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  1. Benchmarking greenhouse gas emissions from US wastewater treatment for targeted reduction

    Here, in this study, to assess the national climate impact of wastewater treatment and inform decarbonization, we assembled a comprehensive greenhouse gas inventory of 15,863 facilities in the contiguous USA. Considering location and treatment configurations, we modelled on-site CH4, N2O and CO2 production and emissions associated with energy, chemical inputs and solids disposal. Using Monte Carlo simulations, we estimated median national emissions at 47 million tonnes of CO2 equivalent per year, with on-site process CH4 and N2O emissions exceeding current government estimates by 41%. Treatment configurations with anaerobic digesters are responsible for 16 million tonnes of CO2 equivalent per yearmore » of fugitive methane, outweighing benefits achieved through on-site electricity generation. Systems designed for nutrient removal have the highest greenhouse gas emissions intensity, attributable to energy requirements and N2O production, demonstrating current trade-offs between meeting water quality and climate objectives. We analysed key sensitivities and included a geospatial analysis to highlight the scale and distribution of opportunities for reducing life cycle greenhouse gas emissions.« less
  2. Potential Adoption and Benefits of Co-Optimized Multimode Engines and Fuels for U.S. Light-Duty Vehicles

    Exploring a diverse portfolio of technologies for decarbonization is crucial to understanding the potential impacts of different technological solutions and their associated environmental implications. Using high-octane, high-sensitivity biofuel blends in co-optimized multimode engines can increase engine efficiency and reduce vehicle emissions. Here, the multimode engine research focuses on the benefits of light-duty vehicle engines, which can operate in multiple modes depending on the vehicle's load. Low-temperature combustion can improve efficiency and reduce emissions (such as those from oxides of nitrogen and particulate matter) during low-load operation, while spark ignition performance is maintained in high-load operation. These advanced engines can bemore » optimized to run on blends of biobased fuels. This analysis models scenarios for potential market adoption of co-optimized multimode vehicles fueled by three different bioblendstocks: ethanol, isopropanol, and isobutanol. An integrated modeling approach is used to forecast the energy and environmental impacts of the deployment of co-optimized multimode vehicles and fuels in the light-duty sector over the 2020-to-2050 time horizon. The multidisciplinary approach combines vehicle sales modeling, system dynamics modeling of the biorefining industry, and life cycle assessment to estimate the emissions and energy benefits. The models consider market forces such as consumer preferences for vehicle attributes, biofuel supply and demand dynamics subject to biorefinery capacity build-out and bioresource constraints, and forecasted changes to the U.S. bulk energy system over time. Market adoption of co-optimized vehicles is evaluated across a wide parameter space for incremental vehicle cost and engine efficiency improvement. This analysis reveals that the deployment of co-optimized multimode fuels and vehicles results in up to a 5% reduction in annual sector-wide life cycle greenhouse gas (GHG) emissions by 2050, relative to a business-as-usual scenario, but is also indicates environmental trade-offs, such as higher life cycle water-use. Emission benefits could potentially increase beyond 2050, as the new technologies penetrate the market and gain a foothold. Results also show that, under certain circumstances, vehicles with engines co-optimized for use with high-octane, high-sensitivity biofuel blends can be cost-competitive with conventional gasoline, while reducing GHG emissions. Our modeling results indicate that co-optimized multimode fuels and engines can be strategically leveraged in tandem with electrification to decarbonize the light-duty sector. Co-optimized vehicles could play a role in the early years of the time horizon, while electric vehicles (EVs) could become more competitive in the later years, highlighting the complementary benefits of these technologies for GHG reductions.« less
  3. Toward Enhancing Wastewater Treatment with Resource Recovery in Integrated Assessment and Computable General Equilibrium Models

    Sustainable water management is essential to increasing water availability and decreasing water pollution. The wastewater sector is expanding globally and beginning to incorporate technologies that recover nutrients from wastewater. Nutrient recovery increases energy consumption but may reduce the demand for nutrients from virgin sources. We estimate the increase in annual global energy consumption (1,100 million GJ) and greenhouse gas emissions (84 million t CO2e) for wastewater treatment in the year 2030 compared to today’s levels to meet sustainable development goals. To capture these trends, integrated assessment and computable general equilibrium models that address the energy-water nexus must evolve. We reviewedmore » 16 of these models to assess how well they capture wastewater treatment plant energy consumption and GHG emissions. Only three models include biogas production from the wastewater organic content. Four explicitly represent energy demand for wastewater treatment, and eight include explicit representation of wastewater treatment plant greenhouse gas emissions. Of those eight models, six models quantify methane emissions from treatment, five include representation of emissions of nitrous oxide, and two include representation of emissions of carbon dioxide. Our review concludes with proposals to improve these models to better capture the energy-water nexus associated with the evolving wastewater treatment sector.« less
  4. Reducing Economy-Wide Greenhouse Gas Emissions with Electrofuels and Biofuels as the Grid Decarbonizes

    Biofuels and electrofuels have the potential to complement electrification in speeding greenhouse gas emissions reductions, especially in hard-to-decarbonize sectors. Concentrated waste CO2 streams that can be used as a feedstock for electrofuels, however, may become less available as the share of renewable electricity increases and industries undergo decarbonization. Here, we conduct an analysis with detailed treatment of biofuels and electrofuels to probe their role in decarbonizing multiple industrial sectors and transportation. We examine how the changing availability of CO2 could affect electrofuel production and the potential role of direct air capture in stabilizing the supply of CO2. The results indicatemore » that biofuels could fulfill 12% of the total final energy demand across all U.S. sectors in 2050. Using seven industrial source points of CO2 available in 2050, 15,388 PJ of electrofuels could be produced, which amounts to 25% of the total final energy demand. This result holds even upon decarbonization that requires direct air capture to boost the CO2 supply. Biofuels and e-fuels have the potential to reduce economy-wide GHG emissions by 7 and 21% beyond electrification alone. However, electricity consumption and land use grow markedly with decarbonization at scale.« less
  5. Energy, economic, and environmental impacts assessment of co-optimized on-road heavy-duty engines and bio-blendstocks

    Renewable MCCI bio-blendstocks with advantageous properties co-optimized with engines and a ducted fuel injection could reduce engine-out emissions leading to reduced total cost of vehicle ownership and a potential to penetrate the market at scale.
  6. Life-Cycle Assessment of Biochemicals with Clear Near-Term Market Potential

  7. The contribution of biomass and waste resources to decarbonizing transportation and related energy and environmental effects

    Analyzed the extent to which biomass can contribute to the decarbonization of transportation as electrification of the light-duty fleet increases.
  8. Material Flows of Polyurethane in the United States

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