Two-step annealing induced structural rejuvenation: A cause for memory effect in metallic glasses

Qiu, K. K.; Wang, X. D.; Xu, T. D.; Cao, Q. P.; Ding, S. Q.; Zhang, D. X.; Beyer, K. A.; Jiang, J. Z.

doi:10.1016/j.mtphys.2022.100824

Title: Two-step annealing induced structural rejuvenation: A cause for memory effect in metallic glasses

Abstract

The structural origin of the memory effect is still elusive in glassy materials. Here, in this letter, the memory effect in a series of metallic glasses (MGs) is observed by two step annealing using differential scanning calorimetry (DSC) and molecular dynamics simulations. It demonstrates that the Kovacs peak can be reflected from not only the system potential energy but also the atomic dynamics, showing the memory effect could originate from the formation of more loose packing configurations around mobile atoms by structural rejuvenation in the second step of high temperature annealing. In contrast, the high-low temperature annealing protocol can only induce the monotonic relaxation. Therefore, our results pave a pathway to better understand the origin of memory effect in MGs and other glassy materials from their dynamics and local atomic structure.

Authors:

Qiu, K. K.; Wang, X. D.;

; Cao, Q. P.; Ding, S. Q.;

; Beyer, K. A.; Jiang, J. Z.

Publication Date:: Thu Aug 18 00:00:00 EDT 2022

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: Fundamental Research Funds for the Central Universities; USDOE Office of Science (SC), Basic Energy Sciences (BES); National Key Research and Development Program of China; Natural National Science Foundation of China (NSFC); National Science Foundation of Zhejiang Province

OSTI Identifier:: 1909349

Alternate Identifier(s):: OSTI ID: 1962143

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Materials Today Physics

Additional Journal Information:: Journal Volume: 27; Journal ID: ISSN 2542-5293

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: metallic glasses; Memory effect; atomic dynamics; local structure

Citation Formats


                    Qiu, K. K., Wang, X. D., Xu, T. D., Cao, Q. P., Ding, S. Q., Zhang, D. X., Beyer, K. A., and Jiang, J. Z. Two-step annealing induced structural rejuvenation: A cause for memory effect in metallic glasses.  United States: N. p., 2022. 
Web.  doi:10.1016/j.mtphys.2022.100824.

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                    Qiu, K. K., Wang, X. D., Xu, T. D., Cao, Q. P., Ding, S. Q., Zhang, D. X., Beyer, K. A., & Jiang, J. Z. Two-step annealing induced structural rejuvenation: A cause for memory effect in metallic glasses.  United States.  https://doi.org/10.1016/j.mtphys.2022.100824

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                    Qiu, K. K., Wang, X. D., Xu, T. D., Cao, Q. P., Ding, S. Q., Zhang, D. X., Beyer, K. A., and Jiang, J. Z. Thu .  
"Two-step annealing induced structural rejuvenation: A cause for memory effect in metallic glasses".  United States.  https://doi.org/10.1016/j.mtphys.2022.100824.  https://www.osti.gov/servlets/purl/1909349.

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@article{osti_1909349,

  title        = {Two-step annealing induced structural rejuvenation: A cause for memory effect in metallic glasses},

  author       = {Qiu, K. K. and Wang, X. D. and Xu, T. D. and Cao, Q. P. and Ding, S. Q. and Zhang, D. X. and Beyer, K. A. and Jiang, J. Z.},

  abstractNote = {The structural origin of the memory effect is still elusive in glassy materials. Here, in this letter, the memory effect in a series of metallic glasses (MGs) is observed by two step annealing using differential scanning calorimetry (DSC) and molecular dynamics simulations. It demonstrates that the Kovacs peak can be reflected from not only the system potential energy but also the atomic dynamics, showing the memory effect could originate from the formation of more loose packing configurations around mobile atoms by structural rejuvenation in the second step of high temperature annealing. In contrast, the high-low temperature annealing protocol can only induce the monotonic relaxation. Therefore, our results pave a pathway to better understand the origin of memory effect in MGs and other glassy materials from their dynamics and local atomic structure.},

  doi          = {10.1016/j.mtphys.2022.100824},

  journal      = {Materials Today Physics},

  number       = ,

  volume       = 27,

  place        = {United States},

  year         = {Thu Aug 18 00:00:00 EDT 2022},

  month        = {Thu Aug 18 00:00:00 EDT 2022}

}

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Title: Two-step annealing induced structural rejuvenation: A cause for memory effect in metallic glasses

Abstract

Citation Formats

Relaxation in glassforming liquids and amorphous solids journal, September 2000

Supercooled liquids and the glass transition journal, March 2001

Theoretical perspective on the glass transition and amorphous materials journal, June 2011

Glass Transition Thermodynamics and Kinetics journal, April 2013

Physical Aging in Polymer Glasses journal, March 1995

Structural rejuvenation in bulk metallic glasses journal, March 2015

Atomistic Simulation of Aging and Rejuvenation in Glasses journal, February 2000

Structural relaxation and rejuvenation in a metallic glass induced by shot-peening journal, December 2009

Effect of rolling deformation on the microstructure of bulk Cu60Zr20Ti20 metallic glass and its crystallization journal, September 2006

Effect of pre-existing shear bands on the tensile mechanical properties of a bulk metallic glass journal, February 2010

Atomic-level structural modifications induced by severe plastic shear deformation in bulk metallic glasses journal, January 2011

Structural rejuvenation in a bulk metallic glass induced by severe plastic deformation journal, January 2010

Rejuvenation of metallic glasses by non-affine thermal strain journal, August 2015

Controlled Rejuvenation of Amorphous Metals with Thermal Processing journal, May 2015

Revealing the structural heterogeneity of metallic glass: Mechanical spectroscopy and nanoindentation experiments journal, July 2021

Modification of atomic mobility in a Ti-based bulk metallic glass by plastic deformation or thermal annealing journal, September 2012

Dynamic relaxations and relaxation-property relationships in metallic glasses journal, December 2019

On cryothermal cycling as a method for inducing structural changes in metallic glasses journal, April 2018

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Intermediate structural state for maximizing the rejuvenation effect in metallic glass via thermo-cycling treatment journal, July 2019

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Memory formation in matter journal, July 2019

Structural relaxation and crossover effect in a metallic glass journal, June 1979

A semi-quantitative description of the kinetics of structural relaxation in amorphous Fe40Ni40B20 journal, November 1984

Memory effect in enthalpy relaxation of two metal–alloy glasses journal, November 2007

Crossover relaxation of the viscosity of Pd40Ni40P19Si1 near the glass transition journal, May 1989

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Can Aging Phenomena Discriminate Between the Droplet Model and a Hierarchical Description in Spin Glasses? journal, April 1992

Rejuvenation and Memory in Model Spin Glasses journal, January 2005

Kovacs-Like Memory Effect in Driven Granular Gases journal, May 2014

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Kovacs Memory Effect with an Optically Levitated Nanoparticle journal, September 2021

Nonmonotonic Aging and Memory Retention in Disordered Mechanical Systems journal, February 2017

Kovacs-Like Memory Effect in Athermal Systems: Linear Response Analysis journal, October 2017

Memory Effect Manifested by a Boson Peak in Metallic Glass journal, April 2016

Networks and Hierarchies: How Amorphous Materials Learn to Remember journal, October 2019

Activation Entropy as a Key Factor Controlling the Memory Effect in Glasses journal, September 2020

Shape memory effect in metallic glasses journal, October 2021

Computer simulation and experimental study of elastic properties of amorphous Cu-Zr alloys journal, November 2007

Two-dimensional detector software: From real detector to idealised image or two-theta scan journal, January 1996

Fast Parallel Algorithms for Short-Range Molecular Dynamics journal, March 1995

Canonical dynamics: Equilibrium phase-space distributions journal, March 1985

A unified formulation of the constant temperature molecular dynamics methods journal, July 1984

Role of string-like collective atomic motion on diffusion and structural relaxation in glass forming Cu-Zr alloys journal, April 2015

Random Packings and the Structure of Simple Liquids. I. The Geometry of Random Close Packing journal, November 1970

What Do We Learn from the Local Geometry of Glass-Forming Liquids? journal, August 2002

The glass transition as a free volume related kinetic phenomenon journal, March 1990

Enthalpy relaxation and recovery in amorphous materials journal, April 1994

Structural relaxation in a bulk metallic glass journal, September 2003

Reversible and irreversible β -relaxations in metallic glasses journal, March 2020

Rejuvenation and Memory Effects in a Structural Glass journal, June 2019

Memory formation in cyclically deformed amorphous solids and sphere assemblies journal, September 2018

Global memory from local hysteresis in an amorphous solid journal, January 2020

Self-Organized Short-Term Memories journal, May 1997

Relaxation in glassforming liquids and amorphous solids
journal, September 2000

Supercooled liquids and the glass transition
journal, March 2001

Theoretical perspective on the glass transition and amorphous materials
journal, June 2011

Glass Transition Thermodynamics and Kinetics
journal, April 2013

Physical Aging in Polymer Glasses
journal, March 1995

Structural rejuvenation in bulk metallic glasses
journal, March 2015

Atomistic Simulation of Aging and Rejuvenation in Glasses
journal, February 2000

Structural relaxation and rejuvenation in a metallic glass induced by shot-peening
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Effect of rolling deformation on the microstructure of bulk Cu60Zr20Ti20 metallic glass and its crystallization
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Effect of pre-existing shear bands on the tensile mechanical properties of a bulk metallic glass
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Atomic-level structural modifications induced by severe plastic shear deformation in bulk metallic glasses
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Structural rejuvenation in a bulk metallic glass induced by severe plastic deformation
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On cryothermal cycling as a method for inducing structural changes in metallic glasses
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Microscopic characterization of structural relaxation and cryogenic rejuvenation in metallic glasses
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Phase separation and crystallization in the Zr41.2–Ti13.8–Cu12.5–Ni10–Be22.5 bulk metallic glass determined by physical measurements and electron microscopy
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Memory formation in matter
journal, July 2019

Structural relaxation and crossover effect in a metallic glass
journal, June 1979

A semi-quantitative description of the kinetics of structural relaxation in amorphous Fe40Ni40B20
journal, November 1984

Memory effect in enthalpy relaxation of two metal–alloy glasses
journal, November 2007

Crossover relaxation of the viscosity of Pd40Ni40P19Si1 near the glass transition
journal, May 1989

Activation energy spectra and relaxation in amorphous materials
journal, January 1983

Can Aging Phenomena Discriminate Between the Droplet Model and a Hierarchical Description in Spin Glasses?
journal, April 1992

Rejuvenation and Memory in Model Spin Glasses
journal, January 2005

Kovacs-Like Memory Effect in Driven Granular Gases
journal, May 2014

Granular materials flow like complex fluids
journal, November 2017

Crossover (or Kovacs) Effect in an Aging Molecular Liquid
journal, January 2004

Kovacs Memory Effect with an Optically Levitated Nanoparticle
journal, September 2021

Nonmonotonic Aging and Memory Retention in Disordered Mechanical Systems
journal, February 2017

Kovacs-Like Memory Effect in Athermal Systems: Linear Response Analysis
journal, October 2017

Memory Effect Manifested by a Boson Peak in Metallic Glass
journal, April 2016

Networks and Hierarchies: How Amorphous Materials Learn to Remember
journal, October 2019

Activation Entropy as a Key Factor Controlling the Memory Effect in Glasses
journal, September 2020

Shape memory effect in metallic glasses
journal, October 2021

Computer simulation and experimental study of elastic properties of amorphous Cu-Zr alloys
journal, November 2007

Two-dimensional detector software: From real detector to idealised image or two-theta scan
journal, January 1996

Fast Parallel Algorithms for Short-Range Molecular Dynamics
journal, March 1995

Canonical dynamics: Equilibrium phase-space distributions
journal, March 1985

A unified formulation of the constant temperature molecular dynamics methods
journal, July 1984

Role of string-like collective atomic motion on diffusion and structural relaxation in glass forming Cu-Zr alloys
journal, April 2015

Random Packings and the Structure of Simple Liquids. I. The Geometry of Random Close Packing
journal, November 1970

What Do We Learn from the Local Geometry of Glass-Forming Liquids?
journal, August 2002

The glass transition as a free volume related kinetic phenomenon
journal, March 1990

Enthalpy relaxation and recovery in amorphous materials
journal, April 1994

Structural relaxation in a bulk metallic glass
journal, September 2003

Reversible and irreversible β -relaxations in metallic glasses
journal, March 2020

Rejuvenation and Memory Effects in a Structural Glass
journal, June 2019

Memory formation in cyclically deformed amorphous solids and sphere assemblies
journal, September 2018

Global memory from local hysteresis in an amorphous solid
journal, January 2020

Self-Organized Short-Term Memories
journal, May 1997