Magnetic structure and multiferroicity of Sc-substituted hexagonal YbFeO3

Tang, Y. S.; Wang, S. M.; Lin, L.; Garlea, Vasile Ovidiu; Zou, Tao; Zheng, S. H.; Zhang, H. -M.; Zhou, J. T.; Luo, Z. L.; Yan, Z. B.; Dong, Shuai; Charlton, Timothy R.; Liu, J. -M.

doi:10.1103/physrevb.103.174102

Title: Magnetic structure and multiferroicity of Sc-substituted hexagonal YbFeO₃

Abstract

The hexagonal rare-earth ferrite RFeO₃ family represents a unique class of multiferroics exhibiting weak ferromagnetism, and a strong coupling between magnetism and structural trimerization is predicted. However, the hexagonal structure for RFeO₃ remains metastable in conventional conditions. We have succeeded in stabilizing the hexagonal structure of polycrystalline YbFeO₃ by partial Sc substitution of Yb. Using bulk magnetometry and neutron diffraction, we find that Yb_0.42Sc_0.58FeO₃ orders into a canted antiferromagnetic state with the Néel temperature T_N ~ 165K, below which the Fe³⁺ moments form the triangular configuration in the ab plane and their in-plane projections are parallel to the [100] axis, consistent with magnetic space group P6₃c'm'. It is determined that the spin canting is aligned along the c axis, giving rise to the weak ferromagnetism. Furthermore, the Fe³⁺ moments reorient toward a new direction below reorientation temperature T_R ~ 40K, satisfying magnetic subgroup P6₃, while the Yb³⁺ moments order independently and ferrimagnetically along the c axis at the characteristic temperature T_Yb ~ 15K. Interestingly, reproducible modulation of electric polarization induced by magnetic field at low temperature is achieved, suggesting that the delicate structural distortion associated with two-up/one-down buckling of the Yb/Sc planes and tilting of the FeO₅ bipyramids may mediatemore »« less

Authors:

Tang, Y. S. ^[1]; Wang, S. M. ^[1];

^[1];

^[2]; Zou, Tao ^[3]; Zheng, S. H. ^[1]; Zhang, H. -M. ^[4]; Zhou, J. T. ^[5];

^[5]; Yan, Z. B. ^[1];

^[4];

^[2]; Liu, J. -M. ^[1]

Nanjing Univ. (China)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Shangdong Normal Univ., Jinan (China)
Southeast Univ., Nanjing (China)
Univ. of Science and Technology of China, Hefei (China)

Publication Date:: Thu May 06 00:00:00 EDT 2021

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1818953

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 103; Journal Issue: 17; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; Electric polarization; Magnetic order; Magnetoelectric effect; Multiferroics; Magnetization measurements; Neutron diffraction

Citation Formats


                    Tang, Y. S., Wang, S. M., Lin, L., Garlea, Vasile Ovidiu, Zou, Tao, Zheng, S. H., Zhang, H. -M., Zhou, J. T., Luo, Z. L., Yan, Z. B., Dong, Shuai, Charlton, Timothy R., and Liu, J. -M. Magnetic structure and multiferroicity of Sc-substituted hexagonal YbFeO3.  United States: N. p., 2021. 
Web.  doi:10.1103/physrevb.103.174102.

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                    Tang, Y. S., Wang, S. M., Lin, L., Garlea, Vasile Ovidiu, Zou, Tao, Zheng, S. H., Zhang, H. -M., Zhou, J. T., Luo, Z. L., Yan, Z. B., Dong, Shuai, Charlton, Timothy R., & Liu, J. -M. Magnetic structure and multiferroicity of Sc-substituted hexagonal YbFeO3.  United States.  https://doi.org/10.1103/physrevb.103.174102

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                    Tang, Y. S., Wang, S. M., Lin, L., Garlea, Vasile Ovidiu, Zou, Tao, Zheng, S. H., Zhang, H. -M., Zhou, J. T., Luo, Z. L., Yan, Z. B., Dong, Shuai, Charlton, Timothy R., and Liu, J. -M. Thu .  
"Magnetic structure and multiferroicity of Sc-substituted hexagonal YbFeO3".  United States.  https://doi.org/10.1103/physrevb.103.174102.  https://www.osti.gov/servlets/purl/1818953.

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@article{osti_1818953,

  title        = {Magnetic structure and multiferroicity of Sc-substituted hexagonal YbFeO3},

  author       = {Tang, Y. S. and Wang, S. M. and Lin, L. and Garlea, Vasile Ovidiu and Zou, Tao and Zheng, S. H. and Zhang, H. -M. and Zhou, J. T. and Luo, Z. L. and Yan, Z. B. and Dong, Shuai and Charlton, Timothy R. and Liu, J. -M.},

  abstractNote = {The hexagonal rare-earth ferrite RFeO3 family represents a unique class of multiferroics exhibiting weak ferromagnetism, and a strong coupling between magnetism and structural trimerization is predicted. However, the hexagonal structure for RFeO3 remains metastable in conventional conditions. We have succeeded in stabilizing the hexagonal structure of polycrystalline YbFeO3 by partial Sc substitution of Yb. Using bulk magnetometry and neutron diffraction, we find that Yb0.42Sc0.58FeO3 orders into a canted antiferromagnetic state with the Néel temperature TN ~ 165K, below which the Fe3+ moments form the triangular configuration in the ab plane and their in-plane projections are parallel to the [100] axis, consistent with magnetic space group P63c'm'. It is determined that the spin canting is aligned along the c axis, giving rise to the weak ferromagnetism. Furthermore, the Fe3+ moments reorient toward a new direction below reorientation temperature TR ~ 40K, satisfying magnetic subgroup P63, while the Yb3+ moments order independently and ferrimagnetically along the c axis at the characteristic temperature TYb ~ 15K. Interestingly, reproducible modulation of electric polarization induced by magnetic field at low temperature is achieved, suggesting that the delicate structural distortion associated with two-up/one-down buckling of the Yb/Sc planes and tilting of the FeO5 bipyramids may mediate the coupling between ferroelectric and magnetic orders under magnetic field. Furthermore, the present work represents substantial progress to search for high-temperature multiferroics in hexagonal ferrites and related materials.},

  doi          = {10.1103/physrevb.103.174102},

  journal      = {Physical Review B},

  number       = 17,

  volume       = 103,

  place        = {United States},

  year         = {Thu May 06 00:00:00 EDT 2021},

  month        = {Thu May 06 00:00:00 EDT 2021}

}

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Title: Magnetic structure and multiferroicity of Sc-substituted hexagonal YbFeO3

Abstract

Citation Formats

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Title: Magnetic structure and multiferroicity of Sc-substituted hexagonal YbFeO₃

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Recent advances in magnetic structure determination by neutron powder diffraction
journal, October 1993

Chirality-driven ferroelectricity in LiCuVO4
journal, May 2019

Magnetic Structure and Ordering of Multiferroic Hexagonal ${LuFeO}_{3}$
journal, May 2015

Experimental evidence for an intermediate phase in the multiferroic YMnO ₃
journal, October 2007

Weak Ferromagnetic Transition with a Dielectric Anomaly in Hexagonal Lu _0.5 Sc _0.5 FeO ₃
journal, September 2013

Vortex ferroelectric domains, large-loop weak ferromagnetic domains, and their decoupling in hexagonal (Lu, Sc)FeO3
journal, July 2018

Multiferroic phase diagram of Y partially substituted Dy1−xYxMnO3
journal, January 2011

Commensurate Dy magnetic ordering associated with incommensurate lattice distortion in multiferroic ${DyMnO}_{3}$
journal, May 2006

Room-Temperature Multiferroic Hexagonal ${LuFeO}_{3}$ Films
journal, June 2013

A new protocol for the determination of magnetic structures using simulated annealing and representational analysis (SARAh)
journal, March 2000

Tuning the Néel Temperature of Hexagonal Ferrites by Structural Distortion
journal, December 2018

Ferroelectricity and Ferrimagnetism of Hexagonal YbFeO ₃ Thin Films
journal, February 2012

Structurally Tailored Hexagonal Ferroelectricity and Multiferroism in Epitaxial YbFeO ₃ Thin-Film Heterostructures
journal, January 2012

Room-Temperature Polar Ferromagnet ScFeO ₃ Transformed from a High-Pressure Orthorhombic Perovskite Phase
journal, October 2014

Atomically engineered ferroic layers yield a room-temperature magnetoelectric multiferroic
journal, September 2016

Multiferroics: a magnetic twist for ferroelectricity
journal, January 2007

Ferroelectricity and weak ferromagnetism of hexagonal $ErFe O_{3}$ thin films
journal, August 2015

Enhanced Ferroelectric Polarization by Induced Dy Spin Order in Multiferroic ${DyMnO}_{3}$
journal, February 2007

Multiferroicity: the coupling between magnetic and polarization orders
journal, July 2009

Multiferroic hexagonal ferrites ( h - RFeO ₃ , R = Y , Dy - Lu ): a brief experimental review
journal, August 2014

Spin reorientation behavior in YMn1−xMxO3 (M=Ti, Fe, Ga; x=0, 0.1)
journal, December 2013

Hexagonal phase stabilization and magnetic orders of multiferroic $L u_{1 - x} S c_{x} Fe O_{3}$
journal, February 2016

Electronic structure and direct observation of ferrimagnetism in multiferroic hexagonal ${YbFeO}_{3}$
journal, June 2017

Magnetic-field induced effects on the electric polarization in $R {MnO}_{3} (R = Dy, Gd)$
journal, April 2009

Epitaxially Constrained Hexagonal Ferroelectricity and Canted Triangular Spin Order in LuFeO ₃ Thin Films
journal, June 2012

Spin-Lattice Coupling, Frustration, and Magnetic Order in Multiferroic $R {MnO}_{3}$
journal, August 2009

Epitaxial BiFeO₃ Multiferroic Thin Film Heterostructures
journal, March 2003

Multiferroism in hexagonally stabilized TmFeO ₃ thin films below 120 K
journal, January 2014

Interplay between spin dynamics and crystal field in the multiferroic compound ${HoMnO}_{3}$
journal, September 2019