High-temperature superelasticity in NiTiPt and NiTiPd shape memory alloys
Abstract
Alloying NiTi shape memory alloys with sufficient Pt and Pd at the expense of Ni has been shown to increase transformation temperatures well above those possible with the binary composition, enabling consideration of a new class of high-temperature mechanical sensors and actuators. To achieve shape memory behavior at temperatures greater than 200 °C, previous studies of NiTiPt and NiTiPd compositions have focused primarily on alloys with greater than 16 at.% Pt and 25 at.% Pd. While generally not the focus, none of these previous studies demonstrated superelastic behavior at high temperatures. In an effort to identify alloys that transform to austenite at approximately 200 °C and exhibit superelastic behavior with recoverable strains greater than 2%, a series of Ti-rich NiTiPt ternary alloys with 15.5–16.5 at.% Pt, and Ti-rich NiTiPd ternary alloys with 25–26 at.% Pd have been targeted. The polycrystalline alloys were processed via arc melting followed by homogenization heat treatment. Thermomechanical properties were measured using electro-discharge machined tension test coupons and a miniature load frame equipped with a clamshell furnace. Ultimately, superelasticity in uniaxial tension with clear plateau regions was demonstrated and characterized in these alloys at temperatures between 219 °C and 270 °C.
- Authors:
-
[1];
- Department of Engineering Sciences, Sandia National Laboratories, Albuquerque, NM, USA
- NASA Glenn Research Center, Cleveland, OH, USA
- Publication Date:
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1875004
- Resource Type:
- Published Article
- Journal Name:
- Journal of Intelligent Material Systems and Structures
- Additional Journal Information:
- Journal Name: Journal of Intelligent Material Systems and Structures Journal Volume: 34 Journal Issue: 4; Journal ID: ISSN 1045-389X
- Publisher:
- SAGE Publications
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Massad, Jordan E., Buchheit, Thomas E., Susan, Donald F., Noebe, Ronald D., and McElhanon, James R. High-temperature superelasticity in NiTiPt and NiTiPd shape memory alloys. United States: N. p., 2022.
Web. doi:10.1177/1045389X221105885.
Massad, Jordan E., Buchheit, Thomas E., Susan, Donald F., Noebe, Ronald D., & McElhanon, James R. High-temperature superelasticity in NiTiPt and NiTiPd shape memory alloys. United States. https://doi.org/10.1177/1045389X221105885
Massad, Jordan E., Buchheit, Thomas E., Susan, Donald F., Noebe, Ronald D., and McElhanon, James R. Wed .
"High-temperature superelasticity in NiTiPt and NiTiPd shape memory alloys". United States. https://doi.org/10.1177/1045389X221105885.
@article{osti_1875004,
title = {High-temperature superelasticity in NiTiPt and NiTiPd shape memory alloys},
author = {Massad, Jordan E. and Buchheit, Thomas E. and Susan, Donald F. and Noebe, Ronald D. and McElhanon, James R.},
abstractNote = {Alloying NiTi shape memory alloys with sufficient Pt and Pd at the expense of Ni has been shown to increase transformation temperatures well above those possible with the binary composition, enabling consideration of a new class of high-temperature mechanical sensors and actuators. To achieve shape memory behavior at temperatures greater than 200 °C, previous studies of NiTiPt and NiTiPd compositions have focused primarily on alloys with greater than 16 at.% Pt and 25 at.% Pd. While generally not the focus, none of these previous studies demonstrated superelastic behavior at high temperatures. In an effort to identify alloys that transform to austenite at approximately 200 °C and exhibit superelastic behavior with recoverable strains greater than 2%, a series of Ti-rich NiTiPt ternary alloys with 15.5–16.5 at.% Pt, and Ti-rich NiTiPd ternary alloys with 25–26 at.% Pd have been targeted. The polycrystalline alloys were processed via arc melting followed by homogenization heat treatment. Thermomechanical properties were measured using electro-discharge machined tension test coupons and a miniature load frame equipped with a clamshell furnace. Ultimately, superelasticity in uniaxial tension with clear plateau regions was demonstrated and characterized in these alloys at temperatures between 219 °C and 270 °C.},
doi = {10.1177/1045389X221105885},
journal = {Journal of Intelligent Material Systems and Structures},
number = 4,
volume = 34,
place = {United States},
year = {Wed Jul 06 00:00:00 EDT 2022},
month = {Wed Jul 06 00:00:00 EDT 2022}
}
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1177/1045389X221105885
https://doi.org/10.1177/1045389X221105885
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Improvement of a Ti50Pd30Ni20 high temperature shape memory alloy by thermomechanical treatments
journal, May 1994
- Golberg, D.; Xu, Ya; Murakami, Y.
- Scripta Metallurgica et Materialia, Vol. 30, Issue 10
Martensite structure in Ti–Ni–Hf–Cu quaternary alloy ribbons containing (Ti,Hf)2Ni precipitates
journal, June 2010
- Meng, X. L.; Cai, W.; Fu, Y. D.
- Acta Materialia, Vol. 58, Issue 10
High-temperature superelasticity of Ni50.6Ti24.4Hf25.0 shape memory alloy
journal, May 2015
- Patriarca, Luca; Sehitoglu, Huseyin
- Scripta Materialia, Vol. 101
Iron-based superelastic alloys with near-constant critical stress temperature dependence
journal, August 2020
- Xia, Ji; Noguchi, Yuki; Xu, Xiao
- Science, Vol. 369, Issue 6505
Tensile behavior of Ti50.6Pd30Ni19.4 alloy under different tensile conditions
journal, February 2002
- Tian, Qingchao; Wu, Jiansheng
- Materials Science and Engineering: A, Vol. 325, Issue 1-2
FeMnNiAl Iron-Based Shape Memory Alloy: Promises and Challenges
journal, August 2019
- Abuzaid, W.; Wu, Y.; Sidharth, R.
- Shape Memory and Superelasticity, Vol. 5, Issue 3
Microstructural characterization and superelastic response of a Ni50.3Ti29.7Zr20 high-temperature shape memory alloy
journal, June 2014
- Evirgen, A.; Karaman, I.; Santamarta, R.
- Scripta Materialia, Vol. 81
Microstructure and transformation related behaviors of a Ni45.3Ti29.7Hf20Cu5 high temperature shape memory alloy
journal, March 2015
- Karaca, H. E.; Acar, E.; Ded, G. S.
- Materials Science and Engineering: A, Vol. 627
The Effect of Uniaxial Cyclic Deformation on the Evolution of Phase Transformation Fronts in Pseudoelastic NiTi Wire
journal, February 2002
- Iadicola, Mark A.; Shaw, John A.
- Journal of Intelligent Material Systems and Structures, Vol. 13, Issue 2-3
Compressive response of nickel-rich NiTiHf high-temperature shape memory single crystals along the [111] orientation
journal, October 2011
- Karaca, H. E.; Saghaian, S. M.; Basaran, B.
- Scripta Materialia, Vol. 65, Issue 7
Structure and thermomechanical behavior of NiTiPt shape memory alloy wires
journal, January 2009
- Lin, B.; Gall, K.; Maier, H.
- Acta Biomaterialia, Vol. 5, Issue 1
Characteristics of Ti50Pd30Ni20 high-temperature shape memory alloy
journal, January 1995
- Golberg, D.; Xu, Ya; Murakami, Y.
- Intermetallics, Vol. 3, Issue 1
Load-biased shape-memory and superelastic properties of a precipitation strengthened high-temperature Ni50.3Ti29.7Hf20 alloy
journal, April 2011
- Bigelow, G. S.; Garg, A.; Padula II, S. A.
- Scripta Materialia, Vol. 64, Issue 8
Shape memory characteristics of Ti49.5Ni25Pd25Sc0.5 high-temperature shape memory alloy after severe plastic deformation
journal, July 2011
- Atli, K. C.; Karaman, I.; Noebe, R. D.
- Acta Materialia, Vol. 59, Issue 12
Effect of pseudoelastic cycling on the Clausius–Clapeyron relation for stress-induced martensitic transformation in NiTi
journal, January 2008
- Liu, Yinong; Mahmud, Abdus; Kursawe, Fabian
- Journal of Alloys and Compounds, Vol. 449, Issue 1-2
Characterization of Ternary NiTiPd High-Temperature Shape-Memory Alloys under Load-Biased Thermal Cycling
journal, July 2010
- Bigelow, Glen S.; Padula, Santo A.; Garg, Anita
- Metallurgical and Materials Transactions A, Vol. 41, Issue 12
Ratchetting deformation of super-elastic and shape-memory NiTi alloys
journal, February 2009
- Kang, Guozheng; Kan, Qianhua; Qian, Linmao
- Mechanics of Materials, Vol. 41, Issue 2
The effect of isothermal mechanical cycling on Cu–13.3Al–4.0Ni (wt.%) shape memory alloy single crystal wires
journal, November 2006
- Kannarpady, Ganesh K.; Bhattacharyya, Abhijit; Pulnev, Sergei
- Journal of Alloys and Compounds, Vol. 425, Issue 1-2
Superelastic Effect in Polycrystalline Ferrous Alloys
journal, June 2011
- Omori, T.; Ando, K.; Okano, M.
- Science, Vol. 333, Issue 6038
The superelasticity of TiPdNi high temperature shape memory alloy
journal, August 2003
- Wu, Jiansheng; Tian, Qingchao
- Intermetallics, Vol. 11, Issue 8
Mechanical and Functional Behavior of High-Temperature Ni-Ti-Pt Shape Memory Alloys
journal, January 2016
- Buchheit, Thomas E.; Susan, Donald F.; Massad, Jordan E.
- Metallurgical and Materials Transactions A, Vol. 47, Issue 4
Effects of aging on the shape memory behavior of Ni-rich Ni50.3Ti29.7Hf20 single crystals
journal, April 2015
- Saghaian, S. M.; Karaca, H. E.; Tobe, H.
- Acta Materialia, Vol. 87
Stress hysteresis and temperature dependence of phase transition stress in nanostructured NiTi—Effects of grain size
journal, July 2013
- Ahadi, Aslan; Sun, Qingping
- Applied Physics Letters, Vol. 103, Issue 2
High temperature shape memory alloys
journal, September 2010
- Ma, J.; Karaman, I.; Noebe, R. D.
- International Materials Reviews, Vol. 55, Issue 5