Irreparable Interphase Chemistry Degradation Induced by Temperature Pulse in Lithium‐Ion Batteries

Cui, Zehao; Guo, Zezhou; Manthiram, Arumugam

doi:10.1002/ange.202313437

Title: Irreparable Interphase Chemistry Degradation Induced by Temperature Pulse in Lithium‐Ion Batteries

Journal Article · 15 November 2023 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.202313437 · OSTI ID:2229158

Cui, Zehao ^[1]; Guo, Zezhou ^[1];

^[1]

Materials Science &, Engineering Program and Texas Materials Institute The University of Texas at Austin Austin TX 78712 USA

Abstract While it is widely recognized that the operating temperature significantly affects the energy density and cycle life of lithium‐ion batteries, the consequence of electrode‐electrolyte interphase chemistry to sudden environmental temperature changes remains inadequately understood. Here, we systematically investigate the effects of a temperature pulse (T pulse) on the electrochemical performance of LiNi _0.8 Mn _0.1 Co _0.1 O ₂ (NMC811) pouch full cells. By utilizing advanced characterization tools, such as time‐of‐flight secondary‐ion mass spectrometry, we reveal that the T pulse can lead to an irreversible degradation of cathode‐electrolyte interphase chemistry and architecture. Despite negligible immediate impacts on the solid‐electrolyte interphase (SEI) on graphite anode, aggregated cathode‐to‐anode chemical crossover gradually degrades the SEI by catalyzing electrolyte reduction decomposition and inducing metallic dead Li formation because of insufficient cathode passivation after the T pulse. Consequently, pouch cells subjected to the T pulse show an inferior cycle stability to those free of the T pulse. This work unveils the effects of sudden temperature changes on the interphase chemistry and cell performance, emphasizing the importance of a proper temperature management in assessing performance.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: EE0007762

OSTI ID:: 2229158

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Vol. 135 Journal Issue: 50; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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