Paving Pathways Toward Long–Life Graphite/LiNi0.5Mn1.5O4 Full Cells: Electrochemical and Interphasial Points of View
Abstract
Abstract The high‐voltage spinel cathode LiNi 0.5 Mn 1.5 O 4 (LNMO) with no cobalt and low nickel content is promising for lithium‐ion batteries due to its high energy and power densities, good thermal stability, and low cost. However, its high operating voltage (≈4.7 V) results in a decomposition of the electrolyte, severe chemical crossover, and deterioration of electrode‐electrolyte interphases (EEIs), hindering its practical viability. It is demonstrated here that by electrochemically pre‐cycling the graphite in an electrolyte containing 30 wt.% fluoroethylene carbonate, a robust LiF‐rich artificial solid electrolyte interphase can be constructed for surface protection; on the other hand, an electrochemical pre‐lithiation of Fe‐doped LNMO serves as a lithium source for graphite at a full‐cell voltage of 2.6 V. As a result, the full cells with the as‐modified electrodes deliver a high capacity of 129 mA h g −1 with an excellent capacity retention of 93% after 200 cycles, vastly outperforming the full cells with fresh electrodes (120 mA h g −1 initial capacity with 78% retention). Finally, pathways toward long‐life graphite||LNMO full cells are pictured based on the inspirations from the electrochemical modifications and in‐depth analyses of the EEIs in this study.
- Publication Date:
- Research Org.:
- Univ. of California, San Diego, CA (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Office of Sustainable Transportation. Vehicle Technologies Office (VTO); Welch Foundation; USDOE
- OSTI Identifier:
- 1969523
- Alternate Identifier(s):
- OSTI ID: 1885488
- Grant/Contract Number:
- EE0008442; F-1254; DE‐EE0008442
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Volume: 32; Journal Issue: 36; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Cui, Zehao, Zou, Feng, Celio, Hugo, and Manthiram, Arumugam. Paving Pathways Toward Long–Life Graphite/LiNi0.5Mn1.5O4 Full Cells: Electrochemical and Interphasial Points of View. United States: N. p., 2022.
Web. doi:10.1002/adfm.202203779.
Cui, Zehao, Zou, Feng, Celio, Hugo, & Manthiram, Arumugam. Paving Pathways Toward Long–Life Graphite/LiNi0.5Mn1.5O4 Full Cells: Electrochemical and Interphasial Points of View. United States. https://doi.org/10.1002/adfm.202203779
Cui, Zehao, Zou, Feng, Celio, Hugo, and Manthiram, Arumugam. Wed .
"Paving Pathways Toward Long–Life Graphite/LiNi0.5Mn1.5O4 Full Cells: Electrochemical and Interphasial Points of View". United States. https://doi.org/10.1002/adfm.202203779. https://www.osti.gov/servlets/purl/1969523.
@article{osti_1969523,
title = {Paving Pathways Toward Long–Life Graphite/LiNi0.5Mn1.5O4 Full Cells: Electrochemical and Interphasial Points of View},
author = {Cui, Zehao and Zou, Feng and Celio, Hugo and Manthiram, Arumugam},
abstractNote = {Abstract The high‐voltage spinel cathode LiNi 0.5 Mn 1.5 O 4 (LNMO) with no cobalt and low nickel content is promising for lithium‐ion batteries due to its high energy and power densities, good thermal stability, and low cost. However, its high operating voltage (≈4.7 V) results in a decomposition of the electrolyte, severe chemical crossover, and deterioration of electrode‐electrolyte interphases (EEIs), hindering its practical viability. It is demonstrated here that by electrochemically pre‐cycling the graphite in an electrolyte containing 30 wt.% fluoroethylene carbonate, a robust LiF‐rich artificial solid electrolyte interphase can be constructed for surface protection; on the other hand, an electrochemical pre‐lithiation of Fe‐doped LNMO serves as a lithium source for graphite at a full‐cell voltage of 2.6 V. As a result, the full cells with the as‐modified electrodes deliver a high capacity of 129 mA h g −1 with an excellent capacity retention of 93% after 200 cycles, vastly outperforming the full cells with fresh electrodes (120 mA h g −1 initial capacity with 78% retention). Finally, pathways toward long‐life graphite||LNMO full cells are pictured based on the inspirations from the electrochemical modifications and in‐depth analyses of the EEIs in this study.},
doi = {10.1002/adfm.202203779},
journal = {Advanced Functional Materials},
number = 36,
volume = 32,
place = {United States},
year = {Wed Jun 29 00:00:00 EDT 2022},
month = {Wed Jun 29 00:00:00 EDT 2022}
}
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Works referenced in this record:
Rational design of spontaneous reactions for protecting porous lithium electrodes in lithium–sulfur batteries
journal, July 2019
- Ren, Y. X.; Zeng, L.; Jiang, H. R.
- Nature Communications, Vol. 10, Issue 1
In Situ Mitigation of First-Cycle Anode Irreversibility in a New Spinel/FeSb Lithium-Ion Cell Enabled via a Microwave-Assisted Chemical Lithiation Process
journal, October 2014
- Moorhead-Rosenberg, Zachary; Allcorn, Eric; Manthiram, Arumugam
- Chemistry of Materials, Vol. 26, Issue 20
Is Cobalt Needed in Ni-Rich Positive Electrode Materials for Lithium Ion Batteries?
journal, January 2019
- Li, Hongyang; Cormier, Marc; Zhang, Ning
- Journal of The Electrochemical Society, Vol. 166, Issue 4
An Approach for Pre-Lithiation of Li 1+ x Ni 0.5 Mn 1.5 O 4 Cathodes Mitigating Active Lithium Loss
journal, January 2019
- Betz, Johannes; Nowak, Laura; Winter, Martin
- Journal of The Electrochemical Society, Vol. 166, Issue 15
Designing In-Situ-Formed Interphases Enables Highly Reversible Cobalt-Free LiNiO2 Cathode for Li-ion and Li-metal Batteries
journal, October 2019
- Deng, Tao; Fan, Xiulin; Cao, Longsheng
- Joule, Vol. 3, Issue 10
A New Strategy to Stabilize Capacity and Insight into the Interface Behavior in Electrochemical Reaction of LiNi 0.5 Mn 1.5 O 4 /Graphite System for High-Voltage Lithium-Ion Batteries
journal, September 2017
- Wang, Hongqiang; Xie, Xuesong; Wei, Xiaolu
- ACS Applied Materials & Interfaces, Vol. 9, Issue 38
Crossover Effects in Batteries with High‐Nickel Cathodes and Lithium‐Metal Anodes
journal, February 2021
- Langdon, Jayse; Manthiram, Arumugam
- Advanced Functional Materials, Vol. 31, Issue 17
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
A Comprehensive Analysis of the Interphasial and Structural Evolution over Long‐Term Cycling of Ultrahigh‐Nickel Cathodes in Lithium‐Ion Batteries
journal, October 2019
- Li, Jianyu; Manthiram, Arumugam
- Advanced Energy Materials, Vol. 9, Issue 45
Challenges of prelithiation strategies for next generation high energy lithium-ion batteries
journal, May 2022
- Min, Xueqing; Xu, Gaojie; Xie, Bin
- Energy Storage Materials, Vol. 47
Influence of Cation Ordering and Lattice Distortion on the Charge–Discharge Behavior of LiMn 1.5 Ni 0.5 O 4 Spinel between 5.0 and 2.0 V
journal, September 2012
- Lee, Eun-Sung; Nam, Kyung-Wan; Hu, Enyuan
- Chemistry of Materials, Vol. 24, Issue 18
Long-life LiNi0.5Mn1.5O4/graphite lithium-ion cells with an artificial graphite-electrolyte interface
journal, December 2021
- Zou, Feng; Nallan, Himamshu C.; Dolocan, Andrei
- Energy Storage Materials, Vol. 43
Localized concentrated high-concentration electrolyte enhanced stability and safety for high voltage Li-ion batteries
journal, October 2019
- Dai, Wenhui; Dong, Ning; Xia, Yonggao
- Electrochimica Acta, Vol. 320
Fluorinated Electrolytes for Li-Ion Batteries: The Lithium Difluoro(oxalato)borate Additive for Stabilizing the Solid Electrolyte Interphase
journal, December 2017
- Xia, Lan; Lee, Saixi; Jiang, Yabei
- ACS Omega, Vol. 2, Issue 12
Comparative Study of Fluoroethylene Carbonate and Vinylene Carbonate for Silicon Anodes in Lithium Ion Batteries
journal, January 2014
- Nguyen, Cao Cuong; Lucht, Brett L.
- Journal of The Electrochemical Society, Vol. 161, Issue 12
Weakly Solvating Solution Enables Chemical Prelithiation of Graphite–SiO x Anodes for High-Energy Li-Ion Batteries
journal, June 2021
- Choi, Jinkwan; Jeong, Hyangsoo; Jang, Juyoung
- Journal of the American Chemical Society, Vol. 143, Issue 24
Fluorinated electrolytes for Li-ion battery: An FEC-based electrolyte for high voltage LiNi0.5Mn1.5O4/graphite couple
journal, October 2013
- Hu, Libo; Zhang, Zhengcheng; Amine, Khalil
- Electrochemistry Communications, Vol. 35
A Cobalt‐ and Manganese‐Free High‐Nickel Layered Oxide Cathode for Long‐Life, Safer Lithium‐Ion Batteries
journal, October 2021
- Cui, Zehao; Xie, Qiang; Manthiram, Arumugam
- Advanced Energy Materials, Vol. 11, Issue 41
A Long Cycle‐Life High‐Voltage Spinel Lithium‐Ion Battery Electrode Achieved by Site‐Selective Doping
journal, April 2020
- Liang, Gemeng; Wu, Zhibin; Didier, Christophe
- Angewandte Chemie International Edition, Vol. 59, Issue 26
High-nickel layered oxide cathodes for lithium-based automotive batteries
journal, January 2020
- Li, Wangda; Erickson, Evan M.; Manthiram, Arumugam
- Nature Energy, Vol. 5, Issue 1
LiMn2O4 spinel and substituted cathodes
journal, May 2021
- Thackeray, Michael M.; Amine, Khalil
- Nature Energy, Vol. 6, Issue 5
Rechargeable Lithium–Sulfur Batteries
journal, July 2014
- Manthiram, Arumugam; Fu, Yongzhu; Chung, Sheng-Heng
- Chemical Reviews, Vol. 114, Issue 23
High-voltage liquid electrolytes for Li batteries: progress and perspectives
journal, January 2021
- Fan, Xiulin; Wang, Chunsheng
- Chemical Society Reviews, Vol. 50, Issue 18
High‐Nickel NMA: A Cobalt‐Free Alternative to NMC and NCA Cathodes for Lithium‐Ion Batteries
journal, July 2020
- Li, Wangda; Lee, Steven; Manthiram, Arumugam
- Advanced Materials, Vol. 32, Issue 33
Developing high-voltage spinel LiNi 0.5 Mn 1.5 O 4 cathodes for high-energy-density lithium-ion batteries: current achievements and future prospects
journal, January 2020
- Liang, Gemeng; Peterson, Vanessa K.; See, Khay Wai
- Journal of Materials Chemistry A, Vol. 8, Issue 31
Key strategies for enhancing the cycling stability and rate capacity of LiNi0.5Mn1.5O4 as high-voltage cathode materials for high power lithium-ion batteries
journal, June 2016
- Yi, Ting-Feng; Mei, Jie; Zhu, Yan-Rong
- Journal of Power Sources, Vol. 316
Nanostructured Li-Rich Fluoride Coated by Ionic Liquid as High Ion-Conductivity Solid Electrolyte Additive to Suppress Dendrite Growth at Li Metal Anode
journal, September 2018
- Hu, Jiulin; Chen, Keyi; Li, Chilin
- ACS Applied Materials & Interfaces, Vol. 10, Issue 40
Extending the Service Life of High-Ni Layered Oxides by Tuning the Electrode-Electrolyte Interphase
journal, September 2018
- Li, Jianyu; Li, Wangda; You, Ya
- Advanced Energy Materials, Vol. 8, Issue 29
Role of Electrolyte Oxidation and Difluorophosphoric Acid Generation in Crossover and Capacity Fade in Lithium Ion Batteries
journal, October 2021
- Jayawardana, Chamithri; Rodrigo, Nuwanthi; Parimalam, Bharathy
- ACS Energy Letters, Vol. 6, Issue 11
Enhanced Li+ ion transport in LiNi0.5Mn1.5O4 through control of site disorder
journal, January 2012
- Zheng, Jianming; Xiao, Jie; Yu, Xiqian
- Physical Chemistry Chemical Physics, Vol. 14, Issue 39
Prelithiation: A Crucial Strategy for Boosting the Practical Application of Next-Generation Lithium Ion Battery
journal, February 2021
- Wang, Fei; Wang, Bo; Li, Jingxuan
- ACS Nano, Vol. 15, Issue 2
LiNixFeyAlzO2, a new cobalt-free layered cathode material for advanced Li-ion batteries
journal, September 2020
- Muralidharan, Nitin; Essehli, Rachid; Hermann, Raphael P.
- Journal of Power Sources, Vol. 471
Zinc-Doped High-Nickel, Low-Cobalt Layered Oxide Cathodes for High-Energy-Density Lithium-Ion Batteries
journal, March 2021
- Cui, Zehao; Xie, Qiang; Manthiram, Arumugam
- ACS Applied Materials & Interfaces, Vol. 13, Issue 13
Liquid Polydimethylsiloxane Grafting to Enable Dendrite‐Free Li Plating for Highly Reversible Li‐Metal Batteries
journal, May 2019
- Meng, Junwei; Chu, Fulu; Hu, Jiulin
- Advanced Functional Materials, Vol. 29, Issue 30
Effects of Dissolved Transition Metals on the Electrochemical Performance and SEI Growth in Lithium-Ion Batteries
journal, January 2014
- Joshi, Tapesh; Eom, KwangSup; Yushin, Gleb
- Journal of The Electrochemical Society, Vol. 161, Issue 12
Advanced Electrolytes for Fast‐Charging High‐Voltage Lithium‐Ion Batteries in Wide‐Temperature Range
journal, April 2020
- Zhang, Xianhui; Zou, Lianfeng; Xu, Yaobin
- Advanced Energy Materials, Vol. 10, Issue 22
On the Beneficial Impact of Li 2 CO 3 as Electrolyte Additive in NCM523 ∥ Graphite Lithium Ion Cells Under High‐Voltage Conditions
journal, January 2021
- Klein, Sven; Harte, Patrick; Henschel, Jonas
- Advanced Energy Materials, Vol. 11, Issue 10
Application of Stabilized Lithium Metal Powder (SLMP®) in graphite anode – A high efficient prelithiation method for lithium-ion batteries
journal, August 2014
- Wang, Zhihui; Fu, Yanbao; Zhang, Zhengcheng
- Journal of Power Sources, Vol. 260, p. 57-61
Advances and Prospects of High‐Voltage Spinel Cathodes for Lithium‐Based Batteries
journal, February 2021
- Yu, Xingwen; Yu, Wiley A.; Manthiram, Arumugam
- Small Methods, Vol. 5, Issue 5
Transition Metal Dissolution, Ion Migration, Electrocatalytic Reduction and Capacity Loss in Lithium-Ion Full Cells
journal, December 2016
- Gilbert, James A.; Shkrob, Ilya A.; Abraham, Daniel P.
- Journal of The Electrochemical Society, Vol. 164, Issue 2
Effect of fluoroethylene carbonate and vinylene carbonate additives on full-cell optimization of Li-ion capacitors
journal, January 2021
- Ahn, Seongki; Fukushima, Minori; Nara, Hiroki
- Electrochemistry Communications, Vol. 122
A perspective on the high-voltage LiMn1.5Ni0.5O4 spinel cathode for lithium-ion batteries
journal, January 2014
- Manthiram, Arumugam; Chemelewski, Katharine; Lee, Eun-Sung
- Energy & Environmental Science, Vol. 7, Issue 4
Achieving Desirable Initial Coulombic Efficiencies and Full Capacity Utilization of Li‐Ion Batteries by Chemical Prelithiation of Graphite Anode
journal, April 2021
- Shen, Yifei; Shen, Xiaohui; Yang, Mei
- Advanced Functional Materials, Vol. 31, Issue 24
Dopant Distribution in Co-Free High-Energy Layered Cathode Materials
journal, November 2019
- Mu, Linqin; Zhang, Rui; Kan, Wang Hay
- Chemistry of Materials, Vol. 31, Issue 23
Formation and Inhibition of Metallic Lithium Microstructures in Lithium Batteries Driven by Chemical Crossover
journal, May 2017
- Li, Wangda; Kim, Un-Hyuck; Dolocan, Andrei
- ACS Nano, Vol. 11, Issue 6
Chemical Stability of Lithium 2-Trifluoromethyl-4,5-dicyanoimidazolide, an Electrolyte Salt for Li-Ion Cells
journal, December 2016
- Shkrob, Ilya A.; Pupek, Krzysztof Z.; Gilbert, James A.
- The Journal of Physical Chemistry C, Vol. 120, Issue 50
High-Performance LiNi 0.5 Mn 1.5 O 4 Spinel Controlled by Mn 3+ Concentration and Site Disorder
journal, March 2012
- Xiao, Jie; Chen, Xilin; Sushko, Peter V.
- Advanced Materials, Vol. 24, Issue 16
A reflection on lithium-ion battery cathode chemistry
journal, March 2020
- Manthiram, Arumugam
- Nature Communications, Vol. 11, Issue 1
Insight into the Atomic Structure of High-Voltage Spinel LiNi 0.5 Mn 1.5 O 4 Cathode Material in the First Cycle
journal, December 2014
- Lin, Mingxiang; Ben, Liubin; Sun, Yang
- Chemistry of Materials, Vol. 27, Issue 1
Insights into Li‐Rich Mn‐Based Cathode Materials with High Capacity: from Dimension to Lattice to Atom
journal, March 2021
- Cui, Shao‐Lun; Gao, Ming‐Yue; Li, Guo‐Ran
- Advanced Energy Materials, Vol. 12, Issue 4
Enabling high areal capacity for Co-free high voltage spinel materials in next-generation Li-ion batteries
journal, October 2020
- Li, Weikang; Cho, Yoon-Gyo; Yao, Weiliang
- Journal of Power Sources, Vol. 473
Synthesis, Modification, and Lithium‐Storage Properties of Spinel LiNi
0.5
Mn
1.5
O
4
journal, January 2021
- Chen, Junxin; Huang, Zhe; Zeng, Weihao
- ChemElectroChem, Vol. 8, Issue 4
Olivine LiFePO 4 : the remaining challenges for future energy storage
journal, January 2015
- Wang, Jiajun; Sun, Xueliang
- Energy & Environmental Science, Vol. 8, Issue 4
Zr-doping effect on the capacity retention of LiNi0.5Mn1.5O4–δ cycled between 5.0 and 1.0 V: In situ synchrotron X-Ray diffraction study
journal, November 2017
- Yoon, Jaesang; Jeong, Mihee; Bae, In Tae
- Journal of Power Sources, Vol. 368
Fluorophosphates: Next Generation Cathode Materials for Rechargeable Batteries
journal, July 2020
- Sharma, Lalit; Adiga, Shashishekar P.; Alshareef, Husam N.
- Advanced Energy Materials, Vol. 10, Issue 43
Some Fluorinated Carbonates as Electrolyte Additives for Li(Ni 0.4 Mn 0.4 Co 0.2 )O 2 /Graphite Pouch Cells
journal, January 2016
- Xia, Jian; Petibon, Remi; Xiao, A.
- Journal of The Electrochemical Society, Vol. 163, Issue 8
LiPO 2 F 2 as an Electrolyte Additive in Li[Ni 0.5 Mn 0.3 Co 0.2 ]O 2 /Graphite Pouch Cells
journal, January 2018
- Ma, Lin; Ellis, Leah; Glazier, S. L.
- Journal of The Electrochemical Society, Vol. 165, Issue 5
Studies of LiNi 0.5 Mn 1.5 O 4 as a Positive Electrode for Li-Ion Batteries: M 3+ Doping (M = Al, Fe, Co and Cr), Electrolyte Salts and LiNi 0.5 Mn 1.5 O 4 /Li 4 Ti 5 O 12 Cells
journal, January 2013
- Li, S. R.; Chen, C. H.; Dahn, J. R.
- Journal of The Electrochemical Society, Vol. 160, Issue 11
Electrolyte Therapy for Improving the Performance of LiNi 0.5 Mn 1.5 O 4 Cathodes Assembled Lithium–Ion Batteries
journal, April 2020
- Zou, Zhenyu; Xu, Hantao; Zhang, Huanrui
- ACS Applied Materials & Interfaces, Vol. 12, Issue 19
Effect of Substituting LiBF 4 for LiPF 6 in High Voltage Lithium-Ion Cells Containing Electrolyte Additives
journal, January 2016
- Ellis, L. D.; Xia, J.; Louli, A. J.
- Journal of The Electrochemical Society, Vol. 163, Issue 8
Investigation of Pre-lithiation in Graphite and Hard-Carbon Anodes Using Different Lithium Source Structures
journal, January 2017
- Shellikeri, A.; Watson, V.; Adams, D.
- Journal of The Electrochemical Society, Vol. 164, Issue 14
Morphological Evolution of High-Voltage Spinel LiNi 0.5 Mn 1.5 O 4 Cathode Materials for Lithium-Ion Batteries: The Critical Effects of Surface Orientations and Particle Size
journal, February 2016
- Liu, Haidong; Wang, Jun; Zhang, Xiaofei
- ACS Applied Materials & Interfaces, Vol. 8, Issue 7
Long-Term Cycling of a Mn-Rich High-Voltage Spinel Cathode by Stabilizing the Surface with a Small Dose of Iron
journal, November 2021
- Zou, Feng; Cui, Zehao; Nallan, Himamshu C.
- ACS Applied Energy Materials, Vol. 4, Issue 11
Liquid Ammonia Chemical Lithiation: An Approach for High-Energy and High-Voltage Si–Graphite|Li 1+ x Ni 0.5 Mn 1.5 O 4 Li-Ion Batteries
journal, June 2019
- Dose, Wesley M.; Blauwkamp, James; Piernas-Muñoz, María José
- ACS Applied Energy Materials, Vol. 2, Issue 7
Quantification of PF 5 and POF 3 from Side Reactions of LiPF 6 in Li-Ion Batteries
journal, January 2018
- Solchenbach, Sophie; Metzger, Michael; Egawa, Masamitsu
- Journal of The Electrochemical Society, Vol. 165, Issue 13
Influence of manganese(II), cobalt(II), and nickel(II) additives in electrolyte on performance of graphite anode for lithium-ion batteries
journal, February 2002
- Komaba, Shinichi; Kumagai, Naoaki; Kataoka, Yoichi
- Electrochimica Acta, Vol. 47, Issue 8
Li-rich cathodes for rechargeable Li-based batteries: reaction mechanisms and advanced characterization techniques
journal, January 2020
- Zuo, Wenhua; Luo, Mingzeng; Liu, Xiangsi
- Energy & Environmental Science, Vol. 13, Issue 12
Spinel LiNi0.5Mn1.5O4 and its derivatives as cathodes for high-voltage Li-ion batteries
journal, April 2010
- Liu, G. Q.; Wen, L.; Liu, Y. M.
- Journal of Solid State Electrochemistry, Vol. 14, Issue 12
LiNi0.5Mn1.5O4 Hollow Structures as High-Performance Cathodes for Lithium-Ion Batteries
journal, November 2011
- Zhou, Liang; Zhao, Dongyuan; Lou, XiongWen David
- Angewandte Chemie International Edition, Vol. 51, Issue 1
Nano‐Sized AlPO 4 Coating Layer on Graphite Powder to Improve the Electrochemical Properties of High‐Voltage Graphite/LiNi 0.5 Mn 1.5 O 4 Li‐Ion Cells
journal, June 2019
- Zeng, Huanna; He, Jia; Fang, Danyang
- Energy Technology, Vol. 7, Issue 9
Understanding Transition-Metal Dissolution Behavior in LiNi 0.5 Mn 1.5 O 4 High-Voltage Spinel for Lithium Ion Batteries
journal, July 2013
- Pieczonka, Nicholas P. W.; Liu, Zhongyi; Lu, Peng
- The Journal of Physical Chemistry C, Vol. 117, Issue 31
C–F-rich oil drop as a non-expendable fluid interface modifier with low surface energy to stabilize a Li metal anode
journal, January 2021
- Yang, Qifan; Hu, Jiulin; Meng, Junwei
- Energy & Environmental Science, Vol. 14, Issue 6
Lithium Bis(2,2,2-trifluoroethyl)phosphate Li[O 2 P(OCH 2 CF 3 ) 2 ]: A High Voltage Additive for LNMO/Graphite Cells
journal, January 2018
- Milien, Mickdy S.; Beyer, Hans; Beichel, Witali
- Journal of The Electrochemical Society, Vol. 165, Issue 11
A facile synthesis of non-aqueous LiPO2F2 solution as the electrolyte additive for high performance lithium ion batteries
journal, December 2020
- Zhao, Weimin; Ren, Fucheng; Yan, Qizhang
- Chinese Chemical Letters, Vol. 31, Issue 12