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Title: Managing potential environmental and human health risks of lead halide perovskite photovoltaic modules

Abstract

Perovskite solar cells (PSCs) are emerging photovoltaic (PV) technologies capable of matching power conversion efficiencies (PCEs) of current PV technologies in the market at lower manufacturing costs, making perovskite solar modules (PSMs) cost competitive if manufactured at scale and perform with minimal degradation. PSCs with the highest PCEs, to date, are lead halide perovskites. Lead presents potential environmental and human health risks if PSMs are to be commercialized, as the lead in PSMs are more soluble in water compared to other PV technologies. Therefore, prior to commercialization of PSMs, it is important to highlight, identify, and establish the potential environmental and human health risks of PSMs as well as develop methods for assessing the potential risks. Here, we identify and discuss a variety of international standards, U.S. regulations, and permits applicable to PSM deployment that relate to the potential environmental and human health risks associated with PSMs. The potential risks for lead and other hazardous material exposures to humans and the environment are outlined which include water quality, air quality, human health, wildlife, land use, and soil contamination, followed by examples of how developers of other PV technologies have navigated human health and environmental risks previously. Potential experimentation, methodology, andmore » research efforts are proposed to elucidate and characterize potential lead leaching risks and concerns pertaining to fires, in-field module damage, and sampling and leach testing of PSMs at end of life. Lastly, lower technology readiness level solutions to mitigate lead leaching, currently being explored for PSMs, are discussed. PSMs have the potential to become a cost competitive PV technology for the solar industry and taking steps toward understanding, identifying, and creating solutions to mitigate potential environmental and human health risks will aid in improving their commercial viability.« less

Authors:
ORCiD logo; ; ; ORCiD logo
Publication Date:
Research Org.:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Org.:
USDOE National Nuclear Security Administration (NNSA); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
OSTI Identifier:
2282200
Alternate Identifier(s):
OSTI ID: 2311243
Report Number(s):
SAND-2024-00691J
Journal ID: ISSN 0038-092X; S0038092X24000318; 112337; PII: S0038092X24000318
Grant/Contract Number:  
38050; NA0003525
Resource Type:
Published Article
Journal Name:
Solar Energy
Additional Journal Information:
Journal Name: Solar Energy Journal Volume: 269 Journal Issue: C; Journal ID: ISSN 0038-092X
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
14 SOLAR ENERGY; perovskite solar cells; perovskite solar modules; PV environmental and human health risks; perovskite PV end of life management

Citation Formats

Rencheck, Mitchell L., Libby, Cara, Montgomery, Angelique, and Stein, Joshua S. Managing potential environmental and human health risks of lead halide perovskite photovoltaic modules. United States: N. p., 2024. Web. doi:10.1016/j.solener.2024.112337.
Rencheck, Mitchell L., Libby, Cara, Montgomery, Angelique, & Stein, Joshua S. Managing potential environmental and human health risks of lead halide perovskite photovoltaic modules. United States. https://doi.org/10.1016/j.solener.2024.112337
Rencheck, Mitchell L., Libby, Cara, Montgomery, Angelique, and Stein, Joshua S. Thu . "Managing potential environmental and human health risks of lead halide perovskite photovoltaic modules". United States. https://doi.org/10.1016/j.solener.2024.112337.
@article{osti_2282200,
title = {Managing potential environmental and human health risks of lead halide perovskite photovoltaic modules},
author = {Rencheck, Mitchell L. and Libby, Cara and Montgomery, Angelique and Stein, Joshua S.},
abstractNote = {Perovskite solar cells (PSCs) are emerging photovoltaic (PV) technologies capable of matching power conversion efficiencies (PCEs) of current PV technologies in the market at lower manufacturing costs, making perovskite solar modules (PSMs) cost competitive if manufactured at scale and perform with minimal degradation. PSCs with the highest PCEs, to date, are lead halide perovskites. Lead presents potential environmental and human health risks if PSMs are to be commercialized, as the lead in PSMs are more soluble in water compared to other PV technologies. Therefore, prior to commercialization of PSMs, it is important to highlight, identify, and establish the potential environmental and human health risks of PSMs as well as develop methods for assessing the potential risks. Here, we identify and discuss a variety of international standards, U.S. regulations, and permits applicable to PSM deployment that relate to the potential environmental and human health risks associated with PSMs. The potential risks for lead and other hazardous material exposures to humans and the environment are outlined which include water quality, air quality, human health, wildlife, land use, and soil contamination, followed by examples of how developers of other PV technologies have navigated human health and environmental risks previously. Potential experimentation, methodology, and research efforts are proposed to elucidate and characterize potential lead leaching risks and concerns pertaining to fires, in-field module damage, and sampling and leach testing of PSMs at end of life. Lastly, lower technology readiness level solutions to mitigate lead leaching, currently being explored for PSMs, are discussed. PSMs have the potential to become a cost competitive PV technology for the solar industry and taking steps toward understanding, identifying, and creating solutions to mitigate potential environmental and human health risks will aid in improving their commercial viability.},
doi = {10.1016/j.solener.2024.112337},
journal = {Solar Energy},
number = C,
volume = 269,
place = {United States},
year = {Thu Feb 01 00:00:00 EST 2024},
month = {Thu Feb 01 00:00:00 EST 2024}
}

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