Synthesis and Properties of Stable Sub-2-nm-Thick Aluminum Nanosheets: Oxygen Passivation and Two-Photon Luminescence
Abstract
The high reductivity of aluminum (Al) implies the utmost difficulty in achieving oxygen-resistant, ultrathin Al nanostructures. Herein, we demonstrate that sub-2-nm-thick Al nanosheets with ambient stability can be synthesized through a facile wet-chemical approach. Selective oxygen adsorption on the (111) facets of the face-centered cubic (fcc) Al has been revealed as the reason of controlling the morphology and stability of Al nanosheets, tailoring the thickness from 18 nm to 1.5 nm. Within the (111) surface passivation, Al nanosheets have achieved satisfactory stability, ensuring the possibility to study thickness-dependent localized surface plasmon resonance from visible to near-infrared (near-IR) region, and significantly enhanced two-photon luminescence. Furthermore, this work demonstrates, for the first time, the feasibility in obtaining stable ultrathin nanostructures of Al metal, which paves the way toward optical applications of Al as a sustainable plasmonic material, and shows great potential in the synthesis of other active metal-based nanomaterials.
- Authors:
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division
- OSTI Identifier:
- 1877703
- Alternate Identifier(s):
- OSTI ID: 1579901
- Report Number(s):
- BNL-212414-2019-JAAM
Journal ID: ISSN 2451-9294; S2451929419305145; PII: S2451929419305145
- Grant/Contract Number:
- SC0012704; 2016YFF0204402
- Resource Type:
- Published Article
- Journal Name:
- Chem
- Additional Journal Information:
- Journal Name: Chem Journal Volume: 6 Journal Issue: 2; Journal ID: ISSN 2451-9294
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Luo, Liang, Li, Yang, Sun, Xiong, Li, Jing, Hu, Enyuan, Liu, Yinglan, Tian, Yang, Yang, Xiao-Qing, Li, Yaping, Lin, Wen-Feng, Kuang, Yun, Liu, Wen, and Sun, Xiaoming. Synthesis and Properties of Stable Sub-2-nm-Thick Aluminum Nanosheets: Oxygen Passivation and Two-Photon Luminescence. United States: N. p., 2020.
Web. doi:10.1016/j.chempr.2019.11.004.
Luo, Liang, Li, Yang, Sun, Xiong, Li, Jing, Hu, Enyuan, Liu, Yinglan, Tian, Yang, Yang, Xiao-Qing, Li, Yaping, Lin, Wen-Feng, Kuang, Yun, Liu, Wen, & Sun, Xiaoming. Synthesis and Properties of Stable Sub-2-nm-Thick Aluminum Nanosheets: Oxygen Passivation and Two-Photon Luminescence. United States. https://doi.org/10.1016/j.chempr.2019.11.004
Luo, Liang, Li, Yang, Sun, Xiong, Li, Jing, Hu, Enyuan, Liu, Yinglan, Tian, Yang, Yang, Xiao-Qing, Li, Yaping, Lin, Wen-Feng, Kuang, Yun, Liu, Wen, and Sun, Xiaoming. Sat .
"Synthesis and Properties of Stable Sub-2-nm-Thick Aluminum Nanosheets: Oxygen Passivation and Two-Photon Luminescence". United States. https://doi.org/10.1016/j.chempr.2019.11.004.
@article{osti_1877703,
title = {Synthesis and Properties of Stable Sub-2-nm-Thick Aluminum Nanosheets: Oxygen Passivation and Two-Photon Luminescence},
author = {Luo, Liang and Li, Yang and Sun, Xiong and Li, Jing and Hu, Enyuan and Liu, Yinglan and Tian, Yang and Yang, Xiao-Qing and Li, Yaping and Lin, Wen-Feng and Kuang, Yun and Liu, Wen and Sun, Xiaoming},
abstractNote = {The high reductivity of aluminum (Al) implies the utmost difficulty in achieving oxygen-resistant, ultrathin Al nanostructures. Herein, we demonstrate that sub-2-nm-thick Al nanosheets with ambient stability can be synthesized through a facile wet-chemical approach. Selective oxygen adsorption on the (111) facets of the face-centered cubic (fcc) Al has been revealed as the reason of controlling the morphology and stability of Al nanosheets, tailoring the thickness from 18 nm to 1.5 nm. Within the (111) surface passivation, Al nanosheets have achieved satisfactory stability, ensuring the possibility to study thickness-dependent localized surface plasmon resonance from visible to near-infrared (near-IR) region, and significantly enhanced two-photon luminescence. Furthermore, this work demonstrates, for the first time, the feasibility in obtaining stable ultrathin nanostructures of Al metal, which paves the way toward optical applications of Al as a sustainable plasmonic material, and shows great potential in the synthesis of other active metal-based nanomaterials.},
doi = {10.1016/j.chempr.2019.11.004},
journal = {Chem},
number = 2,
volume = 6,
place = {United States},
year = {Sat Feb 01 00:00:00 EST 2020},
month = {Sat Feb 01 00:00:00 EST 2020}
}
https://doi.org/10.1016/j.chempr.2019.11.004
Web of Science
Works referenced in this record:
Ultrathin rhodium nanosheets
journal, January 2014
- Duan, Haohong; Yan, Ning; Yu, Rong
- Nature Communications, Vol. 5, Issue 1
Seeded Growth of Uniform Ag Nanoplates with High Aspect Ratio and Widely Tunable Surface Plasmon Bands
journal, December 2010
- Zhang, Qiao; Hu, Yongxing; Guo, Shirui
- Nano Letters, Vol. 10, Issue 12
Ab-initio pseudopotential study of electronic structure and chemisorption of oxygen on aluminium surface
journal, February 2009
- Khan, Gobinda Gopal; Bandyopadhyay, N. R.; Basumallick, A.
- Journal of Physics and Chemistry of Solids, Vol. 70, Issue 2
Oxygen-Assisted Chemical Vapor Deposition Growth of Large Single-Crystal and High-Quality Monolayer MoS 2
journal, December 2015
- Chen, Wei; Zhao, Jing; Zhang, Jing
- Journal of the American Chemical Society, Vol. 137, Issue 50
An ESCA method for determining the oxide thickness on aluminum alloys
journal, January 1990
- Strohmeier, Brian R.
- Surface and Interface Analysis, Vol. 15, Issue 1
Solution phase chemical synthesis of nano aluminium particles stabilized in poly(vinylpyrrolidone) and poly(methylmethacrylate) matrices
journal, January 2010
- Ghanta, Sekher Reddy; Muralidharan, Krishnamurthi
- Nanoscale, Vol. 2, Issue 6
Control of Si Nanowire Growth by Oxygen
journal, June 2006
- Kodambaka, Suneel; Hannon, James B.; Tromp, Rudolf M.
- Nano Letters, Vol. 6, Issue 6, p. 1292-1296
Vivid, full-color aluminum plasmonic pixels
journal, September 2014
- Olson, Jana; Manjavacas, Alejandro; Liu, Lifei
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 40
2D Metals by Repeated Size Reduction
journal, July 2016
- Liu, Hanwen; Tang, Hao; Fang, Minghao
- Advanced Materials, Vol. 28, Issue 37
Synthesis of Al nanoparticles: Transmission electron microscopy, thermal and spectral studies
journal, June 2012
- Chandra, Sulekh; Kumar, Avdhesh; Tomar, Praveen Kumar
- Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, Vol. 92
Highly Crystalline Multimetallic Nanoframes with Three-Dimensional Electrocatalytic Surfaces
journal, February 2014
- Chen, C.; Kang, Y.; Huo, Z.
- Science, Vol. 343, Issue 6177
Synthesis of Ultrathin PdCu Alloy Nanosheets Used as a Highly Efficient Electrocatalyst for Formic Acid Oxidation
journal, June 2017
- Yang, Nailiang; Zhang, Zhicheng; Chen, Bo
- Advanced Materials, Vol. 29, Issue 29
Aluminum for Plasmonics
journal, December 2013
- Knight, Mark W.; King, Nicholas S.; Liu, Lifei
- ACS Nano, Vol. 8, Issue 1
An ultrafast rechargeable aluminium-ion battery
journal, April 2015
- Lin, Meng-Chang; Gong, Ming; Lu, Bingan
- Nature, Vol. 520, Issue 7547
Single-Crystalline Ultrathin Nickel Nanosheets Array from In Situ Topotactic Reduction for Active and Stable Electrocatalysis
journal, November 2015
- Kuang, Yun; Feng, Guang; Li, Pengsong
- Angewandte Chemie International Edition, Vol. 55, Issue 2
Preparation of Al nanoparticles in a controlled environment
journal, May 1994
- Sun, X. K.; Xu, J.; Chen, W. X.
- Nanostructured Materials, Vol. 4, Issue 3
An XPS study of the elemental enrichment on aluminum alloy surfaces from chemical cleaning
journal, March 2001
- Moffitt, C. E.; Wieliczka, D. M.; Yasuda, H. K.
- Surface and Coatings Technology, Vol. 137, Issue 2-3
Synthesis of hexagonal close-packed gold nanostructures
journal, April 2011
- Huang, Xiao; Li, Shaozhou; Huang, Yizhong
- Nature Communications, Vol. 2, Issue 1
FUNCTIONAL OXIDE NANOBELTS: Materials, Properties and Potential Applications in Nanosystems and Biotechnology
journal, June 2004
- Wang, Zhong Lin
- Annual Review of Physical Chemistry, Vol. 55, Issue 1
Amorphous/Crystalline Hetero-Phase Pd Nanosheets: One-Pot Synthesis and Highly Selective Hydrogenation Reaction
journal, August 2018
- Yang, Nailiang; Cheng, Hongfei; Liu, Xiaozhi
- Advanced Materials, Vol. 30, Issue 39
Formation and Properties of Stabilized Aluminum Nanoparticles
journal, February 2009
- Meziani, Mohammed J.; Bunker, Christopher E.; Lu, Fushen
- ACS Applied Materials & Interfaces, Vol. 1, Issue 3
Multi-Atomic Layers of Metallic Aluminum for Ultralong Life Lithium Storage with High Volumetric Capacity
journal, May 2017
- Gu, Jianan; Li, Bin; Du, Zhiguo
- Advanced Functional Materials, Vol. 27, Issue 27
Ultrastable atomic copper nanosheets for selective electrochemical reduction of carbon dioxide
journal, September 2017
- Dai, Lei; Qin, Qing; Wang, Pei
- Science Advances, Vol. 3, Issue 9
Aluminum for Nonlinear Plasmonics: Resonance-Driven Polarized Luminescence of Al, Ag, and Au Nanoantennas
journal, November 2011
- Castro-Lopez, Marta; Brinks, Daan; Sapienza, Riccardo
- Nano Letters, Vol. 11, Issue 11
Aluminum Nanoparticles Capped by Polymerization of Alkyl-Substituted Epoxides: Ratio-Dependent Stability and Particle Size
journal, June 2011
- Hammerstroem, Douglas W.; Burgers, Mark A.; Chung, Stephen W.
- Inorganic Chemistry, Vol. 50, Issue 11
Shape-Controlled Synthesis of Gold and Silver Nanoparticles
journal, December 2002
- Sun, Yugang; Xia, Younan
- Science, Vol. 298, Issue 5601, p. 2176-2179
Oxygen Molecule Dissociation on the Al(111) Surface
journal, January 2000
- Honkala, Karoliina; Laasonen, Kari
- Physical Review Letters, Vol. 84, Issue 4
A Laser Ablation Method for the Synthesis of Crystalline Semiconductor Nanowires
journal, January 1998
- Morales, Alfredo M.; Lieber, Charles M.
- Science, Vol. 279, Issue 5348, p. 208-211
Control of Photoluminescence Properties of CdSe Nanocrystals in Growth
journal, March 2002
- Qu, Lianhua; Peng, Xiaogang
- Journal of the American Chemical Society, Vol. 124, Issue 9
Ru Nanocrystals with Shape-Dependent Surface-Enhanced Raman Spectra and Catalytic Properties: Controlled Synthesis and DFT Calculations
journal, December 2012
- Yin, An-Xiang; Liu, Wen-Chi; Ke, Jun
- Journal of the American Chemical Society, Vol. 134, Issue 50
Capping and Passivation of Aluminum Nanoparticles Using Alkyl-Substituted Epoxides
journal, July 2009
- Chung, Stephen W.; Guliants, Elena A.; Bunker, Christopher E.
- Langmuir, Vol. 25, Issue 16
Suppression of aluminum corrosion by using high concentration LiTFSI electrolyte
journal, June 2013
- Matsumoto, Kazuaki; Inoue, Kazuhiko; Nakahara, Kentaro
- Journal of Power Sources, Vol. 231
Efficient Tandem Polymer Solar Cells Fabricated by All-Solution Processing
journal, July 2007
- Kim, Jin Young; Lee, Kwanghee; Coates, Nelson E.
- Science, Vol. 317, Issue 5835, p. 222-225
Seeded High Yield Synthesis of Short Au Nanorods in Aqueous Solution
journal, July 2004
- Sau, Tapan K.; Murphy, Catherine J.
- Langmuir, Vol. 20, Issue 15
Oxygen mediated synthesis of high quality InN nanowires above their decomposition temperature
journal, January 2014
- Quddus, Ehtesham B.; Wilson, Alina; Webb, Richard A.
- Nanoscale, Vol. 6, Issue 2
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
journal, January 2016
- Gao, Shan; Lin, Yue; Jiao, Xingchen
- Nature, Vol. 529, Issue 7584
Epitaxial Growth and Photochemical Annealing of Graded CdS/ZnS Shells on Colloidal CdSe Nanorods
journal, June 2002
- Manna, Liberato; Scher, Erik C.; Li, Liang-Shi
- Journal of the American Chemical Society, Vol. 124, Issue 24, p. 7136-7145
Aluminum Plasmonic Nanoantennas
journal, October 2012
- Knight, Mark W.; Liu, Lifei; Wang, Yumin
- Nano Letters, Vol. 12, Issue 11
Generation and characterization of nano aluminium powder obtained through wire explosion process
journal, April 2007
- Sindhu, T. K.; Sarathi, R.; Chakravarthy, S. R.
- Bulletin of Materials Science, Vol. 30, Issue 2
Chemical synthesis of aluminum nanoparticles
journal, May 2013
- Ghanta, Sekher Reddy; Muralidharan, Krishnamurthi
- Journal of Nanoparticle Research, Vol. 15, Issue 6
Indium phosphide nanowires as building blocks for nanoscale electronic and optoelectronic devices
journal, January 2001
- Duan, Xiangfeng; Huang, Yu; Cui, Yi
- Nature, Vol. 409, Issue 6816, p. 66-69
Aluminum Nanocrystals
journal, March 2015
- McClain, Michael J.; Schlather, Andrea E.; Ringe, Emilie
- Nano Letters, Vol. 15, Issue 4
Quantification of oxide film thickness at the surface of aluminium using XPS
journal, January 2002
- Alexander, M. R.; Thompson, G. E.; Zhou, X.
- Surface and Interface Analysis, Vol. 34, Issue 1
Freestanding palladium nanosheets with plasmonic and catalytic properties
journal, December 2010
- Huang, Xiaoqing; Tang, Shaoheng; Mu, Xiaoliang
- Nature Nanotechnology, Vol. 6, Issue 1
Submonolayered Ru Deposited on Ultrathin Pd Nanosheets used for Enhanced Catalytic Applications
journal, November 2016
- Zhang, Zhicheng; Liu, Ye; Chen, Bo
- Advanced Materials, Vol. 28, Issue 46
Accuracy of pair distribution function analysis applied to crystalline and non-crystalline materials
journal, May 1992
- Toby, B. H.; Egami, T.
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 48, Issue 3