Nickel(ii) complexes based on dithiolate–polyamine binary ligand systems: crystal structures, hirshfeld surface analysis, theoretical study, and catalytic activity study on photocatalytic hydrogen generation
Abstract
To ascertain the influence of binary ligand systems [1,1-dicyanoethylene-2,2-dithiolate (i-mnt-2) and polyamine {tetraen = tris(2-aminoethyl)amine, tren = diethylene triamine and opda = o-phenylenediamine}] on the coordination modes of the Ni(II) metal center and resulting supramolecular architectures, a series of nickel(II) thiolate complexes [Ni(tetraen)(i-mnt)](DMSO) (1), [Ni2(tren)2(i-mnt)2] (2), and [Ni2(i-mnt)2(opda)2]n (3) have been synthesized in high yield in one step in water and structurally characterized by single crystal X-ray crystallography and spectroscopic techniques. X-ray diffraction studies disclose the diverse i-mnt-2 coordination to the Ni+2 center in the presence of active polyamine ligands, forming a slightly distorted octahedral geometry (NiN4S2) in 1, square planar (NiS4) and distorted octahedral geometries (NiN6) in the bimetallic co-crystallized aggregate of cationic [Ni(tren)2]+2 and anionic [Ni(i-mnt)2]-2 in 2, and a one dimensional (1D) polymeric chain along the [100] axis in 3, having consecutive square planar (NiS4) and octahedral (NiN6) coordination kernels. The N–H···O, N–H···S, N–H···N, N–H···S, N–H···N, and N–H···O type hydrogen bonds stabilize the supramolecular assemblies in 1, 2, and 3 respectively imparting interesting graph-set-motifs. The molecular Hirshfeld surface analyses (HS) and 2D fingerprint plots were utilized for decoding all types of non-covalent contacts in the crystal networks. Atomic HS analysis of the Ni+2 centers reveals significant Ni–Nmore »
- Authors:
-
- Govt. Degree College, Dharmanagar (India)
- Bineswar Brahma Engineering College, Kokrajhar (India)
- Westfälische Wilhelms-Univ. Münster (Germany)
- Univ. de les Illes Balears, Palma de Mallorca (Spain)
- Carnegie Mellon Univ., Pittsburgh, PA (United States)
- Publication Date:
- Research Org.:
- Carnegie Mellon Univ., Pittsburgh, PA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1853622
- Alternate Identifier(s):
- OSTI ID: 1776377
- Grant/Contract Number:
- SC0020392
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Dalton Transactions
- Additional Journal Information:
- Journal Volume: 50; Journal Issue: 16; Journal ID: ISSN 1477-9226
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Adhikari, Suman, Bhattacharjee, Tirtha, Bhattacharjee, Sharmila, Daniliuc, Constantin Gabriel, Frontera, Antonio, Lopato, Eric M., and Bernhard, Stefan. Nickel(ii) complexes based on dithiolate–polyamine binary ligand systems: crystal structures, hirshfeld surface analysis, theoretical study, and catalytic activity study on photocatalytic hydrogen generation. United States: N. p., 2021.
Web. doi:10.1039/d1dt00352f.
Adhikari, Suman, Bhattacharjee, Tirtha, Bhattacharjee, Sharmila, Daniliuc, Constantin Gabriel, Frontera, Antonio, Lopato, Eric M., & Bernhard, Stefan. Nickel(ii) complexes based on dithiolate–polyamine binary ligand systems: crystal structures, hirshfeld surface analysis, theoretical study, and catalytic activity study on photocatalytic hydrogen generation. United States. https://doi.org/10.1039/d1dt00352f
Adhikari, Suman, Bhattacharjee, Tirtha, Bhattacharjee, Sharmila, Daniliuc, Constantin Gabriel, Frontera, Antonio, Lopato, Eric M., and Bernhard, Stefan. Tue .
"Nickel(ii) complexes based on dithiolate–polyamine binary ligand systems: crystal structures, hirshfeld surface analysis, theoretical study, and catalytic activity study on photocatalytic hydrogen generation". United States. https://doi.org/10.1039/d1dt00352f. https://www.osti.gov/servlets/purl/1853622.
@article{osti_1853622,
title = {Nickel(ii) complexes based on dithiolate–polyamine binary ligand systems: crystal structures, hirshfeld surface analysis, theoretical study, and catalytic activity study on photocatalytic hydrogen generation},
author = {Adhikari, Suman and Bhattacharjee, Tirtha and Bhattacharjee, Sharmila and Daniliuc, Constantin Gabriel and Frontera, Antonio and Lopato, Eric M. and Bernhard, Stefan},
abstractNote = {To ascertain the influence of binary ligand systems [1,1-dicyanoethylene-2,2-dithiolate (i-mnt-2) and polyamine {tetraen = tris(2-aminoethyl)amine, tren = diethylene triamine and opda = o-phenylenediamine}] on the coordination modes of the Ni(II) metal center and resulting supramolecular architectures, a series of nickel(II) thiolate complexes [Ni(tetraen)(i-mnt)](DMSO) (1), [Ni2(tren)2(i-mnt)2] (2), and [Ni2(i-mnt)2(opda)2]n (3) have been synthesized in high yield in one step in water and structurally characterized by single crystal X-ray crystallography and spectroscopic techniques. X-ray diffraction studies disclose the diverse i-mnt-2 coordination to the Ni+2 center in the presence of active polyamine ligands, forming a slightly distorted octahedral geometry (NiN4S2) in 1, square planar (NiS4) and distorted octahedral geometries (NiN6) in the bimetallic co-crystallized aggregate of cationic [Ni(tren)2]+2 and anionic [Ni(i-mnt)2]-2 in 2, and a one dimensional (1D) polymeric chain along the [100] axis in 3, having consecutive square planar (NiS4) and octahedral (NiN6) coordination kernels. The N–H···O, N–H···S, N–H···N, N–H···S, N–H···N, and N–H···O type hydrogen bonds stabilize the supramolecular assemblies in 1, 2, and 3 respectively imparting interesting graph-set-motifs. The molecular Hirshfeld surface analyses (HS) and 2D fingerprint plots were utilized for decoding all types of non-covalent contacts in the crystal networks. Atomic HS analysis of the Ni+2 centers reveals significant Ni–N metal–ligand interactions compared to Ni–S interactions. We have also studied the unorthodox interactions observed in the solid state structures of 1–3 by QTAIM and NBO analyses. Moreover, all the complexes proved to be highly active water reduction co-catalysts (WRC) in a photo-catalytic hydrogen evolution process involving iridium photosensitizers, wherein 2 and 3 having a square planar arrangement around the nickel center(s) – were found to be the most active ones, achieving 1000 and 1119 turnover numbers (TON), respectively.},
doi = {10.1039/d1dt00352f},
journal = {Dalton Transactions},
number = 16,
volume = 50,
place = {United States},
year = {Tue Mar 16 00:00:00 EDT 2021},
month = {Tue Mar 16 00:00:00 EDT 2021}
}
Works referenced in this record:
Robust photocatalytic water reduction with cyclometalated Ir(iii) 4-vinyl-2,2′-bipyridine complexes
journal, January 2010
- Metz, Stefan; Bernhard, Stefan
- Chemical Communications, Vol. 46, Issue 40
Cationic Cyclometalated Iridium Luminophores: Photophysical, Redox, and Structural Characterization
journal, November 2004
- Neve, Francesco; La Deda, Massimo; Crispini, Alessandra
- Organometallics, Vol. 23, Issue 24
Nickel(ii) macrocycles: highly efficient electrocatalysts for the selective reduction of CO2 to CO
journal, January 2012
- Schneider, Jacob; Jia, Hongfei; Kobiro, Kazuya
- Energy & Environmental Science, Vol. 5, Issue 11
Snap Frozen! Capturing Two Metastable Polymorphs in a Tetramorphic One-Dimensional Coordination Polymer Constructed from Cadmium, Dithiophosphate, and 4-Pyridinealdazine
journal, March 2020
- Tan, Yee Seng; Otero-de-la-Roza, Alberto; Jotani, Mukesh M.
- Crystal Growth & Design, Vol. 20, Issue 5
Influence of substituents within bidentate nitrogenous bases on the spectra of mixed-ligand (1,1-dithiolato)copper(II) and nickel(II) chelates
journal, March 1997
- Alkam, Hussein H.; Hatzidimitriou, Antonis; Hadjikostas, Christos C.
- Inorganica Chimica Acta, Vol. 256, Issue 1
Sterically Stabilized Terminal Hydride of a Diiron Dithiolate
journal, January 2018
- Carlson, Michaela R.; Gray, Danielle L.; Richers, Casseday P.
- Inorganic Chemistry, Vol. 57, Issue 4
Calix[4]pyrrole-Based Heteroditopic Ion-Pair Receptor That Displays Anion-Modulated, Cation-Binding Behavior
journal, October 2012
- Park, In-Won; Yoo, Jaeduk; Adhikari, Suman
- Chemistry - A European Journal, Vol. 18, Issue 47
High-throughput Synthesis and Screening of Iridium(III) Photocatalysts for the Fast and Chemoselective Dehalogenation of Aryl Bromides
journal, May 2020
- Mdluli, Velabo; Diluzio, Stephen; Lewis, Jacqueline
- ACS Catalysis, Vol. 10, Issue 13
Biferrocene−M(mnt) 2 Charge-Transfer Complexes (M = Ni, Co; mnt = Maleonitriledithiolate). Structure, Valence States, and Magnetic Properties
journal, November 2005
- Mochida, Tomoyuki; Takazawa, Kousuke; Matsui, Hideaki
- Inorganic Chemistry, Vol. 44, Issue 23
Quinoline based receptor in fluorometric discrimination of carboxylic acids
journal, January 2008
- Ghosh, Kumaresh; Adhikari, Suman; Chattopadhyay, Asoke P.
- Beilstein Journal of Organic Chemistry, Vol. 4
Molecular mechanics and molecular shape. III. Surface area and cross-sectional areas of organic molecules: Molecular Mechanics And Shape
journal, April 1986
- Meyer, A. Y.
- Journal of Computational Chemistry, Vol. 7, Issue 2
Coordination polymers and molecular structures among complexes of mercury(II) halides with selected 1-benzoylthioureas
journal, April 2015
- Okuniewski, Andrzej; Rosiak, Damian; Chojnacki, Jarosław
- Polyhedron, Vol. 90
Proton Inventory and Dynamics in the Ni a -S to Ni a -C Transition of a [NiFe] Hydrogenase
journal, March 2016
- Greene, Brandon L.; Wu, Chang-Hao; Vansuch, Gregory E.
- Biochemistry, Vol. 55, Issue 12
Pyridine‐Based Macrocyclic and Open Receptors for Urea
journal, November 2019
- Adhikari, Suman; Kar, Debasis; Fröhlich, Roland
- ChemistrySelect, Vol. 4, Issue 44
Phatolysis of Water Catalyzed by Transition Metal Dithiolenes
journal, August 1980
- Henning, Rainer; Schlamann, Wilhelm; Kisch, Horst
- Angewandte Chemie International Edition in English, Vol. 19, Issue 8
van der Waals Volumes and Radii
journal, March 1964
- Bondi, A.
- The Journal of Physical Chemistry, Vol. 68, Issue 3, p. 441-451
Efficient photo-driven hydrogen evolution by binuclear nickel catalysts of different coordination in noble-metal-free systems
journal, January 2013
- Cui, Hong-hua; Wang, Jin-yun; Hu, Ming-qiang
- Dalton Transactions, Vol. 42, Issue 24
Towards quantitative analysis of intermolecular interactions with Hirshfeld surfaces
journal, January 2007
- McKinnon, Joshua J.; Jayatilaka, Dylan; Spackman, Mark A.
- Chemical Communications, Issue 37
A new cadmium(II) complex with bridging dithiolate ligand: Synthesis, crystal structure and antifungal activity study
journal, July 2017
- Singh, Mahesh Kumar; Sutradhar, Sanjit; Paul, Bijaya
- Journal of Molecular Structure, Vol. 1139
Mixed-ligand complexes of zinc(II) with 1,1-dicyanoethylene-2,2-dithiolate and N-donor ligands: A combined experimental and theoretical study
journal, July 2018
- Singh, Mahesh Kumar; Sutradhar, Sanjit; Paul, Bijaya
- Journal of Molecular Structure, Vol. 1164
Nickel Complexes for Robust Light-Driven and Electrocatalytic Hydrogen Production from Water
journal, January 2015
- Das, Amit; Han, Zhiji; Brennessel, William W.
- ACS Catalysis, Vol. 5, Issue 3
High-Throughput Screening of Earth-Abundant Water Reduction Catalysts toward Photocatalytic Hydrogen Evolution
journal, January 2021
- Motz, Rachel N.; Lopato, Eric M.; Connell, Timothy U.
- Inorganic Chemistry, Vol. 60, Issue 2
Efficient H2-producing photocatalytic systems based on cyclometalated iridium- and tricarbonylrhenium-diimine photosensitizers and cobaloxime catalysts
journal, January 2008
- Fihri, Aziz; Artero, Vincent; Pereira, Alexandre
- Dalton Transactions, Issue 41
Experimental and theoretical anion binding studies on coumarin linked thiourea and urea molecules
journal, October 2011
- Ghosh, Kumaresh; Adhikari, Suman; Fröhlich, Roland
- Journal of Molecular Structure, Vol. 1004, Issue 1-3
Coordination framework of cadmium(II), harvested from dithiolate-imidazole binary ligand systems: Crystal structure, Hirshfeld surface analysis, antibacterial, and DNA cleavage potential
journal, December 2020
- Adhikari, Suman; Bhattacharjee, Tirtha; Gupta, Raj
- Polyhedron, Vol. 192
Bimetallic and trimetallic Cd(II) and Hg(II) mixed-ligand complexes with 1,1-dicyanoethylene-2,2-dithiolate and polyamines: Synthesis, crystal structure, Hirshfeld surface analysis, and antimicrobial study
journal, November 2020
- Adhikari, Suman; Bhattacharjee, Tirtha; Nath, Priyatosh
- Inorganica Chimica Acta, Vol. 512
Synthesis and Characterization of Strong Cyclometalated Iridium Photoreductants for Application in Photocatalytic Aryl Bromide Hydrodebromination
journal, August 2019
- Shon, Jong-Hwa; Sittel, Steven; Teets, Thomas S.
- ACS Catalysis, Vol. 9, Issue 9
Two mixed-ligand cadmium( ii ) compounds bearing 5-nitrosopyrimidine and N-donor aromatic blocks: self-assembly generation, structural and topological features, DFT studies, and Hirshfeld surface analysis
journal, January 2016
- Banik, Rupak; Roy, Subhadip; Kirillov, Alexander M.
- CrystEngComm, Vol. 18, Issue 30
Judicious Design of Cationic, Cyclometalated Ir(III) Complexes for Photochemical Energy Conversion and Optoelectronics
journal, January 2018
- Mills, Isaac N.; Porras, Jonathan A.; Bernhard, Stefan
- Accounts of Chemical Research, Vol. 51, Issue 2
Nickel–Thiolate Complex Catalyst Assembled in One Step in Water for Solar H 2 Production
journal, December 2011
- Zhang, Wei; Hong, Jindui; Zheng, Jianwei
- Journal of the American Chemical Society, Vol. 133, Issue 51
Photocatalytic Hydrogen Generation System Using a Nickel-Thiolate Hexameric Cluster
journal, July 2013
- Kagalwala, Husain N.; Gottlieb, Eric; Li, Gao
- Inorganic Chemistry, Vol. 52, Issue 15
The aspherity of random walks
journal, March 1986
- Rudnick, J.; Gaspari, G.
- Journal of Physics A: Mathematical and General, Vol. 19, Issue 4
High-Throughput Screening and Automated Data-Driven Analysis of the Triplet Photophysical Properties of Structurally Diverse, Heteroleptic Iridium(III) Complexes
journal, January 2021
- DiLuzio, Stephen; Mdluli, Velabo; Connell, Timothy U.
- Journal of the American Chemical Society, Vol. 143, Issue 2
A Square Pyramidal Coordination Cap: The Co(III) Complex of a Novel Tetrapodal Pentadentate Ligand with an NN 4 Donor Set
journal, January 1996
- Grohmann, Andreas; Knoch, Falk
- Inorganic Chemistry, Vol. 35, Issue 26
SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015
- Sheldrick, George M.
- Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8
Nickel(II) Thiolate Complexes with a Flexiblecyclo-{Ni10S20} Framework
journal, June 2006
- Zhang, Chi; Takada, Satoshi; Kölzer, Michael
- Angewandte Chemie International Edition, Vol. 45, Issue 23
High-throughput measurement of the influence of pH on hydrogen production from BaTiO3/TiO2 core/shell photocatalysts
journal, July 2020
- Song, Wenjia; Lopato, Eric M.; Bernhard, Stefan
- Applied Catalysis B: Environmental, Vol. 269
Benzyl Dihydrazone versus Thiosemicarbazone Schiff Base: Effects on the Supramolecular Arrangement of Cobalt Thiocyanate Complexes and the Generation of CoN 6 and CoN 4 S 2 Coordination Spheres: Benzyl Dihydrazone versus Thiosemicarbazone Schiff Base: Effects on the Supramolecular Arrangement of Cobalt Thiocyanate Complexes and the Generation
journal, October 2017
- Mahmoudi, Ghodrat; Zaręba, Jan K.; Gurbanov, Atash V.
- European Journal of Inorganic Chemistry, Vol. 2017, Issue 40
Rhodamine-Platinum Diimine Dithiolate Complex Dyads as Efficient and Robust Photosensitizers for Light-Driven Aqueous Proton Reduction to Hydrogen
journal, February 2018
- Li, Guocan; Mark, Michael F.; Lv, Hongjin
- Journal of the American Chemical Society, Vol. 140, Issue 7
Structure−Activity Correlations Among Iridium(III) Photosensitizers in a Robust Water-Reducing System
journal, July 2009
- Curtin, Peter N.; Tinker, Leonard L.; Burgess, Christine M.
- Inorganic Chemistry, Vol. 48, Issue 22
Photophysical and Electrochemical Properties of Heteroleptic Tris-Cyclometalated Iridium(III) Complexes
journal, June 2005
- Dedeian, Kenneth; Shi, Jianmin; Shepherd, Nigel
- Inorganic Chemistry, Vol. 44, Issue 13
Studies on Thioacids and Their Derivatives. XIV. Reactions of Carbon Disulfide with Active Methylene Compounds.
journal, January 1968
- Jensen, Kai Arne; Henriksen, Lars; Weeks, Owen B.
- Acta Chemica Scandinavica, Vol. 22
A Robust Visible-Light-Harvesting Cyclometalated Ir(III) Diimine Sensitizer for Homogeneous Photocatalytic Hydrogen Production
journal, January 2020
- Yang, Mo; Yarnell, James E.; El Roz, Karim
- ACS Applied Energy Materials, Vol. 3, Issue 2
Recurrent supramolecular motifs in discrete complexes and coordination polymers based on mercury halides: prevalence of chelate ring stacking and substituent effects
journal, January 2018
- Mahmoudi, Ghodrat; Zaręba, Jan K.; Bauzá, Antonio
- CrystEngComm, Vol. 20, Issue 8
A new photosensitizer—catalyst for the photochemical cleavage of water
journal, July 1985
- Hontzopoulos, E.; Vrachnou-Astra, E.; Konstantatos, J.
- Journal of Photochemistry, Vol. 30, Issue 1
On the supramolecular properties of neutral, anionic and cationic cadmium complexes harvested from dithiolate–polyamine binary ligand systems
journal, January 2020
- Adhikari, Suman; Bhattacharjee, Tirtha; Das, Arijit
- CrystEngComm, Vol. 22, Issue 46
A novel definition of a molecule in a crystal
journal, March 1997
- Spackman, Mark A.; Byrom, Patrick G.
- Chemical Physics Letters, Vol. 267, Issue 3-4
Geometrically specific multidentate ligands and their complexes. I. A nickel(II) complex of the potentially heptadentate Schiff base derived from 2,2'2''-triaminotriethylamine and 2-pyridinecarboxaldehyde
journal, October 1968
- Wilson, L. J.; Rose, Norman J.
- Journal of the American Chemical Society, Vol. 90, Issue 22
Synthesis and characterization of mixed-ligand Zn(II) and Cu(II) complexes including polyamines and dicyano-dithiolate(2-): In vitro cytotoxic activity of Cu(II) compounds
journal, December 2019
- Adhikari, Suman; Bhattacharjee, Tirtha; Butcher, Raymond J.
- Inorganica Chimica Acta, Vol. 498
Synthesis, characterization, toxicity, cytogenetic and in vivo antitumor studies of 1,1-dithiolate Cu(II) complexes with di-, tri-, tetra- amines and 1,3-thiazoles. Structure–activity correlation
journal, April 2009
- Bolos, C. A.; Chaviara, A. T.; Mourelatos, D.
- Bioorganic & Medicinal Chemistry, Vol. 17, Issue 8
Hydroboration of CO 2 catalyzed by bis(phosphinite) pincer ligated nickel thiolate complexes
journal, January 2017
- Liu, Ting; Meng, Wenjuan; Ma, Qiang-Qiang
- Dalton Transactions, Vol. 46, Issue 14
Photosensitizers based on Ir(III) complexes for highly efficient photocatalytic hydrogen generation
journal, November 2019
- Wang, Yue; Zhao, Xinyu; Zhao, Yingnan
- Dyes and Pigments, Vol. 170
Reaction of transition metal thiolato units V. Formation of a binuclear mercury(II) complex with the dithiolato ligand i-mnt (1,1-dicyanoethylene-2,2-dithiolate)
journal, July 1998
- Kang, Bei-Sheng; Chen, Zhong-Ning; Su, Cheng-Yong
- Polyhedron, Vol. 17, Issue 15
Oligoether-Strapped Calix[4]pyrrole: An Ion-Pair Receptor Displaying Cation-Dependent Chloride Anion Transport
journal, February 2012
- Park, In-Won; Yoo, Jaeduk; Kim, Bohyang
- Chemistry - A European Journal, Vol. 18, Issue 9
Roles of thiolate ligands in the synthesis, properties and catalytic application of gold nanoclusters
journal, August 2018
- Nasaruddin, Ricca Rahman; Chen, Tiankai; Yan, Ning
- Coordination Chemistry Reviews, Vol. 368
Unprecedented Inequivalent Metal Coordination Environments in a Mixed-Ligand Dicobalt Complex: Unprecedented Inequivalent Metal Coordination Environments in a Mixed-Ligand Dicobalt Complex
journal, August 2017
- Cioncoloni, Giacomo; Sproules, Stephen; Wilson, Claire
- European Journal of Inorganic Chemistry, Vol. 2017, Issue 31
Highly Phosphorescent Bis-Cyclometalated Iridium Complexes: Synthesis, Photophysical Characterization, and Use in Organic Light Emitting Diodes
journal, May 2001
- Lamansky, Sergey; Djurovich, Peter; Murphy, Drew
- Journal of the American Chemical Society, Vol. 123, Issue 18
New Magnetic Nickel(II)-Thiolate Cluster-Based Coordination Polymer Constructed from 2-Mercaptonicotinic Acid
journal, March 2018
- Yuan, Ning; Tian, Chongbin; Sheng, Tianlu
- Crystal Growth & Design, Vol. 18, Issue 5
Fluorescence sensing of tartaric acid: a case of excimer emission caused by hydrogen bond-mediated complexation
journal, May 2006
- Ghosh, Kumaresh; Adhikari, Suman
- Tetrahedron Letters, Vol. 47, Issue 21
Crystal structure refinement with SHELXL
journal, January 2015
- Sheldrick, George M.
- Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8
Metal–Sulfur Compounds in N 2 Reduction and Nitrogenase-Related Chemistry
journal, May 2020
- Tanifuji, Kazuki; Ohki, Yasuhiro
- Chemical Reviews, Vol. 120, Issue 12
Multicomponent Supramolecular Assemblies of Melamine and α-Hydroxycarboxylic Acids: Understanding the Hydrogen Bonding Patterns and Their Physicochemical Consequences
journal, October 2018
- Castiñeiras, Alfonso; García-Santos, Isabel; González-Pérez, Josefa María
- Crystal Growth & Design, Vol. 18, Issue 11
Response of Hirshfeld Surface to Structural Modifications in Transition-Metal Coordination Compounds
journal, June 2020
- Pinto, Camila Batista; Dos Santos, Leonardo H. R.; Rodrigues, Bernardo Lages
- Crystal Growth & Design, Vol. 20, Issue 7
[NiFe] hydrogenases: A common active site for hydrogen metabolism under diverse conditions
journal, August 2013
- Shafaat, Hannah S.; Rüdiger, Olaf; Ogata, Hideaki
- Biochimica et Biophysica Acta (BBA) - Bioenergetics, Vol. 1827, Issue 8-9
Parallelized Screening of Characterized and DFT-Modeled Bimetallic Colloidal Cocatalysts for Photocatalytic Hydrogen Evolution
journal, March 2020
- Lopato, Eric M.; Eikey, Emily A.; Simon, Zoe C.
- ACS Catalysis, Vol. 10, Issue 7
Blue Dimetallic Complexes of Two Heavy Metal Ions Cd II and Hg II with an Extended Nitrogen Donor Ligand. Preparation, Spectral Characterization, and Crystallographic Studies
journal, December 2003
- Das, Srijit; Hung, Chen-Hsiung; Goswami, Sreebrata
- Inorganic Chemistry, Vol. 42, Issue 25
Nickel Pyridinethiolate Complexes as Catalysts for the Light-Driven Production of Hydrogen from Aqueous Solutions in Noble-Metal-Free Systems
journal, September 2013
- Han, Zhiji; Shen, Luxi; Brennessel, William W.
- Journal of the American Chemical Society, Vol. 135, Issue 39
Towards a functional model of hydrogenase: electrocatalytic reduction of protons to dihydrogen by a nickel macrocyclic complex
journal, April 1992
- Efros, Laura L.; Thorp, H. Holden; Brudvig, Gary W.
- Inorganic Chemistry, Vol. 31, Issue 9
A pyridine-based macrocyclic host for urea and acetone
journal, August 2008
- Ghosh, Kumaresh; Adhikari, Suman; Fröhlich, Roland
- Tetrahedron Letters, Vol. 49, Issue 34
The variable coordination chemistry of a potentially heptadentate ligand with a series of 3d transition metal ions. The chemistry and structures of [M(py3tren)]2+, where M(II) Mn, Fe, Co, Ni, Cu, and Zn and (py3tren) N{CH2CH2C(H)(C5H4N)}3
journal, April 1987
- Kirchner, Richard M.; Mealli, Carlo; Bailey, M.
- Coordination Chemistry Reviews, Vol. 77
Photocatalysis with Transition Metal Based Photosensitizers
journal, December 2019
- Shon, Jong-Hwa; Teets, Thomas S.
- Comments on Inorganic Chemistry, Vol. 40, Issue 2
A Nickel Thiolate Catalyst for the Long-Lived Photocatalytic Production of Hydrogen in a Noble-Metal-Free System
journal, January 2012
- Han, Zhiji; McNamara, William R.; Eum, Min-Sik
- Angewandte Chemie International Edition, Vol. 51, Issue 7
Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt
journal, September 1980
- Fisher, Barbara J.; Eisenberg, Richard
- Journal of the American Chemical Society, Vol. 102, Issue 24, p. 7361-7363
Novel tools for visualizing and exploring intermolecular interactions in molecular crystals
journal, November 2004
- McKinnon, Joshua J.; Spackman, Mark A.; Mitchell, Anthony S.
- Acta Crystallographica Section B Structural Science, Vol. 60, Issue 6
Square-planar d8 metal mixed-ligand dithiolene complexes as second order nonlinear optical chromophores: Structure/property relationship
journal, July 2010
- Deplano, Paola; Pilia, Luca; Espa, Davide
- Coordination Chemistry Reviews, Vol. 254, Issue 13-14
Sustained Solar H 2 Evolution from a Thiazolo[5,4- d ]thiazole-Bridged Covalent Organic Framework and Nickel-Thiolate Cluster in Water
journal, June 2019
- Biswal, Bishnu P.; Vignolo-González, Hugo A.; Banerjee, Tanmay
- Journal of the American Chemical Society, Vol. 141, Issue 28
Multiparametric scaling of diffraction intensities
journal, April 2003
- Otwinowski, Zbyszek; Borek, Dominika; Majewski, Wladyslaw
- Acta Crystallographica Section A Foundations of Crystallography, Vol. 59, Issue 3
[20] Processing of X-ray diffraction data collected in oscillation mode
book, January 1997
- Otwinowski, Zbyszek; Minor, Wladek
- Macromolecular Crystallography Part A, 307-326
Metal dithiolene complexes in olefin addition and purification, small molecule adsorption, H2 evolution and CO2 reduction
journal, October 2020
- Pitchaimani, Jayaraman; Ni, Shao-Fei; Dang, Li
- Coordination Chemistry Reviews, Vol. 420