Evaluation of coated steels in supercritical CO2

Pint, Bruce A.; Pillai, Rishi; Su, Yi‐Feng; Lance, Michael J.; Keiser, James R.

doi:10.1002/maco.202314271

Title: Evaluation of coated steels in supercritical CO₂

Journal Article · 10 February 2024 · Materials and Corrosion

DOI: https://doi.org/10.1002/maco.202314271 · OSTI ID:2438946

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Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

The carburizing supercritical CO₂ (sCO₂) environment limits the use of lower cost steels in the lower temperature (450–650°C) portions of the sCO₂ Brayton cycle because of concerns about internal carburization and embrittlement. Results on a ferritic–martensitic steel and conventional and advanced austenitic steels at 450–650°C in 30 MPa sCO₂ with and without 1% O₂ and 0.1% H₂O additions have indicated that sCO₂ environments will have lower maximum operating temperatures compared to steam plants. Pack Al and Cr coatings were evaluated at 650°C on T91 and 316H substrates and showed some benefit for up to 2000 h at 650°C, especially without impurities. However, characterization indicated Al₂O₃ was not formed and Cr-rich carbides formed in the Cr coatings. With the addition of impurities in the sCO₂, the coatings were less protective at 650°C. Subsequent exposures at 600°C in sCO₂ showed similar behavior. Postexposure evaluations included measuring the bulk C content and room temperature tensile properties. Finally, improvements were indicated but the tensile results were complicated by the high temperature pack coating process affecting the substrate properties.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; USDOE Office of Fossil Energy and Carbon Management (FECM); USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 2438946

Journal Information:: Materials and Corrosion, Journal Name: Materials and Corrosion Vol. 75; ISSN 0947-5117

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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36 MATERIALS SCIENCE
coatings
impurities
pack cementation
steels
supercritical carbon dioxide

Title: Evaluation of coated steels in supercritical CO2

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References (42)

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Related Subjects

Title: Evaluation of coated steels in supercritical CO₂