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Giant Apparent Optical Circular Dichroism in Thin Films of Bismuth‐Based Hybrid Organic–Inorganic Metal Halide Semiconductor Through Preferred Orientation
Abstract
Abstract Introducing chirality into organic/inorganic hybrid materials can impart chiroptical properties such as circular dichroism. The ability to tune chiroptical properties in self‐assembled materials can have important implications for spintronic and optoelectronic applications. Here, a chiral organic cation, ( R/S )‐4‐methoxy‐α‐methylbenzylammonium, is incorporated to synthesize the bismuth‐based hybrid organic–inorganic metal halide semiconductor, ( R/S ‐MeOMePMA)BiI 4 . Thin films of this Bi‐based compound demonstrate large chiroptical responses, with circular dichroism anisotropy (g CD ) values up to ≈0.1, close to the highest value observed in another chiral metal‐halide semiconductor, ( R ‐MBA 2 CuCl 4 ). Detailed investigation reveals that this large g CD in ( R/S ‐MeOMePMA)BiI 4 is caused by the apparent CD effect. Careful selection of deposition conditions and the concomitant thin‐film orientation enables the control of g CD , with maximum value observed when its thin film has a well‐crystallized preferred (001) orientation parallel to the substrate. The results support a growing body of evidence that low symmetry plays an important role in achieving unusually large g CD in these chiral metal–halide materials and provides design rules for achieving large chiroptical response via morphology control.
- Authors:
-
[1];
[2];
[3];
[4];
[5];
[6];
[1]
- Department of Chemistry University of North Carolina at Chapel Hill Chapel Hill NC 27599 USA
- University program in Materials Science and Engineering Duke University Durham North Carolina 27708 USA, Department of Mechanical Engineering and Materials Science Duke University Durham NC 27708 USA
- Department of Mechanical Engineering and Materials Science Duke University Durham NC 27708 USA, Department of Chemistry Duke University Durham NC 27708 USA
- Center for Hybrid Organic Inorganic Semiconductors for Energy Golden CO 80401 USA
- Materials, Chemistry, and Computation Science Directorate National Renewable Energy Laboratory Golden CO 80401 USA, Department of Physics Colorado School of Mines Golden CO 80401 USA
- Materials, Chemistry, and Computation Science Directorate National Renewable Energy Laboratory Golden CO 80401 USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 2282205
- Resource Type:
- Publisher's Accepted Manuscript
- Journal Name:
- Advanced Optical Materials
- Additional Journal Information:
- Journal Name: Advanced Optical Materials; Journal ID: ISSN 2195-1071
- Publisher:
- Wiley Blackwell (John Wiley & Sons)
- Country of Publication:
- Germany
- Language:
- English
Citation Formats
Yan, Liang, Xie, Yi, Mitzi, David B., Sercel, Peter C., Phillips, Alan J., Blackburn, Jeffrey L., and You, Wei. Giant Apparent Optical Circular Dichroism in Thin Films of Bismuth‐Based Hybrid Organic–Inorganic Metal Halide Semiconductor Through Preferred Orientation. Germany: N. p., 2024.
Web. doi:10.1002/adom.202302766.
Yan, Liang, Xie, Yi, Mitzi, David B., Sercel, Peter C., Phillips, Alan J., Blackburn, Jeffrey L., & You, Wei. Giant Apparent Optical Circular Dichroism in Thin Films of Bismuth‐Based Hybrid Organic–Inorganic Metal Halide Semiconductor Through Preferred Orientation. Germany. https://doi.org/10.1002/adom.202302766
Yan, Liang, Xie, Yi, Mitzi, David B., Sercel, Peter C., Phillips, Alan J., Blackburn, Jeffrey L., and You, Wei. Tue .
"Giant Apparent Optical Circular Dichroism in Thin Films of Bismuth‐Based Hybrid Organic–Inorganic Metal Halide Semiconductor Through Preferred Orientation". Germany. https://doi.org/10.1002/adom.202302766.
@article{osti_2282205,
title = {Giant Apparent Optical Circular Dichroism in Thin Films of Bismuth‐Based Hybrid Organic–Inorganic Metal Halide Semiconductor Through Preferred Orientation},
author = {Yan, Liang and Xie, Yi and Mitzi, David B. and Sercel, Peter C. and Phillips, Alan J. and Blackburn, Jeffrey L. and You, Wei},
abstractNote = {Abstract Introducing chirality into organic/inorganic hybrid materials can impart chiroptical properties such as circular dichroism. The ability to tune chiroptical properties in self‐assembled materials can have important implications for spintronic and optoelectronic applications. Here, a chiral organic cation, ( R/S )‐4‐methoxy‐α‐methylbenzylammonium, is incorporated to synthesize the bismuth‐based hybrid organic–inorganic metal halide semiconductor, ( R/S ‐MeOMePMA)BiI 4 . Thin films of this Bi‐based compound demonstrate large chiroptical responses, with circular dichroism anisotropy (g CD ) values up to ≈0.1, close to the highest value observed in another chiral metal‐halide semiconductor, ( R ‐MBA 2 CuCl 4 ). Detailed investigation reveals that this large g CD in ( R/S ‐MeOMePMA)BiI 4 is caused by the apparent CD effect. Careful selection of deposition conditions and the concomitant thin‐film orientation enables the control of g CD , with maximum value observed when its thin film has a well‐crystallized preferred (001) orientation parallel to the substrate. The results support a growing body of evidence that low symmetry plays an important role in achieving unusually large g CD in these chiral metal–halide materials and provides design rules for achieving large chiroptical response via morphology control.},
doi = {10.1002/adom.202302766},
journal = {Advanced Optical Materials},
number = ,
volume = ,
place = {Germany},
year = {Tue Jan 16 00:00:00 EST 2024},
month = {Tue Jan 16 00:00:00 EST 2024}
}
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