Lithium substituted poly(amic acid) as a water-soluble anode binder for high-temperature pre-lithiation

Zhu, Tianyu; Tran, Thanh-Nhan; Fang, Chen; Liu, Dongye; Herle, Subramanya P.; Guan, Jie; Gopal, Girish; Joshi, Ajey; Cushing, James; Minor, Andrew M.; Liu, Gao

doi:10.1016/j.jpowsour.2021.230889

Title: Lithium substituted poly(amic acid) as a water-soluble anode binder for high-temperature pre-lithiation

Abstract

Multifunctional binders hold great promise in advanced electrode designs for both fundamental research and practical utilization of lithium-ion batteries (LIBs). The reactions between Si/SiO_x-dominated anodes with lithium are expected to be exothermic in principle, while the thermal tolerance along with the volume change makes high-temperature binders attractive for large scale roll-to-roll manufacturing. For instance, if a high temperature binder is also water soluble, it can be compatible with the current graphite-based anode manufacturing process. In this work, we present a water-soluble poly(amic acid)-based binder, which can withstand high temperature for industrial pre-lithiation process and effectively hold active materials together during repeated charge and discharge cycles. This lithium substituted poly(amic acid) binder (denoted as Li-Pa) can serve as a drop-in replacement for environmentally friendly electrode fabrication in large scale by providing aqueous solubility, exceptional thermal stability and mechanical flexibility.

Authors:

^[1];

^[1]; Liu, Dongye ^[2]; Herle, Subramanya P. ^[3]; Guan, Jie ^[3]; Gopal, Girish ^[3]; Joshi, Ajey ^[3]; Cushing, James ^[3]; Minor, Andrew M. ^[2];

^[1]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Applied Materials, Inc., Santa Clara, CA (United States)

Publication Date:: Tue Dec 21 00:00:00 EST 2021

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1855217

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Power Sources

Additional Journal Information:: Journal Volume: 521; Journal ID: ISSN 0378-7753

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE

Citation Formats


                    Zhu, Tianyu, Tran, Thanh-Nhan, Fang, Chen, Liu, Dongye, Herle, Subramanya P., Guan, Jie, Gopal, Girish, Joshi, Ajey, Cushing, James, Minor, Andrew M., and Liu, Gao. Lithium substituted poly(amic acid) as a water-soluble anode binder for high-temperature pre-lithiation.  United States: N. p., 2021. 
Web.  doi:10.1016/j.jpowsour.2021.230889.

Copy to clipboard


                    Zhu, Tianyu, Tran, Thanh-Nhan, Fang, Chen, Liu, Dongye, Herle, Subramanya P., Guan, Jie, Gopal, Girish, Joshi, Ajey, Cushing, James, Minor, Andrew M., & Liu, Gao. Lithium substituted poly(amic acid) as a water-soluble anode binder for high-temperature pre-lithiation.  United States.  https://doi.org/10.1016/j.jpowsour.2021.230889

Copy to clipboard


                    Zhu, Tianyu, Tran, Thanh-Nhan, Fang, Chen, Liu, Dongye, Herle, Subramanya P., Guan, Jie, Gopal, Girish, Joshi, Ajey, Cushing, James, Minor, Andrew M., and Liu, Gao. Tue .  
"Lithium substituted poly(amic acid) as a water-soluble anode binder for high-temperature pre-lithiation".  United States.  https://doi.org/10.1016/j.jpowsour.2021.230889.  https://www.osti.gov/servlets/purl/1855217.

Copy to clipboard


                    
@article{osti_1855217,

  title        = {Lithium substituted poly(amic acid) as a water-soluble anode binder for high-temperature pre-lithiation},

  author       = {Zhu, Tianyu and Tran, Thanh-Nhan and Fang, Chen and Liu, Dongye and Herle, Subramanya P. and Guan, Jie and Gopal, Girish and Joshi, Ajey and Cushing, James and Minor, Andrew M. and Liu, Gao},

  abstractNote = {Multifunctional binders hold great promise in advanced electrode designs for both fundamental research and practical utilization of lithium-ion batteries (LIBs). The reactions between Si/SiOx-dominated anodes with lithium are expected to be exothermic in principle, while the thermal tolerance along with the volume change makes high-temperature binders attractive for large scale roll-to-roll manufacturing. For instance, if a high temperature binder is also water soluble, it can be compatible with the current graphite-based anode manufacturing process. In this work, we present a water-soluble poly(amic acid)-based binder, which can withstand high temperature for industrial pre-lithiation process and effectively hold active materials together during repeated charge and discharge cycles. This lithium substituted poly(amic acid) binder (denoted as Li-Pa) can serve as a drop-in replacement for environmentally friendly electrode fabrication in large scale by providing aqueous solubility, exceptional thermal stability and mechanical flexibility.},

  doi          = {10.1016/j.jpowsour.2021.230889},

  journal      = {Journal of Power Sources},

  number       = ,

  volume       = 521,

  place        = {United States},

  year         = {Tue Dec 21 00:00:00 EST 2021},

  month        = {Tue Dec 21 00:00:00 EST 2021}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1016/j.jpowsour.2021.230889

Other availability

Search WorldCat to find libraries that may hold this journal

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

The success story of graphite as a lithium-ion anode material – fundamentals, remaining challenges, and recent developments including silicon (oxide) composites
journal, January 2020

Asenbauer, Jakob; Eisenmann, Tobias; Kuenzel, Matthias
Sustainable Energy & Fuels, Vol. 4, Issue 11
DOI: 10.1039/D0SE00175A

Silicon-based anodes for lithium-ion batteries: Effectiveness of materials synthesis and electrode preparation
journal, September 2016

Casimir, Anix; Zhang, Hanguang; Ogoke, Ogechi
Nano Energy, Vol. 27
DOI: 10.1016/j.nanoen.2016.07.023

A Review of the Design of Advanced Binders for High‐Performance Batteries
journal, October 2020

Zou, Feng; Manthiram, Arumugam
Advanced Energy Materials, Vol. 10, Issue 45
DOI: 10.1002/aenm.202002508

Solubility improvements in aromatic polyimides by macromolecular engineering
journal, January 2012

Ghosh, Anindita; Sen, Suman Kumar; Banerjee, Susanta
RSC Advances, Vol. 2, Issue 14
DOI: 10.1039/c2ra20175e

Toward Practical Application of Functional Conductive Polymer Binder for a High-Energy Lithium-Ion Battery Design
journal, October 2014

Zhao, Hui; Wang, Zhihui; Lu, Peng
Nano Letters, Vol. 14, Issue 11
DOI: 10.1021/nl503490h

Production of high-energy Li-ion batteries comprising silicon-containing anodes and insertion-type cathodes
journal, September 2021

Eshetu, Gebrekidan Gebresilassie; Zhang, Heng; Judez, Xabier
Nature Communications, Vol. 12, Issue 1
DOI: 10.1038/s41467-021-25334-8

Stable Li-ion battery anodes by in-situ polymerization of conducting hydrogel to conformally coat silicon nanoparticles
journal, June 2013

Wu, Hui; Yu, Guihua; Pan, Lijia
Nature Communications, Vol. 4, Issue 1
DOI: 10.1038/ncomms2941

A review of the electrochemical performance of alloy anodes for lithium-ion batteries
journal, January 2011

Zhang, Wei-Jun
Journal of Power Sources, Vol. 196, Issue 1
DOI: 10.1016/j.jpowsour.2010.07.020

High-performance lithium battery anodes using silicon nanowires
journal, December 2007

Chan, Candace K.; Peng, Hailin; Liu, Gao
Nature Nanotechnology, Vol. 3, Issue 1, p. 31-35
DOI: 10.1038/nnano.2007.411

Communication—Functional Conductive Polymer Binder for Practical Si-Based Electrodes
journal, May 2021

Zhu, Tianyu; Liu, Gao
Journal of The Electrochemical Society, Vol. 168, Issue 5
DOI: 10.1149/1945-7111/abff01

Advanced polyimide materials: Syntheses, physical properties and applications
journal, July 2012

Liaw, Der-Jang; Wang, Kung-Li; Huang, Ying-Chi
Progress in Polymer Science, Vol. 37, Issue 7
DOI: 10.1016/j.progpolymsci.2012.02.005

Effect of polyimide binder on electrochemical characteristics of surface-modified silicon anode for lithium ion batteries
journal, December 2013

Kim, Jung Sub; Choi, Wonchang; Cho, Kyu Young
Journal of Power Sources, Vol. 244
DOI: 10.1016/j.jpowsour.2013.02.049

Electrochemical properties of non-nano-silicon negative electrodes prepared with a polyimide binder
journal, January 2015

Uchida, Satoshi; Mihashi, Megumi; Yamagata, Masaki
Journal of Power Sources, Vol. 273
DOI: 10.1016/j.jpowsour.2014.09.096

Prospect for Supramolecular Chemistry in High-Energy-Density Rechargeable Batteries
journal, March 2019

Kwon, Tae-woo; Choi, Jang Wook; Coskun, Ali
Joule, Vol. 3, Issue 3
DOI: 10.1016/j.joule.2019.01.006

Metallurgically lithiated SiO _x anode with high capacity and ambient air compatibility
journal, June 2016

Zhao, Jie; Lee, Hyun-Wook; Sun, Jie
Proceedings of the National Academy of Sciences, Vol. 113, Issue 27
DOI: 10.1073/pnas.1603810113

The emerging era of supramolecular polymeric binders in silicon anodes
journal, January 2018

Kwon, Tae-woo; Choi, Jang Wook; Coskun, Ali
Chemical Society Reviews, Vol. 47, Issue 6
DOI: 10.1039/C7CS00858A

High-Performance Lithiated SiO _x Anode Obtained by a Controllable and Efficient Prelithiation Strategy
journal, August 2019

Meng, Qinghai; Li, Ge; Yue, Junpei
ACS Applied Materials & Interfaces, Vol. 11, Issue 35
DOI: 10.1021/acsami.9b12086

Prelithiated Silicon Nanowires as an Anode for Lithium Ion Batteries
journal, July 2011

Liu, Nian; Hu, Liangbing; McDowell, Matthew T.
ACS Nano, Vol. 5, Issue 8
DOI: 10.1021/nn2017167

Li-ion battery materials: present and future
journal, June 2015

Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae
Materials Today, Vol. 18, Issue 5
DOI: 10.1016/j.mattod.2014.10.040

Porous Polyimide Membranes Prepared by Wet Phase Inversion for Use in Low Dielectric Applications
journal, April 2013

Kim, Soohyun; Jang, Keon-Soo; Choi, Hee-Dok
International Journal of Molecular Sciences, Vol. 14, Issue 5
DOI: 10.3390/ijms14058698

Polyimide Binder: A Facile Way to Improve Safety of Lithium Ion Batteries
journal, January 2016

Qian, Guannan; Wang, Li; Shang, Yuming
Electrochimica Acta, Vol. 187
DOI: 10.1016/j.electacta.2015.11.019

Challenges and Recent Progress in the Development of Si Anodes for Lithium-Ion Battery
journal, September 2017

Jin, Yan; Zhu, Bin; Lu, Zhenda
Advanced Energy Materials, Vol. 7, Issue 23
DOI: 10.1002/aenm.201700715

Conductive Rigid Skeleton Supported Silicon as High-Performance Li-Ion Battery Anodes
journal, July 2012

Chen, Xilin; Li, Xiaolin; Ding, Fei
Nano Letters, Vol. 12, Issue 8
DOI: 10.1021/nl301657y

Exploring Chemical, Mechanical, and Electrical Functionalities of Binders for Advanced Energy-Storage Devices
journal, August 2018

Chen, Hao; Ling, Min; Hencz, Luke
Chemical Reviews, Vol. 118, Issue 18
DOI: 10.1021/acs.chemrev.8b00241

Improving the Cycling Performance of Lithium-Ion Battery Si/Graphite Anodes Using a Soluble Polyimide Binder
journal, November 2017

Oh, Jeonghun; Jin, Dahee; Kim, Kyuman
ACS Omega, Vol. 2, Issue 11
DOI: 10.1021/acsomega.7b01365

A review of rational design and investigation of binders applied in silicon-based anodes for lithium-ion batteries
journal, February 2021

Li, Shi; Liu, Yu-Mei; Zhang, Yu-Chao
Journal of Power Sources, Vol. 485
DOI: 10.1016/j.jpowsour.2020.229331

Improving the cyclability of silicon anodes for lithium-ion batteries using a simple pre-lithiation method
journal, May 2020

Kim, K. H.; Shon, J.; Jeong, H.
Journal of Power Sources, Vol. 459
DOI: 10.1016/j.jpowsour.2020.228066

Fluorinated Polyimide as a Novel High-Voltage Binder for High-Capacity Cathode of Lithium-Ion Batteries
journal, November 2017

Pham, Hieu Quang; Kim, Gwansu; Jung, Hyun Min
Advanced Functional Materials, Vol. 28, Issue 2
DOI: 10.1002/adfm.201704690

Recent advancement of SiOx based anodes for lithium-ion batteries
journal, September 2017

Chen, Tao; Wu, Ji; Zhang, Qinglin
Journal of Power Sources, Vol. 363
DOI: 10.1016/j.jpowsour.2017.07.073

Novel conductive binder for high-performance silicon anodes in lithium ion batteries
journal, June 2017

Liu, Dong; Zhao, Yan; Tan, Rui
Nano Energy, Vol. 36
DOI: 10.1016/j.nanoen.2017.04.043

Inorganic Gel-Derived Metallic Frameworks Enabling High-Performance Silicon Anodes
journal, August 2019

Zhang, Anping; Fang, Zhiwei; Tang, Yawen
Nano Letters, Vol. 19, Issue 9
DOI: 10.1021/acs.nanolett.9b02429

Similar Records in DOE PAGES and OSTI.GOV collections:

Understanding of pre-lithiation of poly(acrylic acid) binder: Striking the balances between the cycling performance and slurry stability for silicon-graphite composite electrodes in Li-ion batteries

Journal Article Hu, Bin ; Jiang, Sisi ; Shkrob, Ilya A. ; ... - Journal of Power Sources

Poly(acrylic acid) (PAA) is widely used as a polymer binder for high capacity silicon (Si) anodes in Li-ion batteries. When used, the carboxyl (-CO2H) groups of PAA can be partially lithiated (known as pre-lithiation treatment), which is believed to facilitates lamination process, especially for production on a large scale. However, such treatment impacts numerous physico-chemical properties of the PAA binder that affect the cycling performance of the electrode. Here we seek to quantify the pre-lithiation treatment effect on Li-ion cells containing Si-graphite composite electrodes. The electrochemical cycling results indicated that such pre-lithiation treatment of PAA can undermine the cycling performance,more »« less
Cited by 36
https://doi.org/10.1016/j.jpowsour.2019.01.068

Full Text Available
Re-Engineering Poly(Acrylic Acid) Binder toward Optimized Electrochemical Performance for Silicon Lithium-Ion Batteries: Branching Architecture Leads to Balanced Properties of Polymeric Binders

Journal Article Jiang, Sisi ; Hu, Bin ; Shi, Zhangxing ; ... - Advanced Functional Materials

Silicon is a promising anode material for lithium-ion batteries with its superior capacity. However, the drastic volume changes during lithiation/delithiation cycles hinder the cycling performance, resulting in particle pulverization, conductivity loss, and an unstable electrode-electrolyte interface. In this work, a series of synthetic polymeric binders, poly(acrylic acid-co-tetra(ethylene glycol) diacrylate)-featuring a poly(acrylic acid) (PAA) backbone branched via tetra(ethylene glycol) diacrylate (TEGDA)-are developed that edge toward evidencing well-balanced properties to confront capacity fading in Si-based electrodes. The incorporation of ether chain not only leads to the branching architecture of the PAA backbone, thus affecting its mechanical properties, but also promotes the conductivitymore »« less
Cited by 70
https://doi.org/10.1002/adfm.201908558

Full Text Available
A chemical switch enabled autonomous two-stage crosslinking polymeric binder for high performance silicon anodes

Journal Article Shi, Zhangxing ; Liu, Qian ; Yang, Zhenzhen ; ... - Journal of Materials Chemistry. A

Silicon (Si) is a promising high-capacity anode material for high-energy-density lithium-ion batteries. However, the drastic volumetric changes of Si upon lithiation/delithiation hinder the practical use of Si anodes. Although adhesive polymeric binders, such as poly(acrylic acid) (PAA), mitigate this issue, the cycling performance of the fabricated Si anodes is still far from meeting the criteria of practical applications. In this study, we present a novel polymeric binder system for Si anodes consisting of PAA, a chemical switch (ammonia, NH₃), and a crosslinker (branched polyethylenimine, PEI). The crosslinking between PAA and PEI is switched off in the slurry, which can thenmore »« less
https://doi.org/10.1039/d1ta07112b

Full Text Available
An Investigation of Solid-State Amidization and Imidization Reactions in Vapor Deposited Poly (amic acid)

Journal Article Anthamatten, M ; Letts, S A ; Day, K ; ... - Journal of Polymer Science. Part A, Polymer Chemistry

The condensation polymerization reaction of 4,4'-oxydianiline (ODA) with pyromellitic dianhydride (PMDA) to form poly(amic acid) and the subsequent imidization reaction to form polyimide were investigated for films prepared using vapor deposition polymerization techniques. Fourier-transform infrared spectroscopy (FT-IR), thermal analysis, and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) of films at different temperatures indicate that additional solid-state polymerization occurs prior to imidization reactions. Experiments reveal that, upon vapor deposition, poly(amic acid) oligomers form that have a number-average molecular weight of about 1500 Daltons. Between 100 - 130 C these chains undergo additional condensation reaction to form slightly higher molecular weightmore »« less
Full Text Available
Solvents and slurries comprising a poly(carboxylic acid) binder for silicon electrode manufacture

Patent Zhang, Lu ; Shi, Zhangxing ; Jansen, Andrew ; ...

A binder solution for manufacturing silicon-based anodes useful for lithium-ion electrochemical cells is described herein. The binder solution comprises a poly(carboxylic acid) binder dissolved in a mixed solvent system comprising an amide solvent of Formula I, as described herein, and a second solvent which can be water and/or an organic solvent. The binder preferably comprises poly(acrylic acid). The mixed solvent system comprises about 10 to about 99 vol % of the amide solvent of Formula I. The binder solution is utilized as a solvent for a slurry of silicon-containing particles for preparing a silicon-containing electrode. The slurries made with themore »« less
Full Text Available

Similar Records

Title: Lithium substituted poly(amic acid) as a water-soluble anode binder for high-temperature pre-lithiation

Abstract

Citation Formats

The success story of graphite as a lithium-ion anode material – fundamentals, remaining challenges, and recent developments including silicon (oxide) composites journal, January 2020

Silicon-based anodes for lithium-ion batteries: Effectiveness of materials synthesis and electrode preparation journal, September 2016

A Review of the Design of Advanced Binders for High‐Performance Batteries journal, October 2020

Solubility improvements in aromatic polyimides by macromolecular engineering journal, January 2012

Toward Practical Application of Functional Conductive Polymer Binder for a High-Energy Lithium-Ion Battery Design journal, October 2014

Production of high-energy Li-ion batteries comprising silicon-containing anodes and insertion-type cathodes journal, September 2021

Stable Li-ion battery anodes by in-situ polymerization of conducting hydrogel to conformally coat silicon nanoparticles journal, June 2013

A review of the electrochemical performance of alloy anodes for lithium-ion batteries journal, January 2011

High-performance lithium battery anodes using silicon nanowires journal, December 2007

Communication—Functional Conductive Polymer Binder for Practical Si-Based Electrodes journal, May 2021

Advanced polyimide materials: Syntheses, physical properties and applications journal, July 2012

Effect of polyimide binder on electrochemical characteristics of surface-modified silicon anode for lithium ion batteries journal, December 2013

Electrochemical properties of non-nano-silicon negative electrodes prepared with a polyimide binder journal, January 2015

Prospect for Supramolecular Chemistry in High-Energy-Density Rechargeable Batteries journal, March 2019

Metallurgically lithiated SiO x anode with high capacity and ambient air compatibility journal, June 2016

The emerging era of supramolecular polymeric binders in silicon anodes journal, January 2018

High-Performance Lithiated SiO x Anode Obtained by a Controllable and Efficient Prelithiation Strategy journal, August 2019

Prelithiated Silicon Nanowires as an Anode for Lithium Ion Batteries journal, July 2011

Li-ion battery materials: present and future journal, June 2015

Porous Polyimide Membranes Prepared by Wet Phase Inversion for Use in Low Dielectric Applications journal, April 2013

Polyimide Binder: A Facile Way to Improve Safety of Lithium Ion Batteries journal, January 2016

Challenges and Recent Progress in the Development of Si Anodes for Lithium-Ion Battery journal, September 2017

Conductive Rigid Skeleton Supported Silicon as High-Performance Li-Ion Battery Anodes journal, July 2012

Exploring Chemical, Mechanical, and Electrical Functionalities of Binders for Advanced Energy-Storage Devices journal, August 2018

Improving the Cycling Performance of Lithium-Ion Battery Si/Graphite Anodes Using a Soluble Polyimide Binder journal, November 2017

A review of rational design and investigation of binders applied in silicon-based anodes for lithium-ion batteries journal, February 2021

Improving the cyclability of silicon anodes for lithium-ion batteries using a simple pre-lithiation method journal, May 2020

Fluorinated Polyimide as a Novel High-Voltage Binder for High-Capacity Cathode of Lithium-Ion Batteries journal, November 2017

Recent advancement of SiOx based anodes for lithium-ion batteries journal, September 2017

Novel conductive binder for high-performance silicon anodes in lithium ion batteries journal, June 2017

Inorganic Gel-Derived Metallic Frameworks Enabling High-Performance Silicon Anodes journal, August 2019

The success story of graphite as a lithium-ion anode material – fundamentals, remaining challenges, and recent developments including silicon (oxide) composites
journal, January 2020

Silicon-based anodes for lithium-ion batteries: Effectiveness of materials synthesis and electrode preparation
journal, September 2016

A Review of the Design of Advanced Binders for High‐Performance Batteries
journal, October 2020

Solubility improvements in aromatic polyimides by macromolecular engineering
journal, January 2012

Toward Practical Application of Functional Conductive Polymer Binder for a High-Energy Lithium-Ion Battery Design
journal, October 2014

Production of high-energy Li-ion batteries comprising silicon-containing anodes and insertion-type cathodes
journal, September 2021

Stable Li-ion battery anodes by in-situ polymerization of conducting hydrogel to conformally coat silicon nanoparticles
journal, June 2013

A review of the electrochemical performance of alloy anodes for lithium-ion batteries
journal, January 2011

High-performance lithium battery anodes using silicon nanowires
journal, December 2007

Communication—Functional Conductive Polymer Binder for Practical Si-Based Electrodes
journal, May 2021

Advanced polyimide materials: Syntheses, physical properties and applications
journal, July 2012

Effect of polyimide binder on electrochemical characteristics of surface-modified silicon anode for lithium ion batteries
journal, December 2013

Electrochemical properties of non-nano-silicon negative electrodes prepared with a polyimide binder
journal, January 2015

Prospect for Supramolecular Chemistry in High-Energy-Density Rechargeable Batteries
journal, March 2019

Metallurgically lithiated SiO _x anode with high capacity and ambient air compatibility
journal, June 2016

The emerging era of supramolecular polymeric binders in silicon anodes
journal, January 2018

High-Performance Lithiated SiO _x Anode Obtained by a Controllable and Efficient Prelithiation Strategy
journal, August 2019

Prelithiated Silicon Nanowires as an Anode for Lithium Ion Batteries
journal, July 2011

Li-ion battery materials: present and future
journal, June 2015

Porous Polyimide Membranes Prepared by Wet Phase Inversion for Use in Low Dielectric Applications
journal, April 2013

Polyimide Binder: A Facile Way to Improve Safety of Lithium Ion Batteries
journal, January 2016

Challenges and Recent Progress in the Development of Si Anodes for Lithium-Ion Battery
journal, September 2017

Conductive Rigid Skeleton Supported Silicon as High-Performance Li-Ion Battery Anodes
journal, July 2012

Exploring Chemical, Mechanical, and Electrical Functionalities of Binders for Advanced Energy-Storage Devices
journal, August 2018

Improving the Cycling Performance of Lithium-Ion Battery Si/Graphite Anodes Using a Soluble Polyimide Binder
journal, November 2017

A review of rational design and investigation of binders applied in silicon-based anodes for lithium-ion batteries
journal, February 2021

Improving the cyclability of silicon anodes for lithium-ion batteries using a simple pre-lithiation method
journal, May 2020

Fluorinated Polyimide as a Novel High-Voltage Binder for High-Capacity Cathode of Lithium-Ion Batteries
journal, November 2017

Recent advancement of SiOx based anodes for lithium-ion batteries
journal, September 2017

Novel conductive binder for high-performance silicon anodes in lithium ion batteries
journal, June 2017

Inorganic Gel-Derived Metallic Frameworks Enabling High-Performance Silicon Anodes
journal, August 2019