Emptying and filling a tunnel bronze
Abstract
The classical orthorhombic layered phase of V2O5 has long been regarded as the thermodynamic sink for binary vanadium oxides and has found great practical utility as a result of its open framework and easily accessible redox states. Herein, we exploit a cation-exchange mechanism to synthesize a new stable tunnel-structured polymorph of V2O5 (ζ-V2O5) and demonstrate the subsequent ability of this framework to accommodate Li and Mg ions. The facile extraction and insertion of cations and stabilization of the novel tunnel framework is facilitated by the nanometer-sized dimensions of the materials, which leads to accommodation of strain without amorphization. The topotactic approach demonstrated here indicates not just novel intercalation chemistry accessible at nanoscale dimensions but also suggests a facile synthetic route to ternary vanadium oxide bronzes (MxV2O5) exhibiting intriguing physical properties that range from electronic phase transitions to charge ordering and superconductivity.
- Authors:
-
- TAM
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1170442
- Grant/Contract Number:
- AC02-06CH11357; AC02-98CH10886
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 3; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- ENGLISH
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Marley, Peter M., Abtew, Tesfaye A., Farley, Katie E., Horrocks, Gregory A., Dennis, Robert V., Zhang, Peihong, and Banerjee, Sarbajit. Emptying and filling a tunnel bronze. United States: N. p., 2015.
Web. doi:10.1039/C4SC03748K.
Marley, Peter M., Abtew, Tesfaye A., Farley, Katie E., Horrocks, Gregory A., Dennis, Robert V., Zhang, Peihong, & Banerjee, Sarbajit. Emptying and filling a tunnel bronze. United States. https://doi.org/10.1039/C4SC03748K
Marley, Peter M., Abtew, Tesfaye A., Farley, Katie E., Horrocks, Gregory A., Dennis, Robert V., Zhang, Peihong, and Banerjee, Sarbajit. Tue .
"Emptying and filling a tunnel bronze". United States. https://doi.org/10.1039/C4SC03748K. https://www.osti.gov/servlets/purl/1170442.
@article{osti_1170442,
title = {Emptying and filling a tunnel bronze},
author = {Marley, Peter M. and Abtew, Tesfaye A. and Farley, Katie E. and Horrocks, Gregory A. and Dennis, Robert V. and Zhang, Peihong and Banerjee, Sarbajit},
abstractNote = {The classical orthorhombic layered phase of V2O5 has long been regarded as the thermodynamic sink for binary vanadium oxides and has found great practical utility as a result of its open framework and easily accessible redox states. Herein, we exploit a cation-exchange mechanism to synthesize a new stable tunnel-structured polymorph of V2O5 (ζ-V2O5) and demonstrate the subsequent ability of this framework to accommodate Li and Mg ions. The facile extraction and insertion of cations and stabilization of the novel tunnel framework is facilitated by the nanometer-sized dimensions of the materials, which leads to accommodation of strain without amorphization. The topotactic approach demonstrated here indicates not just novel intercalation chemistry accessible at nanoscale dimensions but also suggests a facile synthetic route to ternary vanadium oxide bronzes (MxV2O5) exhibiting intriguing physical properties that range from electronic phase transitions to charge ordering and superconductivity.},
doi = {10.1039/C4SC03748K},
journal = {Chemical Science},
number = 3,
volume = 6,
place = {United States},
year = {Tue Jan 13 00:00:00 EST 2015},
month = {Tue Jan 13 00:00:00 EST 2015}
}
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