Use of Ethylene Carbonate Free Ester Solvent Systems with Alternative Lithium Salts for Improved Low-Temperature Performance in NCM622∣∣ Graphite Li-ion Batteries

Rodrigo, Nuwanthi D.; Jayawardana, Chamithri; Rynearson, Leah; Hu, Enyuan; Yang, Xiao-Qing; Lucht, Brett L.

doi:10.1149/1945-7111/ac9d0a

Title: Use of Ethylene Carbonate Free Ester Solvent Systems with Alternative Lithium Salts for Improved Low-Temperature Performance in NCM622∣∣ Graphite Li-ion Batteries

Abstract

An investigation of alternative lithium salts, lithium tetrafluoroborate (LiBF ₄ ), lithium difluoro(oxalato)borate (LiDFOB) and lithium hexafluorophosphate (LiPF ₆ ), in novel ester-based (methyl acetate/fluoroethylene carbonate- MA/FEC or methyl propionate/fluoroethylene carbonate- MP/FEC) electrolyte formulations has been conducted in LiNi _0.6 Co _0.2 Mn _0.2 O ₂ (NCM622)/graphite cells to improve low temperature cycling performance of lithium ion batteries at −20 °C. Improved low temperature performance was observed with all the lithium salts in MA/FEC electrolyte while comparable room temperature (25 °C) capacities were observed with LiPF ₆ salt only. Detailed ex-situ analysis of surface films generated with LiBF ₄ , LiDFOB and LiPF ₆ in ester-based electrolytes reveals that the solid electrolyte interphase (SEI) is predominately composed of lithium salt decompaction products and addition of 10% FEC (by volume%) may not be sufficient at forming a protective SEI.

Authors:

;

; Hu, Enyuan;

;

Publication Date:: Thu Nov 03 00:00:00 EDT 2022

Research Org.:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office

OSTI Identifier:: 1896953

Alternate Identifier(s):: OSTI ID: 1894424; OSTI ID: 1898591

Report Number(s):: BNL-223721-2022-JAAM
Journal ID: ISSN 0013-4651

Grant/Contract Number:: SC0012704

Resource Type:: Published Article

Journal Name:: Journal of the Electrochemical Society

Additional Journal Information:: Journal Name: Journal of the Electrochemical Society Journal Volume: 169 Journal Issue: 11; Journal ID: ISSN 0013-4651

Publisher:: The Electrochemical Society

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Rodrigo, Nuwanthi D., Jayawardana, Chamithri, Rynearson, Leah, Hu, Enyuan, Yang, Xiao-Qing, and Lucht, Brett L. Use of Ethylene Carbonate Free Ester Solvent Systems with Alternative Lithium Salts for Improved Low-Temperature Performance in NCM622∣∣ Graphite Li-ion Batteries.  United States: N. p., 2022. 
Web.  doi:10.1149/1945-7111/ac9d0a.

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                    Rodrigo, Nuwanthi D., Jayawardana, Chamithri, Rynearson, Leah, Hu, Enyuan, Yang, Xiao-Qing, & Lucht, Brett L. Use of Ethylene Carbonate Free Ester Solvent Systems with Alternative Lithium Salts for Improved Low-Temperature Performance in NCM622∣∣ Graphite Li-ion Batteries.  United States.  https://doi.org/10.1149/1945-7111/ac9d0a

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                    Rodrigo, Nuwanthi D., Jayawardana, Chamithri, Rynearson, Leah, Hu, Enyuan, Yang, Xiao-Qing, and Lucht, Brett L. Thu .  
"Use of Ethylene Carbonate Free Ester Solvent Systems with Alternative Lithium Salts for Improved Low-Temperature Performance in NCM622∣∣ Graphite Li-ion Batteries".  United States.  https://doi.org/10.1149/1945-7111/ac9d0a.

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@article{osti_1896953,

  title        = {Use of Ethylene Carbonate Free Ester Solvent Systems with Alternative Lithium Salts for Improved Low-Temperature Performance in NCM622∣∣ Graphite Li-ion Batteries},

  author       = {Rodrigo, Nuwanthi D. and Jayawardana, Chamithri and Rynearson, Leah and Hu, Enyuan and Yang, Xiao-Qing and Lucht, Brett L.},

  abstractNote = {An investigation of alternative lithium salts, lithium tetrafluoroborate (LiBF 4 ), lithium difluoro(oxalato)borate (LiDFOB) and lithium hexafluorophosphate (LiPF 6 ), in novel ester-based (methyl acetate/fluoroethylene carbonate- MA/FEC or methyl propionate/fluoroethylene carbonate- MP/FEC) electrolyte formulations has been conducted in LiNi 0.6 Co 0.2 Mn 0.2 O 2 (NCM622)/graphite cells to improve low temperature cycling performance of lithium ion batteries at −20 °C. Improved low temperature performance was observed with all the lithium salts in MA/FEC electrolyte while comparable room temperature (25 °C) capacities were observed with LiPF 6 salt only. Detailed ex-situ analysis of surface films generated with LiBF 4 , LiDFOB and LiPF 6 in ester-based electrolytes reveals that the solid electrolyte interphase (SEI) is predominately composed of lithium salt decompaction products and addition of 10% FEC (by volume%) may not be sufficient at forming a protective SEI.},

  doi          = {10.1149/1945-7111/ac9d0a},

  journal      = {Journal of the Electrochemical Society},

  number       = 11,

  volume       = 169,

  place        = {United States},

  year         = {Thu Nov 03 00:00:00 EDT 2022},

  month        = {Thu Nov 03 00:00:00 EDT 2022}

}

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Title: Use of Ethylene Carbonate Free Ester Solvent Systems with Alternative Lithium Salts for Improved Low-Temperature Performance in NCM622∣∣ Graphite Li-ion Batteries

Abstract

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