Giant Apparent Optical Circular Dichroism in Thin Films of Bismuth-Based Hybrid Organic-Inorganic Metal Halide Semiconductor Through Preferred Orientation

Yan, Liang; Xie, Yi; Mitzi, David B.; Sercel, Peter C.; Phillips, Alan J.; Blackburn, Jeffrey L.; You, Wei

doi:10.1002/adom.202302766

Title: Giant Apparent Optical Circular Dichroism in Thin Films of Bismuth-Based Hybrid Organic-Inorganic Metal Halide Semiconductor Through Preferred Orientation

Journal Article · Tue Jan 16 00:00:00 EST 2024 · Advanced Optical Materials

DOI:https://doi.org/10.1002/adom.202302766· OSTI ID:2305657

Yan, Liang; Xie, Yi; Mitzi, David B.; Sercel, Peter C.; Phillips, Alan J.;

; You, Wei

Introducing chirality into organic/inorganic hybrid materials can impart chiroptical properties such as circular dichroism. The ability to tune chiroptical properties in self-assembled materials can have important implications for spintronic and optoelectronic applications. Here, a chiral organic cation, (R/S)-4-methoxy-a-methylbenzylammonium, is incorporated to synthesize the bismuth-based hybrid organic-inorganic metal halide semiconductor, (R/S-MeOMePMA)BiI4. Thin films of this Bi-based compound demonstrate large chiroptical responses, with circular dichroism anisotropy (gCD) values up to ˜0.1, close to the highest value observed in another chiral metal-halide semiconductor, (R-MBA2CuCl4). Detailed investigation reveals that this large gCD in (R/S-MeOMePMA)BiI4 is caused by the apparent CD effect. Careful selection of deposition conditions and the concomitant thin-film orientation enables the control of gCD, with maximum value observed when its thin film has a well-crystallized preferred (001) orientation parallel to the substrate. The results support a growing body of evidence that low symmetry plays an important role in achieving unusually large gCD in these chiral metal-halide materials and provides design rules for achieving large chiroptical response via morphology control.

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Research Organization:: National Renewable Energy Laboratory (NREL), Golden, CO (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC36-08GO28308

OSTI ID:: 2305657

Report Number(s):: NREL/JA-5K00-88833; MainId:89612; UUID:244ecb0e-811d-49f4-a320-fb6223bd0b4f; MainAdminId:71828

Journal Information:: Advanced Optical Materials, Journal Name: Advanced Optical Materials

Country of Publication:: United States

Language:: English

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Title: Giant Apparent Optical Circular Dichroism in Thin Films of Bismuth-Based Hybrid Organic-Inorganic Metal Halide Semiconductor Through Preferred Orientation

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