Molecular Layer Deposition of Crosslinked Polymeric Lithicone for Superior Lithium Metal Anodes

Meng, Xiangbo; Lau, Kah Chun; Zhou, Hua; Ghosh, Sujan Kumar; Benamara, Mourad; Zou, Min

doi:10.34133/2021/9786201

Title: Molecular Layer Deposition of Crosslinked Polymeric Lithicone for Superior Lithium Metal Anodes

Abstract

In this work, we for the first time developed a novel lithium-containing crosslinked polymeric material, a lithicone that enables excellent protection effects over lithium (Li) metal anodes. This new lithicone was synthesized via an accurately controllable molecular layer deposition (MLD) process, in which lithium tert -butoxide (LTB) and glycerol (GL) were used as precursors. The resultant LiGL lithicone was analyzed using a suite of characterizations. Furthermore, we found that the LiGL thichicone could serve as an exceptional polymeric protection film over Li metal anodes. Our experimental data revealed that the Li electrodes coated by this LiGL lithicone can achieve a superior cycling stability, accounting for an extremely long cyclability of >13,600 Li-stripping/plating cycles and having no failures so far in Li/Li symmetric cells at a current density of 5 mA/cm ² and an areal capacity of 1 mAh/cm ² . We found that, with a sufficient protection by this LiGL coating, Li electrodes could realize long-term stable cyclability with little formation of Li dendrites and solid electrolyte interphase. This novel LiGL represents a facile and effective solution to the existing issues of Li anodes and potentially paves a technically feasible route for lithium metal batteries.

Authors:

^[1];

^[2]; Zhou, Hua ^[3]; Ghosh, Sujan Kumar ^[1]; Benamara, Mourad ^[4];

^[1]

Department of Mechanical Engineering, University of Arkansas, Fayetteville, AR 72701, USA
Department of Physics and Astronomy, California State University Northridge, CA 91330, USA
Advanced Photon Source, Argonne National Laboratory, Lemont, IL 60439, USA
Institute for Nanoscience and Engineering, University of Arkansas, Fayetteville, AR 72701, USA

Publication Date:: Tue Sep 07 00:00:00 EDT 2021

Sponsoring Org.:: USDOE

OSTI Identifier:: 1819246

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Published Article

Journal Name:: Energy Material Advances

Additional Journal Information:: Journal Name: Energy Material Advances Journal Volume: 2021; Journal ID: ISSN 2692-7640

Publisher:: American Association for the Advancement of Science (AAAS)

Country of Publication:: United States

Language:: English

Citation Formats


                    Meng, Xiangbo, Lau, Kah Chun, Zhou, Hua, Ghosh, Sujan Kumar, Benamara, Mourad, and Zou, Min. Molecular Layer Deposition of Crosslinked Polymeric Lithicone for Superior Lithium Metal Anodes.  United States: N. p., 2021. 
Web.  doi:10.34133/2021/9786201.

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                    Meng, Xiangbo, Lau, Kah Chun, Zhou, Hua, Ghosh, Sujan Kumar, Benamara, Mourad, & Zou, Min. Molecular Layer Deposition of Crosslinked Polymeric Lithicone for Superior Lithium Metal Anodes.  United States.  https://doi.org/10.34133/2021/9786201

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                    Meng, Xiangbo, Lau, Kah Chun, Zhou, Hua, Ghosh, Sujan Kumar, Benamara, Mourad, and Zou, Min. Tue .  
"Molecular Layer Deposition of Crosslinked Polymeric Lithicone for Superior Lithium Metal Anodes".  United States.  https://doi.org/10.34133/2021/9786201.

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@article{osti_1819246,

  title        = {Molecular Layer Deposition of Crosslinked Polymeric Lithicone for Superior Lithium Metal Anodes},

  author       = {Meng, Xiangbo and Lau, Kah Chun and Zhou, Hua and Ghosh, Sujan Kumar and Benamara, Mourad and Zou, Min},

  abstractNote = {In this work, we for the first time developed a novel lithium-containing crosslinked polymeric material, a lithicone that enables excellent protection effects over lithium (Li) metal anodes. This new lithicone was synthesized via an accurately controllable molecular layer deposition (MLD) process, in which lithium tert -butoxide (LTB) and glycerol (GL) were used as precursors. The resultant LiGL lithicone was analyzed using a suite of characterizations. Furthermore, we found that the LiGL thichicone could serve as an exceptional polymeric protection film over Li metal anodes. Our experimental data revealed that the Li electrodes coated by this LiGL lithicone can achieve a superior cycling stability, accounting for an extremely long cyclability of >13,600 Li-stripping/plating cycles and having no failures so far in Li/Li symmetric cells at a current density of 5 mA/cm 2 and an areal capacity of 1 mAh/cm 2 . We found that, with a sufficient protection by this LiGL coating, Li electrodes could realize long-term stable cyclability with little formation of Li dendrites and solid electrolyte interphase. This novel LiGL represents a facile and effective solution to the existing issues of Li anodes and potentially paves a technically feasible route for lithium metal batteries.},

  doi          = {10.34133/2021/9786201},

  journal      = {Energy Material Advances},

  number       = ,

  volume       = 2021,

  place        = {United States},

  year         = {Tue Sep 07 00:00:00 EDT 2021},

  month        = {Tue Sep 07 00:00:00 EDT 2021}

}

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Title: Molecular Layer Deposition of Crosslinked Polymeric Lithicone for Superior Lithium Metal Anodes

Abstract

Citation Formats

Generalized Gradient Approximation Made Simple journal, October 1996

Tailoring the Mechanical and Electrochemical Properties of an Artificial Interphase for High‐Performance Metallic Lithium Anode journal, June 2020

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Nitrogen-doped graphene-wrapped Cu2S as a superior anode in sodium-ion batteries journal, December 2020

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Atomic and Molecular Layer Deposition for Superior Lithium-Sulfur Batteries: Strategies, Performance, and Mechanisms
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A bidirectional growth mechanism for a stable lithium anode by a platinum nanolayer sputtered on a polypropylene separator
journal, January 2018

Designing composite solid-state electrolytes for high performance lithium ion or lithium metal batteries
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From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999

A Study of Highly Oriented Pyrolytic Graphite as a Model for the Graphite Anode in Li-Ion Batteries
journal, January 1999

Metalcones: Hybrid Organic–Inorganic Films Fabricated Using Atomic and Molecular Layer Deposition Techniques
journal, September 2011

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journal, October 2018

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journal, December 2018

XPS analysis for the lithium surface immersed in γ-butyrolactone containing various salts
journal, May 1995

Electrical Energy Storage and Intercalation Chemistry
journal, June 1976

The Reactivity of Linear Alkyl Carbonates toward Metallic Lithium
journal, January 2002

Nitrogen-doped graphene-wrapped Cu2S as a superior anode in sodium-ion batteries
journal, December 2020

Semiempirical GGA-type density functional constructed with a long-range dispersion correction
journal, January 2006

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journal, December 2010

Elastic, plastic, and creep mechanical properties of lithium metal
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XPS on Li-Battery-Related Compounds: Analysis of Inorganic SEI Phases and a Methodology for Charge Correction
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journal, September 2020

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Protective coatings for lithium metal anodes: Recent progress and future perspectives
journal, February 2020

Directly Formed Alucone on Lithium Metal for High-Performance Li Batteries and Li–S Batteries with High Sulfur Mass Loading
journal, February 2018

A revisit to atomic layer deposition of zinc oxide using diethylzinc and water as precursors
journal, December 2018

PIM-1 as an artificial solid electrolyte interphase for stable lithium metal anode in high-performance batteries
journal, March 2020

Atomic layer deposition of zirconium oxide thin films
journal, November 2019

Li-Containing Organic Thin Film—Structure of Lithium Propane Dioxide via Molecular Layer Deposition
journal, February 2020