Enabling selective zinc-ion intercalation by a eutectic electrolyte for practical anodeless zinc batteries

Li, Chang; Kingsbury, Ryan; Thind, Arashdeep Singh; Shyamsunder, Abhinandan; Fister, Timothy T.; Klie, Robert F.; Persson, Kristin A.; Nazar, Linda F.

doi:10.1038/s41467-023-38460-2

Title: Enabling selective zinc-ion intercalation by a eutectic electrolyte for practical anodeless zinc batteries

Journal Article · 27 May 2023 · Nature Communications

DOI: https://doi.org/10.1038/s41467-023-38460-2 · OSTI ID:1975427

; Kingsbury, Ryan;

; Shyamsunder, Abhinandan; Fister, Timothy T.;

; Persson, Kristin A.;

Abstract Two major challenges hinder the advance of aqueous zinc metal batteries for sustainable stationary storage: (1) achieving predominant Zn-ion (de)intercalation at the oxide cathode by suppressing adventitious proton co-intercalation and dissolution, and (2) simultaneously overcoming Zn dendrite growth at the anode that triggers parasitic electrolyte reactions. Here, we reveal the competition between Zn ²⁺ vs proton intercalation chemistry of a typical oxide cathode using ex-situ/ operando techniques, and alleviate side reactions by developing a cost-effective and non-flammable hybrid eutectic electrolyte. A fully hydrated Zn ²⁺ solvation structure facilitates fast charge transfer at the solid/electrolyte interface, enabling dendrite-free Zn plating/stripping with a remarkably high average coulombic efficiency of 99.8% at commercially relevant areal capacities of 4 mAh cm ⁻² and function up to 1600 h at 8 mAh cm ⁻² . By concurrently stabilizing Zn redox at both electrodes, we achieve a new benchmark in Zn-ion battery performance of 4 mAh cm ⁻² anode-free cells that retain 85% capacity over 100 cycles at 25 °C. Using this eutectic-design electrolyte, Zn | |Iodine full cells are further realized with 86% capacity retention over 2500 cycles. The approach represents a new avenue for long-duration energy storage.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE; USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1975427

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 14; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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