A Facile Potential Hold Method for Fostering an Inorganic Solid‐Electrolyte Interphase for Anode‐Free Lithium‐Metal Batteries

Shin, Woochul; Manthiram, Arumugam

doi:10.1002/ange.202115909

Title: A Facile Potential Hold Method for Fostering an Inorganic Solid‐Electrolyte Interphase for Anode‐Free Lithium‐Metal Batteries

Journal Article · 09 February 2022 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.202115909 · OSTI ID:1845159

Shin, Woochul ^[1];

^[1]

Texas Materials Institute University of Texas at Austin Austin TX 78712 USA

Abstract Anode‐free lithium batteries are regarded as an ultimate form of high‐energy‐density lithium‐ion batteries. Unfortunately, irreversible lithium loss during cycling plays a major role in degrading the overall cell performance in the anode‐free configuration. To alleviate the deterioration, building a robust solid‐electrolyte interface on an anode current collector is an indispensable requirement. Here, we present a facile in‐situ electrochemical method of a potential hold during the first charge to guide more salt‐derived (less solvent‐derived) decomposition on the anode interface. We show the distinctive decomposition potential of lithium salts and ether/carbonate solvents, where the Li‐solvation structures with salt contact‐ion‐pairs preferentially decompose to form LiF‐rich and less organic components, leading to enhanced lithium Coulombic efficiency in Li||Cu cells as well as mitigating the capacity fade of Cu||LiFePO ₄ and Cu||LiNi _0.8 Mn _0.1 Co _0.1 O ₂ cells.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: EE0007762

OSTI ID:: 1845159

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 13 Vol. 134; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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