Isoxazole-Based Electrolytes for Lithium Metal Protection and Lithium-Sulfurized Polyacrylonitrile (SPAN) Battery Operating at Low Temperature
Abstract
Abstract A new electrolyte system using isoxazole as the salt-dissolving solvent has been developed and studied for lithium metal batteries. By using fluoroethylene carbonate (FEC) as an additive and 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (TTE) as a diluent for localized high concentration electrolyte (LHCE), isoxazole-based electrolytes were successfully implemented in lithium metal batteries, demonstrating excellent lithium metal protection capability. Utilizing several advanced characterization techniques (including synchrotron-based X-ray absorption spectroscopy and photoelectron spectroscopy), the solid electrolyte interphase (SEI) formed on the Li-metal anode after employing these electrolytes was thoroughly investigated. The high ionic conductivity of isoxazole at low temperature and the low impedance of SEI formed in LHCE significantly improved the low-temperature performance of Li-sulfurized polyacrylonitrile (SPAN) batteries, delivering 273.8 mAh g-1 capacity at -30°C with 99.85% capacity retention after 50 cycles.
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States). National Synchrotron Light Source II (NSLS-II) and Center for Functional Nanomaterials (CFN)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; USDOE Office of Science (SC)
- OSTI Identifier:
- 1848018
- Alternate Identifier(s):
- OSTI ID: 1846508; OSTI ID: 1847171
- Report Number(s):
- BNL-222810-2022-JAAM
Journal ID: ISSN 0013-4651
- Grant/Contract Number:
- SC0012704; EE0007764; EE0007765
- Resource Type:
- Published Article
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Name: Journal of the Electrochemical Society Journal Volume: 169 Journal Issue: 3; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE
Citation Formats
Tan, Sha, Liu, Haodong, Wu, Zhaohui, Weiland, Conan, Bak, Seong-Min, Ronne, Arthur, Liu, Ping, Whittingham, M. Stanley, Shadike, Zulipiya, Hu, Enyuan, and Yang, Xiao-Qing. Isoxazole-Based Electrolytes for Lithium Metal Protection and Lithium-Sulfurized Polyacrylonitrile (SPAN) Battery Operating at Low Temperature. United States: N. p., 2022.
Web. doi:10.1149/1945-7111/ac58c5.
Tan, Sha, Liu, Haodong, Wu, Zhaohui, Weiland, Conan, Bak, Seong-Min, Ronne, Arthur, Liu, Ping, Whittingham, M. Stanley, Shadike, Zulipiya, Hu, Enyuan, & Yang, Xiao-Qing. Isoxazole-Based Electrolytes for Lithium Metal Protection and Lithium-Sulfurized Polyacrylonitrile (SPAN) Battery Operating at Low Temperature. United States. https://doi.org/10.1149/1945-7111/ac58c5
Tan, Sha, Liu, Haodong, Wu, Zhaohui, Weiland, Conan, Bak, Seong-Min, Ronne, Arthur, Liu, Ping, Whittingham, M. Stanley, Shadike, Zulipiya, Hu, Enyuan, and Yang, Xiao-Qing. Mon .
"Isoxazole-Based Electrolytes for Lithium Metal Protection and Lithium-Sulfurized Polyacrylonitrile (SPAN) Battery Operating at Low Temperature". United States. https://doi.org/10.1149/1945-7111/ac58c5.
@article{osti_1848018,
title = {Isoxazole-Based Electrolytes for Lithium Metal Protection and Lithium-Sulfurized Polyacrylonitrile (SPAN) Battery Operating at Low Temperature},
author = {Tan, Sha and Liu, Haodong and Wu, Zhaohui and Weiland, Conan and Bak, Seong-Min and Ronne, Arthur and Liu, Ping and Whittingham, M. Stanley and Shadike, Zulipiya and Hu, Enyuan and Yang, Xiao-Qing},
abstractNote = {Abstract A new electrolyte system using isoxazole as the salt-dissolving solvent has been developed and studied for lithium metal batteries. By using fluoroethylene carbonate (FEC) as an additive and 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropyl ether (TTE) as a diluent for localized high concentration electrolyte (LHCE), isoxazole-based electrolytes were successfully implemented in lithium metal batteries, demonstrating excellent lithium metal protection capability. Utilizing several advanced characterization techniques (including synchrotron-based X-ray absorption spectroscopy and photoelectron spectroscopy), the solid electrolyte interphase (SEI) formed on the Li-metal anode after employing these electrolytes was thoroughly investigated. The high ionic conductivity of isoxazole at low temperature and the low impedance of SEI formed in LHCE significantly improved the low-temperature performance of Li-sulfurized polyacrylonitrile (SPAN) batteries, delivering 273.8 mAh g-1 capacity at -30°C with 99.85% capacity retention after 50 cycles.},
doi = {10.1149/1945-7111/ac58c5},
journal = {Journal of the Electrochemical Society},
number = 3,
volume = 169,
place = {United States},
year = {Mon Mar 07 00:00:00 EST 2022},
month = {Mon Mar 07 00:00:00 EST 2022}
}
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