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Title: Current status and future directions of all-solid-state batteries with lithium metal anodes, sulfide electrolytes, and layered transition metal oxide cathodes

Abstract

All-solid-state batteries (ASSBs) offer great promise as a next-generation energy storage technology with higher energy density, wider operating temperature range, and improved safety for electric vehicles. ASSBs employing lithium metal anodes (Li), sulfide-based solid-state electrolytes (SSE), and Ni-rich layered transition metal oxide cathodes (LiMO2, M = Ni, Mn, Co, Al) are particularly promising due to its superior electrochemical performance compared to other solid-electrolyte systems. However, the battery cycle life at high cathode mass loading and high current is still limited because the failure mechanism is not fully understood. Lithium dendrite growth at the anode or inside a solid electrolyte still represents as a serious risk of cell failure. Interfacial resistance increases attributed to electrolyte decomposition and interfacial void formation at both cathode–electrolyte and anode–electrolyte interfaces lead to gradual capacity fading. In this Review, we present the fundamental challenges and recent scientific understandings of each component in ASSBs. The novel diagnostic tools for these components, especially the interfaces buried under the surface that are often hard for characterization are mainly examined. Lastly, we offer a perspective for future research directions. We hope this Review will provide a timely snapshot of state-of-the-art research progress in ASSBs to accelerate the development of ASSBs.

Authors:
 [1];  [2];  [2];  [1];  [1];  [1];  [3];  [3];  [1];  [3];  [1];  [1]
+ Show Author Affiliations
  1. University of Houston, TX (United States)
  2. Zhejiang University of Technology, Hangzhou (China)
  3. Rice University, Houston, TX (United States)
Publication Date:
Research Org.:
Univ. of Houston, TX (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); National Natural Science Foundation of China (NSFC); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1985463
Alternate Identifier(s):
OSTI ID: 1782078; OSTI ID: 1787162
Grant/Contract Number:  
EE0008864; 21972127; U20A20253
Resource Type:
Accepted Manuscript
Journal Name:
Nano Energy
Additional Journal Information:
Journal Volume: 87; Journal ID: ISSN 2211-2855
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; All-solid-state battery; Lithium metal anode; Sulfide electrolyte; Layered ternary oxide cathode

Citation Formats

Wu, Chaoshan, Lou, Jiatao, Zhang, Jun, Chen, Zhaoyang, Kakar, Akshay, Emley, Benjamin, Ai, Qing, Guo, Hua, Liang, Yanliang, Lou, Jun, Yao, Yan, and Fan, Zheng. Current status and future directions of all-solid-state batteries with lithium metal anodes, sulfide electrolytes, and layered transition metal oxide cathodes. United States: N. p., 2021. Web. doi:10.1016/j.nanoen.2021.106081.
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Wu, Chaoshan, Lou, Jiatao, Zhang, Jun, Chen, Zhaoyang, Kakar, Akshay, Emley, Benjamin, Ai, Qing, Guo, Hua, Liang, Yanliang, Lou, Jun, Yao, Yan, & Fan, Zheng. Current status and future directions of all-solid-state batteries with lithium metal anodes, sulfide electrolytes, and layered transition metal oxide cathodes. United States. https://doi.org/10.1016/j.nanoen.2021.106081
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Wu, Chaoshan, Lou, Jiatao, Zhang, Jun, Chen, Zhaoyang, Kakar, Akshay, Emley, Benjamin, Ai, Qing, Guo, Hua, Liang, Yanliang, Lou, Jun, Yao, Yan, and Fan, Zheng. Sat . "Current status and future directions of all-solid-state batteries with lithium metal anodes, sulfide electrolytes, and layered transition metal oxide cathodes". United States. https://doi.org/10.1016/j.nanoen.2021.106081. https://www.osti.gov/servlets/purl/1985463.
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@article{osti_1985463,
title = {Current status and future directions of all-solid-state batteries with lithium metal anodes, sulfide electrolytes, and layered transition metal oxide cathodes},
author = {Wu, Chaoshan and Lou, Jiatao and Zhang, Jun and Chen, Zhaoyang and Kakar, Akshay and Emley, Benjamin and Ai, Qing and Guo, Hua and Liang, Yanliang and Lou, Jun and Yao, Yan and Fan, Zheng},
abstractNote = {All-solid-state batteries (ASSBs) offer great promise as a next-generation energy storage technology with higher energy density, wider operating temperature range, and improved safety for electric vehicles. ASSBs employing lithium metal anodes (Li), sulfide-based solid-state electrolytes (SSE), and Ni-rich layered transition metal oxide cathodes (LiMO2, M = Ni, Mn, Co, Al) are particularly promising due to its superior electrochemical performance compared to other solid-electrolyte systems. However, the battery cycle life at high cathode mass loading and high current is still limited because the failure mechanism is not fully understood. Lithium dendrite growth at the anode or inside a solid electrolyte still represents as a serious risk of cell failure. Interfacial resistance increases attributed to electrolyte decomposition and interfacial void formation at both cathode–electrolyte and anode–electrolyte interfaces lead to gradual capacity fading. In this Review, we present the fundamental challenges and recent scientific understandings of each component in ASSBs. The novel diagnostic tools for these components, especially the interfaces buried under the surface that are often hard for characterization are mainly examined. Lastly, we offer a perspective for future research directions. We hope this Review will provide a timely snapshot of state-of-the-art research progress in ASSBs to accelerate the development of ASSBs.},
doi = {10.1016/j.nanoen.2021.106081},
journal = {Nano Energy},
number = ,
volume = 87,
place = {United States},
year = {Sat May 08 00:00:00 EDT 2021},
month = {Sat May 08 00:00:00 EDT 2021}
}
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Works referenced in this record:

The rechargeable revolution: A better battery
journal, March 2014

Performance and cost of materials for lithium-based rechargeable automotive batteries
journal, April 2018

Practical Evaluation of Li-Ion Batteries
journal, April 2019

Guidelines and trends for next-generation rechargeable lithium and lithium-ion batteries
journal, January 2020

  • Wu, Feixiang; Maier, Joachim; Yu, Yan
  • Chemical Society Reviews, Vol. 49, Issue 5
  • DOI: 10.1039/C7CS00863E

Challenges in Lithium Metal Anodes for Solid-State Batteries
journal, February 2020

Status and challenges in enabling the lithium metal electrode for high-energy and low-cost rechargeable batteries
journal, December 2017

Identifying and Addressing Critical Challenges of High-Voltage Layered Ternary Oxide Cathode Materials
journal, June 2019

Recent progress in Li-rich layered oxides as cathode materials for Li-ion batteries
journal, January 2014

  • Yan, Jianhua; Liu, Xingbo; Li, Bingyun
  • RSC Adv., Vol. 4, Issue 108
  • DOI: 10.1039/C4RA12454E

Review—Li-Rich Layered Oxide Cathodes for Next-Generation Li-Ion Batteries: Chances and Challenges
journal, January 2015

  • Rozier, Patrick; Tarascon, Jean Marie
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0111514jes

Positioning Organic Electrode Materials in the Battery Landscape
journal, September 2018

Review on solid electrolytes for all-solid-state lithium-ion batteries
journal, June 2018

A durable and safe solid-state lithium battery with a hybrid electrolyte membrane
journal, March 2018

A solid future for battery development
journal, September 2016

Electrochemical Stability Window of Polymeric Electrolytes
journal, May 2019

Polymer Electrolyte Membrane with High Ionic Conductivity and Enhanced Interfacial Stability for Lithium Metal Battery
journal, April 2020

  • Liu, Fengquan; Bin, Fengjuan; Xue, Jinxin
  • ACS Applied Materials & Interfaces, Vol. 12, Issue 20
  • DOI: 10.1021/acsami.9b21370

Sulfide solid electrolytes for all-solid-state lithium batteries: Structure, conductivity, stability and application
journal, September 2018

New Lithium Metal Polymer Solid State Battery for an Ultrahigh Energy: Nano C-LiFePO 4 versus Nano Li 1.2 V 3 O 8
journal, March 2015

Nanocomposite polymer electrolytes for lithium batteries
journal, July 1998

  • Croce, F.; Appetecchi, G. B.; Persi, L.
  • Nature, Vol. 394, Issue 6692
  • DOI: 10.1038/28818

A lithium superionic conductor
journal, July 2011

  • Kamaya, Noriaki; Homma, Kenji; Yamakawa, Yuichiro
  • Nature Materials, Vol. 10, Issue 9, p. 682-686
  • DOI: 10.1038/nmat3066

Ionic Conductivity in the Crystalline Polymer Electrolytes PEO 6 :LiXF 6 , X = P, As, Sb
journal, April 2003

  • Stoeva, Zlatka; Martin-Litas, Isabelle; Staunton, Edward
  • Journal of the American Chemical Society, Vol. 125, Issue 15
  • DOI: 10.1021/ja029326t

Hybrid Electrolytes with Controlled Network Structures for Lithium Metal Batteries
journal, August 2015

Not All Lithium Filaments Are the Same in Solid-State Batteries
journal, April 2020

Dendrite Growth in Lithium/Polymer Systems
journal, January 2003

  • Monroe, Charles; Newman, John
  • Journal of The Electrochemical Society, Vol. 150, Issue 10
  • DOI: 10.1149/1.1606686

The Effect of Interfacial Deformation on Electrodeposition Kinetics
journal, January 2004

  • Monroe, Charles; Newman, John
  • Journal of The Electrochemical Society, Vol. 151, Issue 6
  • DOI: 10.1149/1.1710893

The Impact of Elastic Deformation on Deposition Kinetics at Lithium/Polymer Interfaces
journal, January 2005

  • Monroe, Charles; Newman, John
  • Journal of The Electrochemical Society, Vol. 152, Issue 2
  • DOI: 10.1149/1.1850854

Resolution of the Modulus versus Adhesion Dilemma in Solid Polymer Electrolytes for Rechargeable Lithium Metal Batteries
journal, January 2012

  • Stone, G. M.; Mullin, S. A.; Teran, A. A.
  • Journal of The Electrochemical Society, Vol. 159, Issue 3
  • DOI: 10.1149/2.030203jes

Gallium-Doped Li 7 La 3 Zr 2 O 12 Garnet-Type Electrolytes with High Lithium-Ion Conductivity
journal, January 2017

  • Wu, Jian-Fang; Chen, En-Yi; Yu, Yao
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 2
  • DOI: 10.1021/acsami.6b13902

The role of Al and Li concentration on the formation of cubic garnet solid electrolyte of nominal composition Li7La3Zr2O12
journal, January 2012

  • Rangasamy, Ezhiyl; Wolfenstine, Jeff; Sakamoto, Jeffrey
  • Solid State Ionics, Vol. 206, p. 28-32
  • DOI: 10.1016/j.ssi.2011.10.022

Compliant Yet Brittle Mechanical Behavior of Li 2 S-P 2 S 5 Lithium-Ion-Conducting Solid Electrolyte
journal, January 2017

  • McGrogan, Frank P.; Swamy, Tushar; Bishop, Sean R.
  • Advanced Energy Materials, Vol. 7, Issue 12
  • DOI: 10.1002/aenm.201602011

Lithium Metal Penetration Induced by Electrodeposition through Solid Electrolytes: Example in Single-Crystal Li 6 La 3 ZrTaO 12 Garnet
journal, January 2018

  • Swamy, Tushar; Park, Richard; Sheldon, Brian W.
  • Journal of The Electrochemical Society, Vol. 165, Issue 16
  • DOI: 10.1149/2.1391814jes

Mechanism of Lithium Metal Penetration through Inorganic Solid Electrolytes
journal, July 2017

  • Porz, Lukas; Swamy, Tushar; Sheldon, Brian W.
  • Advanced Energy Materials, Vol. 7, Issue 20
  • DOI: 10.1002/aenm.201701003

Inorganic sulfide solid electrolytes for all-solid-state lithium secondary batteries
journal, January 2019

  • Lian, Peng-Jie; Zhao, Bo-Sheng; Zhang, Lian-Qi
  • Journal of Materials Chemistry A, Vol. 7, Issue 36
  • DOI: 10.1039/C9TA04555D

High-power all-solid-state batteries using sulfide superionic conductors
journal, March 2016

Sulfide Solid Electrolytes for Lithium Battery Applications
journal, August 2018

  • Lau, Jonathan; DeBlock, Ryan H.; Butts, Danielle M.
  • Advanced Energy Materials, Vol. 8, Issue 27
  • DOI: 10.1002/aenm.201800933

All-in-one improvement toward Li6PS5Br-Based solid electrolytes triggered by compositional tune
journal, January 2019

Argyrodite Solid Electrolyte with a Stable Interface and Superior Dendrite Suppression Capability Realized by ZnO Co-Doping
journal, September 2019

  • Chen, Ting; Zhang, Long; Zhang, Zhaoxing
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 43
  • DOI: 10.1021/acsami.9b13313

An argyrodite sulfide-based superionic conductor synthesized by a liquid-phase technique with tetrahydrofuran and ethanol
journal, January 2019

  • Yubuchi, So; Uematsu, Miwa; Hotehama, Chie
  • Journal of Materials Chemistry A, Vol. 7, Issue 2
  • DOI: 10.1039/C8TA09477B

Interface Stability of Argyrodite Li 6 PS 5 Cl toward LiCoO 2 , LiNi 1/3 Co 1/3 Mn 1/3 O 2 , and LiMn 2 O 4 in Bulk All-Solid-State Batteries
journal, April 2017

Revealing Nanoscale Solid–Solid Interfacial Phenomena for Long-Life and High-Energy All-Solid-State Batteries
journal, October 2019

  • Banerjee, Abhik; Tang, Hanmei; Wang, Xuefeng
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 46
  • DOI: 10.1021/acsami.9b13955

Stable Thiophosphate-Based All-Solid-State Lithium Batteries through Conformally Interfacial Nanocoating
journal, September 2019

Pressure effects on sulfide electrolytes for all solid-state batteries
journal, January 2020

  • Doux, Jean-Marie; Yang, Yangyuchen; Tan, Darren H. S.
  • Journal of Materials Chemistry A, Vol. 8, Issue 10
  • DOI: 10.1039/C9TA12889A

Influence of Carbon Additives on the Decomposition Pathways in Cathodes of Lithium Thiophosphate-Based All-Solid-State Batteries
journal, July 2020

Dry coating of active material particles with sulfide solid electrolytes for an all-solid-state lithium battery
journal, February 2020

Redox-active cathode interphases in solid-state batteries
journal, January 2017

  • Koerver, Raimund; Walther, Felix; Aygün, Isabel
  • Journal of Materials Chemistry A, Vol. 5, Issue 43
  • DOI: 10.1039/C7TA07641J

Effects of volume variations under different compressive pressures on the performance and microstructure of all-solid-state batteries
journal, October 2020

LiI-Doped Sulfide Solid Electrolyte: Enabling a High-Capacity Slurry-Cast Electrode by Low-Temperature Post-Sintering for Practical All-Solid-State Lithium Batteries
journal, August 2018

  • Choi, Seon-Joo; Choi, Sun-Hwa; Bui, Anh Dinh
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 37
  • DOI: 10.1021/acsami.8b11244

Single-step wet-chemical fabrication of sheet-type electrodes from solid-electrolyte precursors for all-solid-state lithium-ion batteries
journal, January 2017

  • Oh, Dae Yang; Kim, Dong Hyeon; Jung, Sung Hoo
  • J. Mater. Chem. A, Vol. 5, Issue 39
  • DOI: 10.1039/C7TA06873E

Frequency of everyday pro-environmental behaviour is explained by baseline activation in lateral prefrontal cortex
journal, January 2019

  • Baumgartner, Thomas; Langenbach, Benedikt P.; Gianotti, Lorena R. R.
  • Scientific Reports, Vol. 9, Issue 1
  • DOI: 10.1038/s41598-018-36956-2

Attainable Gravimetric and Volumetric Energy Density of Li–S and Li Ion Battery Cells with Solid Separator-Protected Li Metal Anodes
journal, October 2015

Theoretical versus Practical Energy: A Plea for More Transparency in the Energy Calculation of Different Rechargeable Battery Systems
journal, June 2019

  • Betz, Johannes; Bieker, Georg; Meister, Paul
  • Advanced Energy Materials, Vol. 9, Issue 22
  • DOI: 10.1002/aenm.201900761

Deformation and stress in electrode materials for Li-ion batteries
journal, June 2014

State of health and charge measurements in lithium-ion batteries using mechanical stress
journal, December 2014

Chemo-mechanical expansion of lithium electrode materials – on the route to mechanically optimized all-solid-state batteries
journal, January 2018

  • Koerver, Raimund; Zhang, Wenbo; de Biasi, Lea
  • Energy & Environmental Science, Vol. 11, Issue 8
  • DOI: 10.1039/C8EE00907D

Mechanical properties of metallic lithium: from nano to bulk scales
journal, March 2020

Elastic, plastic, and creep mechanical properties of lithium metal
journal, October 2018

  • Masias, Alvaro; Felten, Nando; Garcia-Mendez, Regina
  • Journal of Materials Science, Vol. 54, Issue 3
  • DOI: 10.1007/s10853-018-2971-3

A nanoindentation study of the viscoplastic behavior of pure lithium
journal, March 2017

Enhanced strength and temperature dependence of mechanical properties of Li at small scales and its implications for Li metal anodes
journal, December 2016

  • Xu, Chen; Ahmad, Zeeshan; Aryanfar, Asghar
  • Proceedings of the National Academy of Sciences, Vol. 114, Issue 1
  • DOI: 10.1073/pnas.1615733114

A large deformation elastic–viscoplastic model for lithium
journal, October 2018

Scaling, dimensional analysis, and indentation measurements
journal, August 2004

  • Cheng, Yang-Tse; Cheng, Che-Min
  • Materials Science and Engineering: R: Reports, Vol. 44, Issue 4-5
  • DOI: 10.1016/j.mser.2004.05.001

Nanoindentation of high-purity vapor deposited lithium films: The elastic modulus
journal, May 2018

  • Herbert, Erik G.; Hackney, Stephen A.; Dudney, Nancy J.
  • Journal of Materials Research, Vol. 33, Issue 10
  • DOI: 10.1557/jmr.2018.83

Nanoindentation of high-purity vapor deposited lithium films: A mechanistic rationalization of the transition from diffusion to dislocation-mediated flow
journal, May 2018

  • Herbert, Erik G.; Hackney, Stephen A.; Thole, Violet
  • Journal of Materials Research, Vol. 33, Issue 10
  • DOI: 10.1557/jmr.2018.85

Nanoindentation of high-purity vapor deposited lithium films: A mechanistic rationalization of diffusion-mediated flow
journal, May 2018

  • Herbert, Erik G.; Hackney, Stephen A.; Thole, Violet
  • Journal of Materials Research, Vol. 33, Issue 10
  • DOI: 10.1557/jmr.2018.84

Constitutive Relations of Indium in Extreme-Temperature Electronic Packaging Based on Anand Model
journal, June 2009

Rate-dependent indentation behavior of solder alloys
journal, April 2005

Mechanical Stress Induced Current Focusing and Fracture in Grain Boundaries
journal, January 2019

  • Barai, Pallab; Higa, Kenneth; Ngo, Anh T.
  • Journal of The Electrochemical Society, Vol. 166, Issue 10
  • DOI: 10.1149/2.0321910jes

Simulation of the Effect of Contact Area Loss in All-Solid-State Li-Ion Batteries
journal, January 2017

  • Tian, Hong-Kang; Qi, Yue
  • Journal of The Electrochemical Society, Vol. 164, Issue 11
  • DOI: 10.1149/2.0481711jes

Contact mechanics for randomly rough surfaces
journal, June 2006

Effect of Initial State of Lithium on the Propensity for Dendrite Formation: A Theoretical Study
journal, December 2016

  • Barai, Pallab; Higa, Kenneth; Srinivasan, Venkat
  • Journal of The Electrochemical Society, Vol. 164, Issue 2
  • DOI: 10.1149/2.0661702jes

Impact of External Pressure and Electrolyte Transport Properties on Lithium Dendrite Growth
journal, January 2018

  • Barai, Pallab; Higa, Kenneth; Srinivasan, Venkat
  • Journal of The Electrochemical Society, Vol. 165, Issue 11
  • DOI: 10.1149/2.0651811jes

Influence of Electrolyte Modulus on the Local Current Density at a Dendrite Tip on a Lithium Metal Electrode
journal, January 2016

  • Harry, Katherine J.; Higa, Kenneth; Srinivasan, Venkat
  • Journal of The Electrochemical Society, Vol. 163, Issue 10
  • DOI: 10.1149/2.0191610jes

Regulating electrodeposition morphology of lithium: towards commercially relevant secondary Li metal batteries
journal, January 2020

  • Zheng, Jingxu; Kim, Mun Sek; Tu, Zhengyuan
  • Chemical Society Reviews, Vol. 49, Issue 9
  • DOI: 10.1039/C9CS00883G

Lithium Mechanics: Roles of Strain Rate and Temperature and Implications for Lithium Metal Batteries
journal, January 2019

  • LePage, William S.; Chen, Yuxin; Kazyak, Eric
  • Journal of The Electrochemical Society, Vol. 166, Issue 2
  • DOI: 10.1149/2.0221902jes

Quantitative Model of Electrochemical Ostwald Ripening and Its Application to the Time-Dependent Electrode Potential of Nanocrystalline Metals
journal, June 2006

  • Schröder, A.; Fleig, J.; Gryaznov, D.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 25
  • DOI: 10.1021/jp060788t

Perspective on the Mechanical Interaction Between Lithium Dendrites and Polymer Separators at Low Temperature
journal, August 2016

  • Love, Corey T.
  • Journal of Electrochemical Energy Conversion and Storage, Vol. 13, Issue 3
  • DOI: 10.1115/1.4034483

Nanoscale Mapping of Extrinsic Interfaces in Hybrid Solid Electrolytes
journal, January 2020

Facile and scalable fabrication of polymer-ceramic composite electrolyte with high ceramic loadings
journal, June 2018

Scalable Manufacturing of Hybrid Solid Electrolytes with Interface Control
journal, November 2019

  • Dixit, Marm B.; Zaman, Wahid; Bootwala, Yousuf
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 48
  • DOI: 10.1021/acsami.9b15463

Visualizing percolation and ion transport in hybrid solid electrolytes for Li–metal batteries
journal, January 2019

  • Zaman, Wahid; Hortance, Nicholas; Dixit, Marm B.
  • Journal of Materials Chemistry A, Vol. 7, Issue 41
  • DOI: 10.1039/C9TA05118J

Diffusion Limitation of Lithium Metal and Li–Mg Alloy Anodes on LLZO Type Solid Electrolytes as a Function of Temperature and Pressure
journal, October 2019

  • Krauskopf, Thorben; Mogwitz, Boris; Rosenbach, Carolin
  • Advanced Energy Materials, Vol. 9, Issue 44
  • DOI: 10.1002/aenm.201902568

Critical stripping current leads to dendrite formation on plating in lithium anode solid electrolyte cells
journal, July 2019

  • Kasemchainan, Jitti; Zekoll, Stefanie; Spencer Jolly, Dominic
  • Nature Materials, Vol. 18, Issue 10
  • DOI: 10.1038/s41563-019-0438-9

Characterizing the Li-Solid-Electrolyte Interface Dynamics as a Function of Stack Pressure and Current Density
journal, September 2019

The Indium−Lithium Electrode in Solid‐State Lithium‐Ion Batteries: Phase Formation, Redox Potentials, and Interface Stability
journal, March 2019

  • Santhosha, A. L.; Medenbach, Lukas; Buchheim, Johannes R.
  • Batteries & Supercaps, Vol. 2, Issue 6
  • DOI: 10.1002/batt.201800149

Review—Practical Challenges Hindering the Development of Solid State Li Ion Batteries
journal, January 2017

  • Kerman, Kian; Luntz, Alan; Viswanathan, Venkatasubramanian
  • Journal of The Electrochemical Society, Vol. 164, Issue 7
  • DOI: 10.1149/2.1571707jes

Interface Stability in Solid-State Batteries
journal, December 2015

Intergranular Li metal propagation through polycrystalline Li6.25Al0.25La3Zr2O12 ceramic electrolyte
journal, January 2017

Lithium ion conductivity in Li 2 S–P 2 S 5 glasses – building units and local structure evolution during the crystallization of superionic conductors Li 3 PS 4 , Li 7 P 3 S 11 and Li 4 P 2 S 7
journal, January 2017

  • Dietrich, Christian; Weber, Dominik A.; Sedlmaier, Stefan J.
  • Journal of Materials Chemistry A, Vol. 5, Issue 34
  • DOI: 10.1039/C7TA06067J

Direct observation of lithium dendrites inside garnet-type lithium-ion solid electrolyte
journal, August 2015

Interphase formation on lithium solid electrolytes—An in situ approach to study interfacial reactions by photoelectron spectroscopy
journal, October 2015

Direct Observation of the Interfacial Instability of the Fast Ionic Conductor Li 10 GeP 2 S 12 at the Lithium Metal Anode
journal, March 2016

Interfaces in Solid-State Lithium Batteries
journal, October 2018

Understanding interface stability in solid-state batteries
journal, December 2019

Evolution at the Solid Electrolyte/Gold Electrode Interface during Lithium Deposition and Stripping
journal, March 2017

Rotiferan Hox genes give new insights into the evolution of metazoan bodyplans
journal, April 2017

Degradation of NASICON-Type Materials in Contact with Lithium Metal: Formation of Mixed Conducting Interphases (MCI) on Solid Electrolytes
journal, October 2013

  • Hartmann, Pascal; Leichtweiss, Thomas; Busche, Martin R.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 41
  • DOI: 10.1021/jp4051275

Lithium anode for lithium-air secondary batteries
journal, December 2008

Interfacial Stability of Li Metal–Solid Electrolyte Elucidated via in Situ Electron Microscopy
journal, October 2016

Structures, Li + mobilities, and interfacial properties of solid electrolytes Li 3 PS 4 and Li 3 PO 4 from first principles
journal, September 2013

Clarifying the relationship between redox activity and electrochemical stability in solid electrolytes
journal, January 2020

  • Schwietert, Tammo K.; Arszelewska, Violetta A.; Wang, Chao
  • Nature Materials, Vol. 19, Issue 4
  • DOI: 10.1038/s41563-019-0576-0

Quantum Mechanics Reactive Dynamics Study of Solid Li-Electrode/Li 6 PS 5 Cl-Electrolyte Interface
journal, May 2017

Interphase formation and degradation of charge transfer kinetics between a lithium metal anode and highly crystalline Li7P3S11 solid electrolyte
journal, March 2016

Effect of Processing Conditions of 75Li2S-25P2S5 Solid Electrolyte on its DC Electrochemical Behavior
journal, May 2017

Characterizing the Li–Li7La3Zr2O12 interface stability and kinetics as a function of temperature and current density
journal, January 2016

Stability of Nb-Doped Cubic Li 7 La 3 Zr 2 O 12 with Lithium Metal
journal, January 2013

  • Ishiguro, K.; Nakata, Y.; Matsui, M.
  • Journal of The Electrochemical Society, Vol. 160, Issue 10
  • DOI: 10.1149/2.036310jes

Li Penetration in Ceramic Solid Electrolytes: Operando Microscopy Analysis of Morphology, Propagation, and Reversibility
journal, April 2020

Transparent cubic garnet-type solid electrolyte of Al2O3-doped Li7La3Zr2O12
journal, October 2015

Structural and Electrochemical Consequences of Al and Ga Cosubstitution in Li 7 La 3 Zr 2 O 12 Solid Electrolytes
journal, March 2016

  • Rettenwander, Daniel; Redhammer, Günther; Preishuber-Pflügl, Florian
  • Chemistry of Materials, Vol. 28, Issue 7
  • DOI: 10.1021/acs.chemmater.6b00579

Li 7 La 3 Zr 2 O 12 Interface Modification for Li Dendrite Prevention
journal, April 2016

  • Tsai, Chih-Long; Roddatis, Vladimir; Chandran, C. Vinod
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 16
  • DOI: 10.1021/acsami.6b00831

In-situ, non-destructive acoustic characterization of solid state electrolyte cells
journal, August 2016

Toward All-Solid-State Lithium Batteries: Three-Dimensional Visualization of Lithium Migration in β-Li 3 PS 4 Ceramic Electrolyte
journal, January 2018

  • Seitzman, Natalie; Guthrey, Harvey; Sulas, Dana B.
  • Journal of The Electrochemical Society, Vol. 165, Issue 16
  • DOI: 10.1149/2.0301816jes

Crystal Structure of High-Temperature Phase of Lithium Ionic Conductor, Li 3 PS 4
journal, January 2010

  • Homma, Kenji; Yonemura, Masao; Nagao, Miki
  • Journal of the Physical Society of Japan, Vol. 79, Issue Suppl.A
  • DOI: 10.1143/JPSJS.79SA.90

Structure of the thio-LISICON, Li4GeS4
journal, December 2002

Influence of Lattice Polarizability on the Ionic Conductivity in the Lithium Superionic Argyrodites Li 6 PS 5 X (X = Cl, Br, I)
journal, July 2017

  • Kraft, Marvin A.; Culver, Sean P.; Calderon, Mario
  • Journal of the American Chemical Society, Vol. 139, Issue 31
  • DOI: 10.1021/jacs.7b06327

Lithium Ionic Conductor Thio-LISICON: The Li2S-GeS2-P2S5 System
journal, January 2001

  • Kanno, Ryoji; Murayama, Masahiro
  • Journal of The Electrochemical Society, Vol. 148, Issue 7, p. A742-A746
  • DOI: 10.1149/1.1379028

High performance Li2S–P2S5 solid electrolyte induced by selenide
journal, August 2014

Characterization of Li2S?P2S5 glass-ceramics as a solid electrolyte for lithium secondary batteries
journal, November 2004

Origin of Outstanding Stability in the Lithium Solid Electrolyte Materials: Insights from Thermodynamic Analyses Based on First-Principles Calculations
journal, October 2015

  • Zhu, Yizhou; He, Xingfeng; Mo, Yifei
  • ACS Applied Materials & Interfaces, Vol. 7, Issue 42
  • DOI: 10.1021/acsami.5b07517

Crystal structure of a superionic conductor, Li7P3S11
journal, June 2007

Preparation and characterization of lithium ion conducting Li2S–P2S5–GeS2 glasses and glass-ceramics
journal, October 2010

Synthesis, structure and electrochemical performance of the argyrodite Li 6 PS 5 Cl solid electrolyte for Li-ion solid state batteries
journal, October 2016

Preparation of high lithium-ion conducting Li6PS5Cl solid electrolyte from ethanol solution for all-solid-state lithium batteries
journal, October 2015

An Iodide-Based Li 7 P 2 S 8 I Superionic Conductor
journal, January 2015

  • Rangasamy, Ezhiylmurugan; Liu, Zengcai; Gobet, Mallory
  • Journal of the American Chemical Society, Vol. 137, Issue 4
  • DOI: 10.1021/ja508723m

A solid lithium superionic conductor Li 11 AlP 2 S 12 with a thio-LISICON analogous structure
journal, January 2016

  • Zhou, Pengfei; Wang, Jianbin; Cheng, Fangyi
  • Chemical Communications, Vol. 52, Issue 36
  • DOI: 10.1039/C6CC02131J

Homocysteine directly interacts and activates the angiotensin II type I receptor to aggravate vascular injury
journal, January 2018

Structural change of Li2S–P2S5 sulfide solid electrolytes in the atmosphere
journal, February 2011

  • Muramatsu, Hiromasa; Hayashi, Akitoshi; Ohtomo, Takamasa
  • Solid State Ionics, Vol. 182, Issue 1
  • DOI: 10.1016/j.ssi.2010.10.013

All-solid-state lithium batteries with Li3PS4 glass as active material
journal, October 2015

Air-stable, high-conduction solid electrolytes of arsenic-substituted Li 4 SnS 4
journal, January 2014

  • Sahu, Gayatri; Lin, Zhan; Li, Juchuan
  • Energy Environ. Sci., Vol. 7, Issue 3
  • DOI: 10.1039/C3EE43357A

Modeling of internal mechanical failure of all-solid-state batteries during electrochemical cycling, and implications for battery design
journal, January 2017

  • Bucci, Giovanna; Swamy, Tushar; Chiang, Yet-Ming
  • Journal of Materials Chemistry A, Vol. 5, Issue 36
  • DOI: 10.1039/C7TA03199H

Investigating the Dendritic Growth during Full Cell Cycling of Garnet Electrolyte in Direct Contact with Li Metal
journal, January 2017

  • Aguesse, Frederic; Manalastas, William; Buannic, Lucienne
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 4
  • DOI: 10.1021/acsami.6b13925

The devil is in the electrons
journal, February 2019

High electronic conductivity as the origin of lithium dendrite formation within solid electrolytes
journal, January 2019

Stack Pressure Considerations for Room‐Temperature All‐Solid‐State Lithium Metal Batteries
journal, November 2019

  • Doux, Jean‐Marie; Nguyen, Han; Tan, Darren H. S.
  • Advanced Energy Materials, Vol. 10, Issue 1
  • DOI: 10.1002/aenm.201903253

Elastic Properties of Alkali Superionic Conductor Electrolytes from First Principles Calculations
journal, November 2015

  • Deng, Zhi; Wang, Zhenbin; Chu, Iek-Heng
  • Journal of The Electrochemical Society, Vol. 163, Issue 2
  • DOI: 10.1149/2.0061602jes

(Electro)chemical expansion during cycling: monitoring the pressure changes in operating solid-state lithium batteries
journal, January 2017

  • Zhang, Wenbo; Schröder, Daniel; Arlt, Tobias
  • Journal of Materials Chemistry A, Vol. 5, Issue 20
  • DOI: 10.1039/C7TA02730C

Sulfur-Based Electrode Using a Polyelectrolyte Binder Studied via Coupled in Situ Synchrotron X-ray Diffraction and Tomography
journal, February 2020

  • Lemarié, Quentin; Maire, Eric; Idrissi, Hassane
  • ACS Applied Energy Materials, Vol. 3, Issue 3
  • DOI: 10.1021/acsaem.9b02108

Interfacial Processes and Influence of Composite Cathode Microstructure Controlling the Performance of All-Solid-State Lithium Batteries
journal, May 2017

  • Zhang, Wenbo; Weber, Dominik A.; Weigand, Harald
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 21
  • DOI: 10.1021/acsami.7b01137

Degradation Mechanisms at the Li 10 GeP 2 S 12 /LiCoO 2 Cathode Interface in an All-Solid-State Lithium-Ion Battery
journal, June 2018

  • Zhang, Wenbo; Richter, Felix H.; Culver, Sean P.
  • ACS Applied Materials & Interfaces, Vol. 10, Issue 26
  • DOI: 10.1021/acsami.8b05132

Lattice volume change during charge/discharge reaction and cycle performance of Li[NixCoyMnz]O2
journal, May 2016

Anisotropic Lattice Strain and Mechanical Degradation of High- and Low-Nickel NCM Cathode Materials for Li-Ion Batteries
journal, February 2017

  • Kondrakov, Aleksandr O.; Schmidt, Alexander; Xu, Jin
  • The Journal of Physical Chemistry C, Vol. 121, Issue 6
  • DOI: 10.1021/acs.jpcc.6b12885

Volume Changes of Graphite Anodes Revisited: A Combined Operando X-ray Diffraction and In Situ Pressure Analysis Study
journal, April 2018

  • Schweidler, Simon; de Biasi, Lea; Schiele, Alexander
  • The Journal of Physical Chemistry C, Vol. 122, Issue 16
  • DOI: 10.1021/acs.jpcc.8b01873

Between Scylla and Charybdis: Balancing Among Structural Stability and Energy Density of Layered NCM Cathode Materials for Advanced Lithium-Ion Batteries
journal, November 2017

  • de Biasi, Lea; Kondrakov, Aleksandr O.; Geßwein, Holger
  • The Journal of Physical Chemistry C, Vol. 121, Issue 47
  • DOI: 10.1021/acs.jpcc.7b06363

Reversible and irreversible dilation of lithium-ion battery electrodes investigated by in-situ dilatometry
journal, February 2017

A New Method to Model the Thickness Change of a Commercial Pouch Cell during Discharge
journal, January 2016

  • Rieger, Bernhard; Erhard, Simon V.; Rumpf, Katharina
  • Journal of The Electrochemical Society, Vol. 163, Issue 8
  • DOI: 10.1149/2.0441608jes

Impact of Cathode Material Particle Size on the Capacity of Bulk-Type All-Solid-State Batteries
journal, March 2018

Interfacial Observation between LiCoO 2 Electrode and Li 2 S−P 2 S 5 Solid Electrolytes of All-Solid-State Lithium Secondary Batteries Using Transmission Electron Microscopy †
journal, February 2010

  • Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro
  • Chemistry of Materials, Vol. 22, Issue 3
  • DOI: 10.1021/cm901819c

Enhancing the High Rate Capability and Cycling Stability of LiMn 2 O 4 by Coating of Solid-State Electrolyte LiNbO 3
journal, December 2014

  • Zhang, Zhi-Jia; Chou, Shu-Lei; Gu, Qin-Fen
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 24
  • DOI: 10.1021/am5056504

Solid-state lithium battery with graphite anode
journal, March 2003

LiNbO3-coated LiCoO2 as cathode material for all solid-state lithium secondary batteries
journal, July 2007

Synthesis of phosphorous sulfide solid electrolyte and all-solid-state lithium batteries with graphite electrode
journal, October 2005

  • Seino, Yoshikatsu; Takada, Kazunori; Kim, Bong-Chull
  • Solid State Ionics, Vol. 176, Issue 31-34
  • DOI: 10.1016/j.ssi.2005.03.026

Structural Evolution and High-Voltage Structural Stability of Li(Ni x Mn y Co z )O 2 Electrodes
journal, December 2018

Synthesis of Single Crystal LiNi 0.88 Co 0.09 Al 0.03 O 2  with a Two-Step Lithiation Method
journal, January 2019

  • Li, Hongyang; Li, Jing; Zaker, Nafiseh
  • Journal of The Electrochemical Society, Vol. 166, Issue 10
  • DOI: 10.1149/2.0681910jes

Synthesis of Single Crystal LiNi 0.5 Mn 0.3 Co 0.2 O 2 for Lithium Ion Batteries
journal, January 2017

  • Li, Jing; Li, Hongyang; Stone, Will
  • Journal of The Electrochemical Society, Vol. 164, Issue 14
  • DOI: 10.1149/2.0401714jes

Single-crystal nickel-rich layered-oxide battery cathode materials: synthesis, electrochemistry, and intra-granular fracture
journal, May 2020

Tailoring the surface properties of LiNi 0.4 Mn 0.4 Co 0.2 O 2 by titanium substitution for improved high voltage cycling performance
journal, January 2015

  • Wolff-Goodrich, Silas; Lin, Feng; Markus, Isaac M.
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 34
  • DOI: 10.1039/C5CP03228H

Synthesis and electrochemical properties of LiNi0.85 − x Co x Mn0.15O2 as cathode materials for lithium-ion batteries
journal, August 2007

  • Li, Daocong; Yuan, Chaoqun; Dong, Jiaqing
  • Journal of Solid State Electrochemistry, Vol. 12, Issue 3
  • DOI: 10.1007/s10008-007-0394-1

Recent developments in cathode materials for lithium ion batteries
journal, February 2010

Interfaces Between Cathode and Electrolyte in Solid State Lithium Batteries: Challenges and Perspectives
journal, December 2018

Interface in Solid-State Lithium Battery: Challenges, Progress, and Outlook
journal, May 2019

  • Pervez, Syed Atif; Cambaz, Musa Ali; Thangadurai, Venkataraman
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 25
  • DOI: 10.1021/acsami.9b02675

Three-dimensional bilayer garnet solid electrolyte based high energy density lithium metal–sulfur batteries
journal, January 2017

  • Fu, Kun (Kelvin); Gong, Yunhui; Hitz, Gregory T.
  • Energy & Environmental Science, Vol. 10, Issue 7
  • DOI: 10.1039/C7EE01004D

Electrochemical and In Situ X‐Ray Diffraction Studies of Lithium Intercalation in LixCoO2
journal, January 1992

  • Reimers, Jan N.; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 139, Issue 8, p. 2091-2097
  • DOI: 10.1149/1.2221184

First-principles investigation of phase stability, elastic and thermodynamic properties in L12 Co3(Al,Mo,Nb) phase
journal, November 2016

Obstacles toward unity efficiency of LiNi 1-2x Co x Mn x O 2 (x = 0 ∼ 1/3) (NCM) cathode materials: Insights from ab initio calculations
journal, February 2017

In Situ X-ray Diffraction Study of Layered Li–Ni–Mn–Co Oxides: Effect of Particle Size and Structural Stability of Core–Shell Materials
journal, December 2015

In-situ Neutron Diffraction Study of a High Voltage Li(Ni0.42Mn0.42Co0.16)O2/Graphite Pouch Cell
journal, October 2015

Aging Analysis of Graphite/LiNi 1/3 Mn 1/3 Co 1/3 O 2 Cells Using XRD, PGAA, and AC Impedance
journal, January 2015

  • Buchberger, Irmgard; Seidlmayer, Stefan; Pokharel, Aneil
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0721514jes

Study of the Failure Mechanisms of LiNi 0.8 Mn 0.1 Co 0.1 O 2 Cathode Material for Lithium Ion Batteries
journal, January 2015

  • Li, Jing; Downie, Laura E.; Ma, Lin
  • Journal of The Electrochemical Society, Vol. 162, Issue 7
  • DOI: 10.1149/2.1011507jes

Bulk and surface structural changes in high nickel cathodes subjected to fast charging conditions
journal, January 2020

  • Liu, Tianyi; Du, Zhijia; Wu, Xianyang
  • Chemical Communications, Vol. 56, Issue 51
  • DOI: 10.1039/D0CC02579H

High-Performance Li-Ion Batteries Using Nickel-Rich Lithium Nickel Cobalt Aluminium Oxide–Nanocarbon Core–Shell Cathode: In Operando X-ray Diffraction
journal, August 2019

  • Vadivel, Selvamani; Phattharasupakun, Nutthaphon; Wutthiprom, Juthaporn
  • ACS Applied Materials & Interfaces, Vol. 11, Issue 34
  • DOI: 10.1021/acsami.9b06553

Effect of Metal (Mn, Ti) Doping on NCA Cathode Materials for Lithium Ion Batteries
journal, January 2018

  • Wan, Dao Yong; Fan, Zhi Yu; Dong, Yong Xiang
  • Journal of Nanomaterials, Vol. 2018
  • DOI: 10.1155/2018/8082502

Ni‐Rich Layered Cathode Materials with Electrochemo‐Mechanically Compliant Microstructures for All‐Solid‐State Li Batteries
journal, December 2019

  • Jung, Sung Hoo; Kim, Un‐Hyuck; Kim, Jae‐Hyung
  • Advanced Energy Materials, Vol. 10, Issue 6
  • DOI: 10.1002/aenm.201903360

Observation of Microstructural Evolution in Li Battery Cathode Oxide Particles by In Situ Electron Microscopy
journal, May 2013

  • Miller, Dean J.; Proff, Christian; Wen, J. G.
  • Advanced Energy Materials, Vol. 3, Issue 8
  • DOI: 10.1002/aenm.201300015

Collapse of LiNi 1– x – y Co x Mn y O 2 Lattice at Deep Charge Irrespective of Nickel Content in Lithium-Ion Batteries
journal, March 2019

  • Li, Wangda; Asl, Hooman Yaghoobnejad; Xie, Qiang
  • Journal of the American Chemical Society, Vol. 141, Issue 13
  • DOI: 10.1021/jacs.8b13798

Electrochemical properties of LiNi0.8Co0.15Al0.05O2–graphene composite as cathode materials for lithium-ion batteries
journal, September 2012

Surface modification of LiNi0.8Co0.1Mn0.1O2 with conducting polypyrrole
journal, May 2014

  • Xiong, Xunhui; Ding, Dong; Wang, Zhixing
  • Journal of Solid State Electrochemistry, Vol. 18, Issue 9
  • DOI: 10.1007/s10008-014-2519-7

Long-Life Nickel-Rich Layered Oxide Cathodes with a Uniform Li 2 ZrO 3 Surface Coating for Lithium-Ion Batteries
journal, March 2017

  • Song, Bohang; Li, Wangda; Oh, Seung-Min
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 11
  • DOI: 10.1021/acsami.7b00070

High-energy long-cycling all-solid-state lithium metal batteries enabled by silver–carbon composite anodes
journal, March 2020

Structure Integrity Endowed by a Ti-Containing Surface Layer towards Ultrastable LiNi 0.8 Co 0.15 Al 0.05 O 2 for All-Solid-State Lithium Batteries
journal, January 2016

  • Yang, Jing; Huang, Bingxin; Yin, Jingyun
  • Journal of The Electrochemical Society, Vol. 163, Issue 8
  • DOI: 10.1149/2.0331608jes

LiNbO3-coated LiNi0.8Co0.1Mn0.1O2 cathode with high discharge capacity and rate performance for all-solid-state lithium battery
journal, January 2020

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