical Society, Vol. 135, Issue 13
Hyperbranched Polymers with a Degree of Branching of 100% Prepared by Catalyst Transfer Suzuki−Miyaura Polycondensation
journal, July 2009
- Huang, Weiguo; Su, Linjie; Bo, Zhishan
- Journal of the American Chemical Society, Vol. 131, Issue 30
A Simple Method to Prepare Head-to-Tail Coupled, Regioregular Poly(3-alkylthiophenes) Using Grignard Metathesis
journal, March 1999
- Loewe, Robert S.; Khersonsky, Sonya M.; McCullough, Richard D.
- Advanced Materials, Vol. 11, Issue 3
Experimental Evidence for the Quasi-“Living” Nature of the Grignard Metathesis Method for the Synthesis of Regioregular Poly(3-alkylthiophenes)
journal, October 2005
- Iovu, Mihaela Corina; Sheina, Elena E.; Gil, Roberto R.
- Macromolecules, Vol. 38, Issue 21
Catalyst-Transfer Polycondensation. Mechanism of Ni-Catalyzed Chain-Growth Polymerization Leading to Well-Defined Poly(3-hexylthiophene)
journal, December 2005
- Miyakoshi, Ryo; Yokoyama, Akihiro; Yokozawa, Tsutomu
- Journal of the American Chemical Society, Vol. 127, Issue 49
Catalyst-Transfer Polycondensation for the Synthesis of Poly( p -phenylene) with Controlled Molecular Weight and Low Polydispersity
journal, December 2006
- Miyakoshi, Ryo; Shimono, Kyohei; Yokoyama, Akihiro
- Journal of the American Chemical Society, Vol. 128, Issue 50
Conductive Polymer Brushes of Regioregular Head-to-Tail Poly(3-alkylthiophenes) via Catalyst-Transfer Surface-Initiated Polycondensation
journal, May 2007
- Senkovskyy, Volodymyr; Khanduyeva, Natalya; Komber, Hartmut
- Journal of the American Chemical Society, Vol. 129, Issue 20
Externally Initiated Regioregular P3HT with Controlled Molecular Weight and Narrow Polydispersity
journal, September 2009
- Bronstein, Hugo A.; Luscombe, Christine K.
- Journal of the American Chemical Society, Vol. 131, Issue 36
Controlled Synthesis of Polyfluorenes via Kumada Catalyst Transfer Polycondensation with Ni(acac) 2 /dppp as the Catalyst
journal, June 2012
- Sui, Aiguo; Shi, Xincui; Wu, Shupeng
- Macromolecules, Vol. 45, Issue 13
Controlled Chain-Growth Kumada Catalyst Transfer Polycondensation of a Conjugated Alternating Copolymer
journal, February 2012
- Ono, Robert J.; Kang, Songsu; Bielawski, Christopher W.
- Macromolecules, Vol. 45, Issue 5
Controlled Pd(0)/ t -Bu 3 P-Catalyzed Suzuki Cross-Coupling Polymerization of AB-Type Monomers with PhPd( t -Bu 3 P)I or Pd 2 (dba) 3 / t -Bu 3 P/ArI as the Initiator
journal, August 2012
- Zhang, Hong-Hai; Xing, Chun-Hui; Hu, Qiao-Sheng
- Journal of the American Chemical Society, Vol. 134, Issue 32
A Pd(AcO)2/t-Bu3P/K3PO4 catalytic system for the control of Suzuki cross-coupling polymerisation
journal, January 2014
- Grisorio, R.; Mastrorilli, P.; Suranna, G. P.
- Polymer Chemistry, Vol. 5, Issue 14
Synthesis, Structure, Theoretical Studies, and Ligand Exchange Reactions of Monomeric, T-Shaped Arylpalladium(II) Halide Complexes with an Additional, Weak Agostic Interaction
journal, January 2004
- Stambuli, James P.; Incarvito, Christopher D.; Bühl, Michael
- Journal of the American Chemical Society, Vol. 126, Issue 4
Synthesis, Characterization, and Reactivity of Monomeric, Arylpalladium Halide Complexes with a Hindered Phosphine as the Only Dative Ligand
journal, August 2002
- Stambuli, James P.; Bühl, Michael; Hartwig, John F.
- Journal of the American Chemical Society, Vol. 124, Issue 32
Reductive Elimination of Aryl Halides from Palladium(II)
journal, February 2001
- Roy, Amy H.; Hartwig, John F.
- Journal of the American Chemical Society, Vol. 123, Issue 6
Directly Observed Reductive Elimination of Aryl Halides from Monomeric Arylpalladium(II) Halide Complexes
journal, November 2003
- Roy, Amy H.; Hartwig, John F.
- Journal of the American Chemical Society, Vol. 125, Issue 46
Versatile Catalysts for the Suzuki Cross-Coupling of Arylboronic Acids with Aryl and Vinyl Halides and Triflates under Mild Conditions
journal, May 2000
- Littke, Adam F.; Dai, Chaoyang; Fu, Gregory C.
- Journal of the American Chemical Society, Vol. 122, Issue 17
Electronic Effects on Reductive Elimination To Form Carbon−Carbon and Carbon−Heteroatom Bonds from Palladium(II) Complexes
journal, March 2007
- Hartwig, John F.
- Inorganic Chemistry, Vol. 46, Issue 6
Random Catalyst Walking along Polymerized Poly(3-hexylthiophene) Chains in Kumada Catalyst-Transfer Polycondensation
journal, June 2010
- Tkachov, Roman; Senkovskyy, Volodymyr; Komber, Hartmut
- Journal of the American Chemical Society, Vol. 132, Issue 22
Chain-Growth Versus Step-Growth Mechanisms for the Suzuki-Heck Polymerisation of Fluorenyldibromides with Potassium Vinyl Trifluoroborate
journal, June 2010
- Grisorio, Roberto; Suranna, Gian Paolo; Mastrorilli, Piero
- Chemistry - A European Journal, Vol. 16, Issue 27
Development of a universal chain-growth polymerization protocol of conjugated polymers: Toward a variety of all-conjugated block-copolymers
journal, October 2011
- Verswyvel, Michiel; Verstappen, Pieter; De Cremer, Lieven
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 49, Issue 24
Chain-Growth Polymerization of Aryl Grignards Initiated by a Stabilized NHC-Pd Precatalyst
journal, April 2012
- Bryan, Zachary J.; Smith, Mitchell L.; McNeil, Anne J.
- Macromolecular Rapid Communications, Vol. 33, Issue 9
Palladium-Mediated Surface-Initiated Kumada Catalyst Polycondensation: A Facile Route Towards Oriented Conjugated Polymers
journal, September 2012
- Huddleston, N. Eric; Sontag, S. Kyle; Bilbrey, Jenna A.
- Macromolecular Rapid Communications, Vol. 33, Issue 24
Synthesis of Hyperbranched Poly( m -phenylene)s via Suzuki Polycondensation of a Branched AB 2 Monomer
journal, November 2010
- Xue, Zheng; Finke, Aaron D.; Moore, Jeffrey S.
- Macromolecules, Vol. 43, Issue 22
Synthesis of novel polyfluorene with defined group in the center using aryl dipalladium complex as an initiator
journal, August 2013
- Fu, Hongwei; Li, Jing; Zhang, Zilong
- Journal of Organometallic Chemistry, Vol. 738
Works referencing / citing this record:
A robust nickel catalyst with an unsymmetrical propyl-bridged diphosphine ligand for catalyst-transfer polymerization
journal, September 2019
- Baker, Matthew A.; Ayuso-Carrillo, Josué; Koos, Martin R. M.
- Polymer Journal, Vol. 52, Issue 1
Palladium-catalyzed carbene coupling of N -tosylhydrazones and arylbromides to synthesize cross-conjugated polymers
journal, January 2019
- Zhou, Qi; Gao, Yunpeng; Xiao, Yiyang
- Polymer Chemistry, Vol. 10, Issue 5
Synthesis of zwitterionic palladium complexes and their application as catalysts in cross-coupling reactions of aryl, heteroaryl and benzyl bromides with organoboron reagents in neat water
journal, January 2017
- Ramakrishna, V.; Dastagiri Reddy, N.
- Dalton Transactions, Vol. 46, Issue 26
Room temperature suzuki cross‐coupling polymerizations of aryl dihalides and aryldiboronic acid/acid esters with t ‐Bu 3 P‐coordinated 2‐phenylaniline‐based palladacycle complex as the precatalyst
journal, June 2019
- Peng, Wei; Dong, Jie; Li, Han‐Bin
- Journal of Polymer Science Part A: Polymer Chemistry, Vol. 57, Issue 14
Intramolecular Catalyst Transfer over Sterically Hindered Arenes in Suzuki Cross‐Coupling Reactions
journal, July 2019
- Zhu, Yu‐Xing; Li, En‐Ci; Shen, Kang
- Asian Journal of Organic Chemistry, Vol. 8, Issue 8
Controlled synthesis of ortho , para -alternating linked polyarenes via catalyst-transfer Suzuki coupling polymerization
journal, January 2018
- Zhang, Hong-Hai; Zhu, Yu-Xing; Wang, Weiyu
- Polymer Chemistry, Vol. 9, Issue 24
A General and Air-tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis
text, January 2019
- Magnin, Guillaume; Clifton, Jamie; Schoenebeck, Franziska
- RWTH Aachen University
Diversifying Cross-Coupling Strategies, Catalysts and Monomers for the Controlled Synthesis of Conjugated Polymers
journal, June 2018
- Baker, Matthew A.; Tsai, Chia-Hua; Noonan, Kevin J. T.
- Chemistry - A European Journal, Vol. 24, Issue 50
A General and Air‐tolerant Strategy to Conjugated Polymers within Seconds under Palladium(I) Dimer Catalysis
journal, July 2019
- Magnin, Guillaume; Clifton, Jamie; Schoenebeck, Franziska
- Angewandte Chemie International Edition, Vol. 58, Issue 30