Shape memory effect in metallic glasses
Abstract
Shape memory effect (SME), mainly present in crystalline Ti-Ni alloys, is basically missing in metallic glasses (MGs) that lack the long-range periodic order of crystals. In this work, we report experimental results of SME in annealed MGs, in which the low-energy configuration state recovery is observed by both differential scanning calorimetry and X-ray photon correlation spectroscopy. We elucidate the origin of SME in MGs under the potential energy landscape framework, i.e., after annealing, the energy of MGs enters into a deep basin and atoms are located in the low-energy configuration state. Albeit deviating from their relative stable configurations by temperature changes, atoms in the annealed MGs tend to return to the low-energy atomic configurations along certain trajectories as pre-annealing temperature is approached, These results could extend the application of MGs as functional materials by directionally manipulating their energy states via annealing and rejuvenation.
- Authors:
-
- Zhejiang Univ., Hangzhou (China)
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC); National Natural Science Foundation of China (NSFC); National Key Research and Development Program of China; Zhejiang Provincial Natural Science Foundation of China; Fundamental Research Funds for the Central Universities
- OSTI Identifier:
- 1840033
- Grant/Contract Number:
- AC02-06CH11357; 51671169; U1832203; 11975202; 2017YFA0403400; Y4110192; LZ20E010002
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Matter (Online)
- Additional Journal Information:
- Journal Name: Matter (Online); Journal Volume: 4; Journal Issue: 10; Journal ID: ISSN 2590-2385
- Publisher:
- Cell Press/Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; X-ray photon correlation spectroscopy; atomic dynamics; metallic glass; shape memory effect
Citation Formats
Xu, Tianding, Wang, Xiao-Dong, Dufresne, Eric M., Ren, Yang, Cao, Qingping, Zhang, Dongxian, and Jiang, Jian-Zhong. Shape memory effect in metallic glasses. United States: N. p., 2021.
Web. doi:10.1016/j.matt.2021.08.010.
Xu, Tianding, Wang, Xiao-Dong, Dufresne, Eric M., Ren, Yang, Cao, Qingping, Zhang, Dongxian, & Jiang, Jian-Zhong. Shape memory effect in metallic glasses. United States. https://doi.org/10.1016/j.matt.2021.08.010
Xu, Tianding, Wang, Xiao-Dong, Dufresne, Eric M., Ren, Yang, Cao, Qingping, Zhang, Dongxian, and Jiang, Jian-Zhong. Wed .
"Shape memory effect in metallic glasses". United States. https://doi.org/10.1016/j.matt.2021.08.010. https://www.osti.gov/servlets/purl/1840033.
@article{osti_1840033,
title = {Shape memory effect in metallic glasses},
author = {Xu, Tianding and Wang, Xiao-Dong and Dufresne, Eric M. and Ren, Yang and Cao, Qingping and Zhang, Dongxian and Jiang, Jian-Zhong},
abstractNote = {Shape memory effect (SME), mainly present in crystalline Ti-Ni alloys, is basically missing in metallic glasses (MGs) that lack the long-range periodic order of crystals. In this work, we report experimental results of SME in annealed MGs, in which the low-energy configuration state recovery is observed by both differential scanning calorimetry and X-ray photon correlation spectroscopy. We elucidate the origin of SME in MGs under the potential energy landscape framework, i.e., after annealing, the energy of MGs enters into a deep basin and atoms are located in the low-energy configuration state. Albeit deviating from their relative stable configurations by temperature changes, atoms in the annealed MGs tend to return to the low-energy atomic configurations along certain trajectories as pre-annealing temperature is approached, These results could extend the application of MGs as functional materials by directionally manipulating their energy states via annealing and rejuvenation.},
doi = {10.1016/j.matt.2021.08.010},
journal = {Matter (Online)},
number = 10,
volume = 4,
place = {United States},
year = {Wed Oct 06 00:00:00 EDT 2021},
month = {Wed Oct 06 00:00:00 EDT 2021}
}
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