Finding a soft spot for vanadium: a P-bound OCP ligand

Grant, Lauren N.; Krzystek, J.; Pinter, Balazs; Telser, Joshua; Grützmacher, Hansjörg; Mindiola, Daniel J.

doi:10.1039/c9cc01500k

Title: Finding a soft spot for vanadium: a P-bound OCP ligand

Journal Article · Tue Jan 01 00:00:00 EST 2019 · ChemComm

DOI:https://doi.org/10.1039/c9cc01500k· OSTI ID:1609800

^[1]; Krzystek, J. ^[2]; Pinter, Balazs ^[3];

^[4];

^[5];

^[1]

Department of Chemistry; University of Pennsylvania; Philadelphia; USA
National High Magnetic Field Laboratory; Florida State University; Tallahassee; USA
Department of Chemistry; Universidad Técnica Federico Santa María; Valparaíso; Chile
Department of Biological; Physical and Health Sciences; Roosevelt University; Chicago; USA
Department of Chemistry and Applied Biosciences; ETH Zürich; Hönggerberg; Switzerland

Transmetallation studies with the phosphaethynolate ion, [OCP]^-, have largely resulted in coordination according to classical Lewis acid–base theory. That is, for harder early transition metal ions, O-bound coordination has been observed, whereas in the case of softer late transition metal ions, P-bound coordination predominates. Herein, we report the use of a V(III) complex, namely [(nacnac)VCl(OAr)] (1) (nacnac^- = [ArNC(CH₃)]₂CH; Ar = 2,6-ⁱPr₂C₆H₃), to transmetallate [OCP]^- and bind via the P-atom as [(nacnac)V(OAr)(PCO)] (2), the first example of a 3d early transition metal that binds [OCP]^-via the P-atom. Full characterization studies of this molecule including HFEPR spectroscopy, SQuID measurements, and theoretical studies are presented.

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Research Organization:: Indiana Univ., Bloomington, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences & Biosciences Division

DOE Contract Number:: FG02-07ER15893

OSTI ID:: 1609800

Journal Information:: ChemComm, Vol. 55, Issue 42; ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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Base induced isomerisation of a phosphaethynolato-borane: mechanistic insights into boryl migration and decarbonylation to afford a triplet phosphinidene Wilson, Daniel W. N.; Franco, Mauricio P.; Myers, William K. Chemical Science, Vol. 11, Issue 3 https://doi.org/10.1039/c9sc05969e	journal	January 2020
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