Emergent Ferromagnetism with Fermi-Liquid Behavior in Proton Intercalated
Abstract
The evolution between Fermi-liquid and non-Fermi-liquid states in correlated electron systems has been a central subject in condensed matter physics because of the coupled intriguing magnetic and electronic states. An effective pathway to explore the nature of non-Fermi-liquid behavior is to approach its phase boundary. In this work, we report a crossover from non-Fermi-liquid to Fermi-liquid state in metallic CaRuO3 through ionic liquid gating induced protonation with electric field. This electronic transition subsequently triggers a reversible magnetic transition with the emergence of an exotic ferromagnetic state from this paramagnetic compound. Our theoretical analysis reveals that hydrogen incorporation plays a critical role in both the electronic and magnetic phase transitions via structural distortion and electron doping. These observations not only help understand the correlated magnetic and electronic transitions in perovskite ruthenate systems, but also provide novel pathways to design electronic phases in correlated materials.
- Authors:
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China (NSFC); National Basic Research Program of China; Engineering and Physical Sciences Research Council (EPSRC)
- OSTI Identifier:
- 2325348
- Alternate Identifier(s):
- OSTI ID: 1782050
- Grant/Contract Number:
- AC05-00OR22725; 51788104; 51872155; U1632272; 11521404; 11904196; 2016YFA0301004; EP/N016718/1
- Resource Type:
- Published Article
- Journal Name:
- Physical Review. X
- Additional Journal Information:
- Journal Name: Physical Review. X Journal Volume: 11 Journal Issue: 2; Journal ID: ISSN 2160-3308
- Publisher:
- American Physical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; magnetic phase transitions; thin films; transition-metal oxides; density functional theory; dynamical mean field theory; Hall bar; resistivity measurements; x-ray diffraction
Citation Formats
Shen, Shengchun, Li, Zhuolu, Tian, Zijun, Luo, Weidong, Okamoto, Satoshi, and Yu, Pu. Emergent Ferromagnetism with Fermi-Liquid Behavior in Proton Intercalated CaRuO 3. United States: N. p., 2021.
Web. doi:10.1103/PhysRevX.11.021018.
Shen, Shengchun, Li, Zhuolu, Tian, Zijun, Luo, Weidong, Okamoto, Satoshi, & Yu, Pu. Emergent Ferromagnetism with Fermi-Liquid Behavior in Proton Intercalated CaRuO 3. United States. https://doi.org/10.1103/PhysRevX.11.021018
Shen, Shengchun, Li, Zhuolu, Tian, Zijun, Luo, Weidong, Okamoto, Satoshi, and Yu, Pu. Wed .
"Emergent Ferromagnetism with Fermi-Liquid Behavior in Proton Intercalated CaRuO 3". United States. https://doi.org/10.1103/PhysRevX.11.021018.
@article{osti_2325348,
title = {Emergent Ferromagnetism with Fermi-Liquid Behavior in Proton Intercalated CaRuO 3},
author = {Shen, Shengchun and Li, Zhuolu and Tian, Zijun and Luo, Weidong and Okamoto, Satoshi and Yu, Pu},
abstractNote = {The evolution between Fermi-liquid and non-Fermi-liquid states in correlated electron systems has been a central subject in condensed matter physics because of the coupled intriguing magnetic and electronic states. An effective pathway to explore the nature of non-Fermi-liquid behavior is to approach its phase boundary. In this work, we report a crossover from non-Fermi-liquid to Fermi-liquid state in metallic CaRuO3 through ionic liquid gating induced protonation with electric field. This electronic transition subsequently triggers a reversible magnetic transition with the emergence of an exotic ferromagnetic state from this paramagnetic compound. Our theoretical analysis reveals that hydrogen incorporation plays a critical role in both the electronic and magnetic phase transitions via structural distortion and electron doping. These observations not only help understand the correlated magnetic and electronic transitions in perovskite ruthenate systems, but also provide novel pathways to design electronic phases in correlated materials.},
doi = {10.1103/PhysRevX.11.021018},
journal = {Physical Review. X},
number = 2,
volume = 11,
place = {United States},
year = {Wed Apr 21 00:00:00 EDT 2021},
month = {Wed Apr 21 00:00:00 EDT 2021}
}
https://doi.org/10.1103/PhysRevX.11.021018
Works referenced in this record:
Itinerant-to-localized electron transition in and
journal, December 1996
- Cao, G.; McCall, S.; Bolivar, J.
- Physical Review B, Vol. 54, Issue 21
Reversible manipulation of the magnetic state in SrRuO3 through electric-field controlled proton evolution
journal, January 2020
- Li, Zhuolu; Shen, Shengchun; Tian, Zijun
- Nature Communications, Vol. 11, Issue 1
Magnetic Properties of SrRuO 3 and CaRuO 3
journal, February 1968
- Longo, J. M.; Raccah, P. M.; Goodenough, J. B.
- Journal of Applied Physics, Vol. 39, Issue 2
Electronic structure and magnetism in Ru-based perovskites
journal, August 1997
- Mazin, I. I.; Singh, D. J.
- Physical Review B, Vol. 56, Issue 5
XXXIII. Magnetism and molecular structure
journal, February 1927
- Stoner, Edmund C.
- The London, Edinburgh, and Dublin Philosophical Magazine and Journal of Science, Vol. 3, Issue 14
Non-Fermi-liquid behavior in - and -electron metals
journal, October 2001
- Stewart, G. R.
- Reviews of Modern Physics, Vol. 73, Issue 4
Non-Fermi-liquid nature of the normal state of itinerant-electron ferromagnets
journal, November 2001
- Pfleiderer, C.; Julian, S. R.; Lonzarich, G. G.
- Nature, Vol. 414, Issue 6862
Non-Fermi liquids in oxide heterostructures
journal, May 2018
- Stemmer, Susanne; Allen, S. James
- Reports on Progress in Physics, Vol. 81, Issue 6
Disorder-induced ferromagnetism in
journal, March 2001
- He, T.; Cava, R. J.
- Physical Review B, Vol. 63, Issue 17
Breakdown of Fermi-liquid theory in a copper-oxide superconductor
journal, December 2001
- Hill, R. W.; Proust, Cyril; Taillefer, Louis
- Nature, Vol. 414, Issue 6865
Recent Developments in Non-Fermi Liquid Theory
journal, March 2018
- Lee, Sung-Sik
- Annual Review of Condensed Matter Physics, Vol. 9, Issue 1
The effect of Ru-site dopants on the magnetic properties of CaRuO 3
journal, August 2001
- He, T.; Cava, R. J.
- Journal of Physics: Condensed Matter, Vol. 13, Issue 36
Fermi-liquid instabilities at magnetic quantum phase transitions
journal, August 2007
- Löhneysen, Hilbert v.; Rosch, Achim; Vojta, Matthias
- Reviews of Modern Physics, Vol. 79, Issue 3
Nature of the ferromagnetism induced by nonmagnetic substitutions on the Ru site of
journal, March 2006
- Hardy, V.; Raveau, B.; Retoux, R.
- Physical Review B, Vol. 73, Issue 9
NMR Observation of Universal Behavior of Ferromagnetic Spin Fluctuations in the Itinerant Magnetic System
journal, November 1999
- Yoshimura, K.; Imai, T.; Kiyama, T.
- Physical Review Letters, Vol. 83, Issue 21
Magnetic and Mössbauer studies of and Fe)
journal, August 2002
- Felner, I.; Asaf, U.; Nowik, I.
- Physical Review B, Vol. 66, Issue 5
Structure, physical properties, and applications of thin films
journal, March 2012
- Koster, Gertjan; Klein, Lior; Siemons, Wolter
- Reviews of Modern Physics, Vol. 84, Issue 1
Non-Fermi-liquid behavior in single-crystal CaRuO3: Comparison to ferromagnetic SrRuO3
journal, November 2008
- Cao, G.; Korneta, O.; Chikara, S.
- Solid State Communications, Vol. 148, Issue 7-8
Non-uniform Magnetic System Driven by Non-magnetic Ion Substitution in CaRu 1− x Sc x O 3 : Two-Component Analysis
journal, January 2015
- Yamamoto, Takafumi D.; Okazaki, Ryuji; Taniguchi, Hiroki
- Journal of the Physical Society of Japan, Vol. 84, Issue 1
Strain Doping: Reversible Single-Axis Control of a Complex Oxide Lattice via Helium Implantation
journal, June 2015
- Guo, Hangwen; Dong, Shuai; Rack, Philip D.
- Physical Review Letters, Vol. 114, Issue 25
Ferromagnetic CaRuO3
journal, January 2014
- Tripathi, Shivendra; Rana, Rakesh; Kumar, Sanjay
- Scientific Reports, Vol. 4, Issue 1
Possible non-Fermi-liquid behavior of
journal, July 1999
- Klein, L.; Antognazza, L.; Geballe, T. H.
- Physical Review B, Vol. 60, Issue 3
Superconductivity in a layered perovskite without copper
journal, December 1994
- Maeno, Y.; Hashimoto, H.; Yoshida, K.
- Nature, Vol. 372, Issue 6506
Evolution of transport and magnetic properties near the ferromagnetic quantum critical point in the series
journal, October 2004
- Khalifah, P.; Ohkubo, I.; Christen, H. M.
- Physical Review B, Vol. 70, Issue 13
Thermal, magnetic, and transport properties of single-crystal
journal, July 1997
- Cao, G.; McCall, S.; Shepard, M.
- Physical Review B, Vol. 56, Issue 1
Orbital Non-Fermi-Liquid Behavior in Cubic Ruthenates
journal, March 2008
- Laad, M. S.; Bradarić, I.; Kusmartsev, F. V.
- Physical Review Letters, Vol. 100, Issue 9
Dependence of magnetism on GdFeO distortion in the system RuO ( Sr, Ca)
journal, January 2011
- Middey, Srimanta; Mahadevan, Priya; Sarma, D. D.
- Physical Review B, Vol. 83, Issue 1
Magnetic properties of CaRu1−xFexO3
journal, April 2006
- Mizusaki, S.; Taniguchi, T.; Okada, N.
- Journal of Applied Physics, Vol. 99, Issue 8
Formation of a topological non-Fermi liquid in MnSi
journal, May 2013
- Ritz, R.; Halder, M.; Wagner, M.
- Nature, Vol. 497, Issue 7448
Coexistence of superconductivity and ferromagnetism in the d-band metal ZrZn2
journal, July 2001
- Pfleiderer, C.; Uhlarz, M.; Hayden, S. M.
- Nature, Vol. 412, Issue 6842
Ferromagnetism induced by chromium substitution in the perovskite
journal, July 2006
- Maignan, A.; Raveau, B.; Hardy, V.
- Physical Review B, Vol. 74, Issue 2
Tuning bad metal and non-Fermi liquid behavior in a Mott material: Rare-earth nickelate thin films
journal, November 2015
- Mikheev, Evgeny; Hauser, Adam J.; Himmetoglu, Burak
- Science Advances, Vol. 1, Issue 10
Advances in the Physics of High-Temperature Superconductivity
journal, April 2000
- Orenstein, J.
- Science, Vol. 288, Issue 5465
Ferromagnetism and metallicity in the CaMn1−xRuxO3 perovskites: a highly inhomogeneous system
journal, January 2001
- Maignan, A.; Martin, C.; Hervieu, M.
- Solid State Communications, Vol. 117, Issue 6
Electric‐Field‐Controlled Phase Transformation in WO 3 Thin Films through Hydrogen Evolution
journal, October 2017
- Wang, Meng; Shen, Shengchun; Ni, Jinyang
- Advanced Materials, Vol. 29, Issue 46
Fermi-liquid breakdown in the paramagnetic phase of a pure metal
journal, October 2003
- Doiron-Leyraud, N.; Walker, I. R.; Taillefer, L.
- Nature, Vol. 425, Issue 6958
Manipulating magnetic properties of and with epitaxial and uniaxial strains
journal, June 2008
- Zayak, A. T.; Huang, X.; Neaton, J. B.
- Physical Review B, Vol. 77, Issue 21
Itinerant-to-localized electron transition in perovskite CaRu1−xRhxO3
journal, April 1997
- Cao, G.; Freibert, F.; Crow, J. E.
- Journal of Applied Physics, Vol. 81, Issue 8
Electric-field control of tri-state phase transformation with a selective dual-ion switch
journal, May 2017
- Lu, Nianpeng; Zhang, Pengfei; Zhang, Qinghua
- Nature, Vol. 546, Issue 7656
Spin Freezing Transition and Non-Fermi-Liquid Self-Energy in a Three-Orbital Model
journal, October 2008
- Werner, Philipp; Gull, Emanuel; Troyer, Matthias
- Physical Review Letters, Vol. 101, Issue 16
Electronic correlations, magnetism, and Hund's rule coupling in the ruthenium perovskites and
journal, May 2015
- Dang, Hung T.; Mravlje, Jernej; Georges, Antoine
- Physical Review B, Vol. 91, Issue 19
Ferromagnetic quantum phase transition in Sr 1− x Ca x RuO 3 thin films: Ferromagnetic quantum phase transition in Sr 1− x Ca x RuO 3 thin films
journal, February 2010
- Schneider, M.; Moshnyaga, V.; Gegenwart, P.
- physica status solidi (b), Vol. 247, Issue 3
Strange-metal behaviour in a pure ferromagnetic Kondo lattice
journal, March 2020
- Shen, Bin; Zhang, Yongjun; Komijani, Yashar
- Nature, Vol. 579, Issue 7797
Non-Fermi-liquid behaviour in La4Ru6O19
journal, June 2001
- Khalifah, P.; Nelson, K. D.; Jin, R.
- Nature, Vol. 411, Issue 6838
Magnetic Field-Tuned Quantum Criticality in the Metallic Ruthenate Sr3Ru2O7
journal, October 2001
- Grigera, S. A.
- Science, Vol. 294, Issue 5541
Anomalous Hall effect
journal, May 2010
- Nagaosa, Naoto; Sinova, Jairo; Onoda, Shigeki
- Reviews of Modern Physics, Vol. 82, Issue 2