Re-Engineering Poly(Acrylic Acid) Binder toward Optimized Electrochemical Performance for Silicon Lithium-Ion Batteries: Branching Architecture Leads to Balanced Properties of Polymeric Binders
Abstract
Silicon is a promising anode material for lithium-ion batteries with its superior capacity. However, the drastic volume changes during lithiation/delithiation cycles hinder the cycling performance, resulting in particle pulverization, conductivity loss, and an unstable electrode-electrolyte interface. In this work, a series of synthetic polymeric binders, poly(acrylic acid-co-tetra(ethylene glycol) diacrylate)-featuring a poly(acrylic acid) (PAA) backbone branched via tetra(ethylene glycol) diacrylate (TEGDA)-are developed that edge toward evidencing well-balanced properties to confront capacity fading in Si-based electrodes. The incorporation of ether chain not only leads to the branching architecture of the PAA backbone, thus affecting its mechanical properties, but also promotes the conductivity of Li ions. As a result, a synergistic performance improvement is observed in both half and full cells. The best-performing cell using a branched PAA binder (bPAA) with a feeding molar ratio ([TEGDA]:[acrylic acid(AA)]) of 0.2 results in a 10% increase in initial capacity and a 31% increase in capacity retention over 100 cycles compared to the linear PAA cell. The cross-sectional microscopic images of the cycled electrodes reveal that bPAA binders can drastically reduce the electrode expansion. This improvement results from the well-balanced properties of the polymer design, which could guide further development for more advanced binder materials.
- Authors:
-
[1];
[1];
[2];
[3]
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of Chicago, IL (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States). Joint Center for Energy Storage Research (JCESR)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States). Center for Nanoscale Materials (CNM)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office
- OSTI Identifier:
- 1632851
- Alternate Identifier(s):
- OSTI ID: 1580540; OSTI ID: 1756183
- Grant/Contract Number:
- AC02-06CH11357; AC02‐06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Functional Materials
- Additional Journal Information:
- Journal Volume: 30; Journal Issue: 10; Journal ID: ISSN 1616-301X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; branched PAA; lithium-ion batteries; polymer binder; silicon anode
Citation Formats
Jiang, Sisi, Hu, Bin, Shi, Zhangxing, Chen, Wei, Zhang, Zhengcheng, and Zhang, Lu. Re-Engineering Poly(Acrylic Acid) Binder toward Optimized Electrochemical Performance for Silicon Lithium-Ion Batteries: Branching Architecture Leads to Balanced Properties of Polymeric Binders. United States: N. p., 2019.
Web. doi:10.1002/adfm.201908558.
Jiang, Sisi, Hu, Bin, Shi, Zhangxing, Chen, Wei, Zhang, Zhengcheng, & Zhang, Lu. Re-Engineering Poly(Acrylic Acid) Binder toward Optimized Electrochemical Performance for Silicon Lithium-Ion Batteries: Branching Architecture Leads to Balanced Properties of Polymeric Binders. United States. https://doi.org/10.1002/adfm.201908558
Jiang, Sisi, Hu, Bin, Shi, Zhangxing, Chen, Wei, Zhang, Zhengcheng, and Zhang, Lu. Fri .
"Re-Engineering Poly(Acrylic Acid) Binder toward Optimized Electrochemical Performance for Silicon Lithium-Ion Batteries: Branching Architecture Leads to Balanced Properties of Polymeric Binders". United States. https://doi.org/10.1002/adfm.201908558. https://www.osti.gov/servlets/purl/1632851.
@article{osti_1632851,
title = {Re-Engineering Poly(Acrylic Acid) Binder toward Optimized Electrochemical Performance for Silicon Lithium-Ion Batteries: Branching Architecture Leads to Balanced Properties of Polymeric Binders},
author = {Jiang, Sisi and Hu, Bin and Shi, Zhangxing and Chen, Wei and Zhang, Zhengcheng and Zhang, Lu},
abstractNote = {Silicon is a promising anode material for lithium-ion batteries with its superior capacity. However, the drastic volume changes during lithiation/delithiation cycles hinder the cycling performance, resulting in particle pulverization, conductivity loss, and an unstable electrode-electrolyte interface. In this work, a series of synthetic polymeric binders, poly(acrylic acid-co-tetra(ethylene glycol) diacrylate)-featuring a poly(acrylic acid) (PAA) backbone branched via tetra(ethylene glycol) diacrylate (TEGDA)-are developed that edge toward evidencing well-balanced properties to confront capacity fading in Si-based electrodes. The incorporation of ether chain not only leads to the branching architecture of the PAA backbone, thus affecting its mechanical properties, but also promotes the conductivity of Li ions. As a result, a synergistic performance improvement is observed in both half and full cells. The best-performing cell using a branched PAA binder (bPAA) with a feeding molar ratio ([TEGDA]:[acrylic acid(AA)]) of 0.2 results in a 10% increase in initial capacity and a 31% increase in capacity retention over 100 cycles compared to the linear PAA cell. The cross-sectional microscopic images of the cycled electrodes reveal that bPAA binders can drastically reduce the electrode expansion. This improvement results from the well-balanced properties of the polymer design, which could guide further development for more advanced binder materials.},
doi = {10.1002/adfm.201908558},
journal = {Advanced Functional Materials},
number = 10,
volume = 30,
place = {United States},
year = {Fri Dec 27 00:00:00 EST 2019},
month = {Fri Dec 27 00:00:00 EST 2019}
}
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Works referenced in this record:
Highly elastic binders integrating polyrotaxanes for silicon microparticle anodes in lithium ion batteries
journal, July 2017
- Choi, Sunghun; Kwon, Tae-woo; Coskun, Ali
- Science, Vol. 357, Issue 6348
A Highly Cross-Linked Polymeric Binder for High-Performance Silicon Negative Electrodes in Lithium Ion Batteries
journal, July 2012
- Koo, Bonjae; Kim, Hyunjung; Cho, Younghyun
- Angewandte Chemie International Edition, Vol. 51, Issue 35
A More Versatile Route to Block Copolymers and Other Polymers of Complex Architecture by Living Radical Polymerization: The RAFT Process
journal, March 1999
- Chong, ) Y. K.; Le, Tam P. T.; Moad, Graeme
- Macromolecules, Vol. 32, Issue 6
Using Rheological Data To Determine the Branching Level in Metallocene Polyethylenes
journal, October 2000
- Wood-Adams, Paula M.; Dealy, John M.
- Macromolecules, Vol. 33, Issue 20
Ionically Conductive Self-Healing Binder for Low Cost Si Microparticles Anodes in Li-Ion Batteries
journal, February 2018
- Munaoka, Takatoshi; Yan, Xuzhou; Lopez, Jeffrey
- Advanced Energy Materials, Vol. 8, Issue 14
Characterization of the stereochemical structure of poly(acrylic acid) by one- and two-dimensional 13C-1H nuclear magnetic resonance spectra
journal, January 1995
- Speˇvácˇek, Jirˇí; Suchopárek, Milosˇ; Al-Alawi, Saeed
- Polymer, Vol. 36, Issue 21
Reactivity ratios for acrylic acid–methyl acrylate copolymerization in 1,4-dioxane
journal, November 1976
- Eldridge, R. J.; Treloar, F. E.
- Journal of Polymer Science: Polymer Chemistry Edition, Vol. 14, Issue 11
Effect of Molecular Shape on Rheological Properties in Molecular Dynamics Simulation of Star, H, Comb, and Linear Polymer Melts
journal, July 2003
- Jabbarzadeh, A.; Atkinson, J. D.; Tanner, R. I.
- Macromolecules, Vol. 36, Issue 13
Issues and challenges facing rechargeable lithium batteries
journal, November 2001
- Tarascon, J.-M.; Armand, M.
- Nature, Vol. 414, Issue 6861, p. 359-367
Silicon-Based Anodes for Lithium-Ion Batteries: From Fundamentals to Practical Applications
journal, January 2018
- Feng, Kun; Li, Matthew; Liu, Wenwen
- Small, Vol. 14, Issue 8
Copolymerization reactivity ratios acrylic and methacrylic acids with butyl acrylate and butyl methacrylate
journal, February 1963
- Paxton, Thomas R.
- Journal of Polymer Science Part B: Polymer Letters, Vol. 1, Issue 2
Enhanced Cycling Stability of Sulfur Electrodes through Effective Binding of Pyridine-Functionalized Polymer
journal, September 2017
- Tsao, Yuchi; Chen, Zheng; Rondeau-Gagné, Simon
- ACS Energy Letters, Vol. 2, Issue 10
Sodium Carboxymethyl Cellulose
journal, January 2007
- Li, Jing; Lewis, R. B.; Dahn, J. R.
- Electrochemical and Solid-State Letters, Vol. 10, Issue 2
Surface-Functionalized Silicon Nanoparticles as Anode Material for Lithium-Ion Battery
journal, November 2018
- Jiang, Sisi; Hu, Bin; Sahore, Ritu
- ACS Applied Materials & Interfaces, Vol. 10, Issue 51
Stable Li-ion battery anodes by in-situ polymerization of conducting hydrogel to conformally coat silicon nanoparticles
journal, June 2013
- Wu, Hui; Yu, Guihua; Pan, Lijia
- Nature Communications, Vol. 4, Issue 1
Physically cross-linked polymer binder based on poly(acrylic acid) and ion-conducting poly(ethylene glycol-co-benzimidazole) for silicon anodes
journal, August 2017
- Lim, Sanghyun; Lee, Kukjoo; Shin, Inseop
- Journal of Power Sources, Vol. 360
Rheological behavior of star-shaped polymers
journal, July 1993
- Fetters, Lewis J.; Kiss, Andrea D.; Pearson, Dale S.
- Macromolecules, Vol. 26, Issue 4
Poly(ethylene oxide)-based electrolytes for lithium-ion batteries
journal, January 2015
- Xue, Zhigang; He, Dan; Xie, Xiaolin
- Journal of Materials Chemistry A, Vol. 3, Issue 38
The existence of optimal molecular weight for poly(acrylic acid) binders in silicon/graphite composite anode for lithium-ion batteries
journal, February 2018
- Hu, Bin; Shkrob, Ilya A.; Zhang, Shuo
- Journal of Power Sources, Vol. 378
Phase Behavior of Blends of Poly(ethylene glycol) and Partially Neutralized Poly(acrylic acid)
journal, April 1995
- Lu, Xinya; Weiss, R. A.
- Macromolecules, Vol. 28, Issue 9
Toward Efficient Binders for Li-Ion Battery Si-Based Anodes: Polyacrylic Acid
journal, October 2010
- Magasinski, Alexandre; Zdyrko, Bogdan; Kovalenko, Igor
- ACS Applied Materials & Interfaces, Vol. 2, Issue 11
Physically Cross-linked Polymer Binder Induced by Reversible Acid–Base Interaction for High-Performance Silicon Composite Anodes
journal, October 2015
- Lim, Sanghyun; Chu, Hodong; Lee, Kukjoo
- ACS Applied Materials & Interfaces, Vol. 7, Issue 42
The Effects of Cross-Linking in a Supramolecular Binder on Cycle Life in Silicon Microparticle Anodes
journal, January 2016
- Lopez, Jeffrey; Chen, Zheng; Wang, Chao
- ACS Applied Materials & Interfaces, Vol. 8, Issue 3
Designing nanostructured Si anodes for high energy lithium ion batteries
journal, October 2012
- Wu, Hui; Cui, Yi
- Nano Today, Vol. 7, Issue 5
Building better batteries
journal, February 2008
- Armand, M.; Tarascon, J.-M.
- Nature, Vol. 451, Issue 7179, p. 652-657
Rheological properties of linear and crosslinked polymer blends: Relation between crosslink density and enhancement of elongational viscosity
journal, January 2000
- Yamaguchi, Masayuki
- Journal of Polymer Science Part B: Polymer Physics, Vol. 39, Issue 2
Promises and challenges of nanomaterials for lithium-based rechargeable batteries
journal, June 2016
- Sun, Yongming; Liu, Nian; Cui, Yi
- Nature Energy, Vol. 1, Issue 7
A Major Constituent of Brown Algae for Use in High-Capacity Li-Ion Batteries
journal, September 2011
- Kovalenko, I.; Zdyrko, B.; Magasinski, A.
- Science, Vol. 334, Issue 6052
Hollow Carbon Nanospheres with Superior Rate Capability for Sodium-Based Batteries
journal, May 2012
- Tang, Kun; Fu, Lijun; White, Robin J.
- Advanced Energy Materials, Vol. 2, Issue 7
Enhancement of the Cyclability of a Si/Graphite@Graphene composite as anode for Lithium-ion batteries
journal, January 2014
- Su, Mingru; Wang, Zhixing; Guo, Huajun
- Electrochimica Acta, Vol. 116
Small things make a big difference: binder effects on the performance of Li and Na batteries
journal, January 2014
- Chou, Shu-Lei; Pan, Yuede; Wang, Jia-Zhao
- Phys. Chem. Chem. Phys., Vol. 16, Issue 38
Living Free-Radical Polymerization by Reversible Addition−Fragmentation Chain Transfer: The RAFT Process
journal, August 1998
- Chiefari, John; Chong, Y. K. (Bill); Ercole, Frances
- Macromolecules, Vol. 31, Issue 16
Li-alloy based anode materials for Li secondary batteries
journal, January 2010
- Park, Cheol-Min; Kim, Jae-Hun; Kim, Hansu
- Chemical Society Reviews, Vol. 39, Issue 8, p. 3115-3141
Effect of Side-Chain Branching on Enhancement of Ionic Conductivity and Capacity Retention of a Solid Copolymer Electrolyte Membrane
journal, November 2017
- Fu, Guopeng; Kyu, Thein
- Langmuir, Vol. 33, Issue 49
Correlation between glass transition temperature and chain structure for randomly crosslinked high polymers
journal, September 1996
- Bicerano, Jozef; Sammler, Robert L.; Carriere, Craig J.
- Journal of Polymer Science Part B: Polymer Physics, Vol. 34, Issue 13
High performance polymer binders inspired by chemical finishing of textiles for silicon anodes in lithium ion batteries
journal, January 2017
- Wei, Liangming; Hou, Zhongyu
- J. Mater. Chem. A, Vol. 5, Issue 42
Confronting Issues of the Practical Implementation of Si Anode in High-Energy Lithium-Ion Batteries
journal, September 2017
- Chae, Sujong; Ko, Minseong; Kim, Kyungho
- Joule, Vol. 1, Issue 1
Synthesis and Characterization of Branched Polyelectrolytes. 1. Preparation of Hyperbranched Poly(acrylic acid) via Self-Condensing Atom Transfer Radical Copolymerization
journal, December 2002
- Mori, Hideharu; Seng, Delphine Chan; Lechner, Hans
- Macromolecules, Vol. 35, Issue 25
Size-exclusion chromatography (SEC) of branched polymers and polysaccharides
journal, October 2010
- Gaborieau, Marianne; Castignolles, Patrice
- Analytical and Bioanalytical Chemistry, Vol. 399, Issue 4
Understanding of pre-lithiation of poly(acrylic acid) binder: Striking the balances between the cycling performance and slurry stability for silicon-graphite composite electrodes in Li-ion batteries
journal, March 2019
- Hu, Bin; Jiang, Sisi; Shkrob, Ilya A.
- Journal of Power Sources, Vol. 416
Systematic Investigation of Binders for Silicon Anodes: Interactions of Binder with Silicon Particles and Electrolytes and Effects of Binders on Solid Electrolyte Interphase Formation
journal, May 2016
- Nguyen, Cao Cuong; Yoon, Taeho; Seo, Daniel M.
- ACS Applied Materials & Interfaces, Vol. 8, Issue 19
Influence of cross-link density on rheological properties of temperature-sensitive microgel suspensions
journal, September 2000
- Senff, H.; Richtering, W.
- Colloid & Polymer Science, Vol. 278, Issue 9
Living Radical Polymerization by the RAFT Process
journal, January 2005
- Moad, Graeme; Rizzardo, Ezio; Thang, San H.
- Australian Journal of Chemistry, Vol. 58, Issue 6
Electrochemical performance and interfacial investigation on Si composite anode for lithium ion batteries in full cell
journal, August 2017
- Shobukawa, Hitoshi; Alvarado, Judith; Yang, Yangyuchen
- Journal of Power Sources, Vol. 359
Water Soluble Binder, an Electrochemical Performance Booster for Electrode Materials with High Energy Density
journal, July 2017
- Li, Jun-Tao; Wu, Zhan-Yu; Lu, Yan-Qiu
- Advanced Energy Materials, Vol. 7, Issue 24
Electron/Ion Transport Enhancer in High Capacity Li-Ion Battery Anodes
journal, September 2016
- Kwon, Yo Han; Minnici, Krysten; Huie, Matthew M.
- Chemistry of Materials, Vol. 28, Issue 18
A Highly Cross-Linked Polymeric Binder for High-Performance Silicon Negative Electrodes in Lithium Ion Batteries
journal, July 2012
- Koo, Bonjae; Kim, Hyunjung; Cho, Younghyun
- Angewandte Chemie, Vol. 124, Issue 35
Living Radical Polymerization by the RAFT Process
journal, October 2005
- Moad, Graeme; Rizzardo, Ezio; Thang, San H.
- ChemInform, Vol. 36, Issue 40
Sodium Carboxymethyl Cellulose
journal, January 1985
- Senda, Hisakazu
- Journal of Synthetic Organic Chemistry, Japan, Vol. 43, Issue 4