Valence-band hybridization in sulphides

Weinhardt, Lothar; Hauschild, Dirk; Wansorra, Constantin; Steininger, Ralph; Blum, Monika; Yang, Wanli; Heske, Clemens

doi:10.1039/D4CP02894E

Title: Valence-band hybridization in sulphides

Journal Article · Wed Oct 23 04:00:00 UTC 2024 · Physical Chemistry Chemical Physics. PCCP

DOI: https://doi.org/10.1039/D4CP02894E · OSTI ID:2473178

^[1];

^[2]; Steininger, Ralph ^[3]; Blum, Monika ^[4];

^[5]; Heske, Clemens ^[1]

Institute for Photon Science and Synchrotron Radiation (IPS), Karlsruhe Institute of Technology (KIT), Kaiserstraße 12, 76131 Karlsruhe, Germany, Institute for Chemical Technology and Polymer Chemistry (ITCP), Karlsruhe Institute of Technology (KIT), Kaiserstraße 12, 76131, Karlsruhe, Germany, Department of Chemistry and Biochemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Las Vegas, NV 89154-4003, USA
Institute for Photon Science and Synchrotron Radiation (IPS), Karlsruhe Institute of Technology (KIT), Kaiserstraße 12, 76131 Karlsruhe, Germany, Department of Chemistry and Biochemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Las Vegas, NV 89154-4003, USA
Institute for Photon Science and Synchrotron Radiation (IPS), Karlsruhe Institute of Technology (KIT), Kaiserstraße 12, 76131 Karlsruhe, Germany
Department of Chemistry and Biochemistry, University of Nevada, Las Vegas (UNLV), 4505 Maryland Parkway, Las Vegas, NV 89154-4003, USA, Advanced Light Source (ALS), Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA, Chemical Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA
Advanced Light Source (ALS), Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA

Valence-band hybridization in sulphides is studied with X-ray spectroscopy in experiment and theory. The admixture of the “atomic” states to the hybrid bands scales with their inverse energy separation, which we describe by a simple two-state model.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: NONE; AC02-05CH11231

OSTI ID:: 2473178

Journal Information:: Physical Chemistry Chemical Physics. PCCP, Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Issue: 41 Vol. 26; ISSN 1463-9076; ISSN PPCPFQ

Publisher:: Royal Society of Chemistry (RSC)Copyright Statement

Country of Publication:: United Kingdom

Language:: English

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