Chemical Stability of MIL-101(Cr) upon Adsorption of SO 2 and NO 2 under Dry and Humid Conditions
Abstract
A detailed understanding of the chemical stability of metal–organic frameworks (MOFs) in water and acidic and basic solutions currently exists; however, there has been comparatively little investigation into the chemical stability of MOFs in the presence of acid gas species that may be present in industrial settings. MIL-101(Cr), a MOF that is stable in liquid water as well as acidic and basic solutions, was tested for its stability upon exposure to the acid gases sulfur dioxide (SO2) and nitrogen dioxide (NO2). Successive breakthrough experiments of both SO2 and NO2 show that both gases lower the adsorption capacity of MIL-101(Cr), which is also observed by N2 physisorption experiments. X-ray photoelectron spectroscopy (XPS) confirms the presence of sulfur and nitrogen species in MIL-101(Cr) after exposure to SO2 and NO2 species. In situ infrared spectroscopy experiments suggest that adsorption of SO2 in MIL-101(Cr) is not completely reversible and that adsorption of NO2 in MIL-101(Cr) causes some structural degradation similar to what has been previously observed in HKUST-1.
- Authors:
-
[1];
[1];
[1];
[1]
- School of Chemical and Biomolecular Engineering, Georgia Institute of Technology, 311 Ferst Drive NW, Atlanta, Georgia 30332, United States
- Publication Date:
- Research Org.:
- Georgia Institute of Technology, Atlanta, GA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1975419
- Alternate Identifier(s):
- OSTI ID: 1984029
- Grant/Contract Number:
- FE0026433; SC0012577
- Resource Type:
- Published Article
- Journal Name:
- Industrial and Engineering Chemistry Research
- Additional Journal Information:
- Journal Name: Industrial and Engineering Chemistry Research Journal Volume: 62 Journal Issue: 22; Journal ID: ISSN 0888-5885
- Publisher:
- American Chemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Adsorption; Gases; Isotherms; Metal organic frameworks; Regeneration
Citation Formats
Carter, Eli A., Hungerford, Julian T., Joshi, Jayraj N., DeWitt, Stephen J. A., Jiang, Xiao, Marszalek, Bartosz, Lively, Ryan P., and Walton, Krista S. Chemical Stability of MIL-101(Cr) upon Adsorption of SO 2 and NO 2 under Dry and Humid Conditions. United States: N. p., 2023.
Web. doi:10.1021/acs.iecr.3c00209.
Carter, Eli A., Hungerford, Julian T., Joshi, Jayraj N., DeWitt, Stephen J. A., Jiang, Xiao, Marszalek, Bartosz, Lively, Ryan P., & Walton, Krista S. Chemical Stability of MIL-101(Cr) upon Adsorption of SO 2 and NO 2 under Dry and Humid Conditions. United States. https://doi.org/10.1021/acs.iecr.3c00209
Carter, Eli A., Hungerford, Julian T., Joshi, Jayraj N., DeWitt, Stephen J. A., Jiang, Xiao, Marszalek, Bartosz, Lively, Ryan P., and Walton, Krista S. Fri .
"Chemical Stability of MIL-101(Cr) upon Adsorption of SO 2 and NO 2 under Dry and Humid Conditions". United States. https://doi.org/10.1021/acs.iecr.3c00209.
@article{osti_1975419,
title = {Chemical Stability of MIL-101(Cr) upon Adsorption of SO 2 and NO 2 under Dry and Humid Conditions},
author = {Carter, Eli A. and Hungerford, Julian T. and Joshi, Jayraj N. and DeWitt, Stephen J. A. and Jiang, Xiao and Marszalek, Bartosz and Lively, Ryan P. and Walton, Krista S.},
abstractNote = {A detailed understanding of the chemical stability of metal–organic frameworks (MOFs) in water and acidic and basic solutions currently exists; however, there has been comparatively little investigation into the chemical stability of MOFs in the presence of acid gas species that may be present in industrial settings. MIL-101(Cr), a MOF that is stable in liquid water as well as acidic and basic solutions, was tested for its stability upon exposure to the acid gases sulfur dioxide (SO2) and nitrogen dioxide (NO2). Successive breakthrough experiments of both SO2 and NO2 show that both gases lower the adsorption capacity of MIL-101(Cr), which is also observed by N2 physisorption experiments. X-ray photoelectron spectroscopy (XPS) confirms the presence of sulfur and nitrogen species in MIL-101(Cr) after exposure to SO2 and NO2 species. In situ infrared spectroscopy experiments suggest that adsorption of SO2 in MIL-101(Cr) is not completely reversible and that adsorption of NO2 in MIL-101(Cr) causes some structural degradation similar to what has been previously observed in HKUST-1.},
doi = {10.1021/acs.iecr.3c00209},
journal = {Industrial and Engineering Chemistry Research},
number = 22,
volume = 62,
place = {United States},
year = {Fri May 26 00:00:00 EDT 2023},
month = {Fri May 26 00:00:00 EDT 2023}
}
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