Finding a soft spot for vanadium: a P-bound OCP ligand
Abstract
Transmetallation studies with the phosphaethynolate ion, [OCP]–, have largely resulted in coordination according to classical Lewis acid–base theory. That is, for harder early transition metal ions, O-bound coordination has been observed, whereas in the case of softer late transition metal ions, P-bound coordination predominates. In this work, we report the use of a V(III) complex, namely [(nacnac)VCl(OAr)] (1) (nacnac– = [ArNC(CH3)]2CH; Ar = 2,6-iPr2C6H3), to transmetallate [OCP]– and bind via the P-atom as [(nacnac)V(OAr)(PCO)] (2), the first example of a 3d early transition metal that binds [OCP]– via the P-atom. Full characterization studies of this molecule including HFEPR spectroscopy, SQuID measurements, and theoretical studies are presented.
- Authors:
-
[1];
[4];
[5];
[1]
- Univ. of Pennsylvania, Philadelphia, PA (United States)
- Florida State Univ., Tallahassee, FL (United States). National High Magnetic Field Lab. (MagLab)
- Universidad Tecnica Federico Santa Maria, Valparaiso (Chile)
- Roosevelt Univ., Chicago, IL (United States)
- Eidgenoessische Technische Hochschule (ETH), Zurich (Switzerland)
- Publication Date:
- Research Org.:
- Univ. of Pennsylvania, Philadelphia, PA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division; National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1843654
- Alternate Identifier(s):
- OSTI ID: 1510553
- Grant/Contract Number:
- SC0012486; FG02-07ER15893; DMR-1644779; DEFG02-07ER15893
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 55; Journal Issue: 42; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Grant, Lauren N., Krzystek, J., Pinter, Balazs, Telser, Joshua, Grützmacher, Hansjörg, and Mindiola, Daniel J. Finding a soft spot for vanadium: a P-bound OCP ligand. United States: N. p., 2019.
Web. doi:10.1039/c9cc01500k.
Grant, Lauren N., Krzystek, J., Pinter, Balazs, Telser, Joshua, Grützmacher, Hansjörg, & Mindiola, Daniel J. Finding a soft spot for vanadium: a P-bound OCP ligand. United States. https://doi.org/10.1039/c9cc01500k
Grant, Lauren N., Krzystek, J., Pinter, Balazs, Telser, Joshua, Grützmacher, Hansjörg, and Mindiola, Daniel J. Fri .
"Finding a soft spot for vanadium: a P-bound OCP ligand". United States. https://doi.org/10.1039/c9cc01500k. https://www.osti.gov/servlets/purl/1843654.
@article{osti_1843654,
title = {Finding a soft spot for vanadium: a P-bound OCP ligand},
author = {Grant, Lauren N. and Krzystek, J. and Pinter, Balazs and Telser, Joshua and Grützmacher, Hansjörg and Mindiola, Daniel J.},
abstractNote = {Transmetallation studies with the phosphaethynolate ion, [OCP]–, have largely resulted in coordination according to classical Lewis acid–base theory. That is, for harder early transition metal ions, O-bound coordination has been observed, whereas in the case of softer late transition metal ions, P-bound coordination predominates. In this work, we report the use of a V(III) complex, namely [(nacnac)VCl(OAr)] (1) (nacnac– = [ArNC(CH3)]2CH; Ar = 2,6-iPr2C6H3), to transmetallate [OCP]– and bind via the P-atom as [(nacnac)V(OAr)(PCO)] (2), the first example of a 3d early transition metal that binds [OCP]– via the P-atom. Full characterization studies of this molecule including HFEPR spectroscopy, SQuID measurements, and theoretical studies are presented.},
doi = {10.1039/c9cc01500k},
journal = {ChemComm},
number = 42,
volume = 55,
place = {United States},
year = {Fri Apr 05 00:00:00 EDT 2019},
month = {Fri Apr 05 00:00:00 EDT 2019}
}
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Works referencing / citing this record:
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journal, August 2019
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