External-Field-Induced Phase Transformation and Associated Properties in a Ni50Mn34Fe3In13 Metamagnetic Shape Memory Wire
Abstract
Metamagnetic shape memory alloys exhibit a series of intriguing multifunctional properties and have great potential for applications in magnetic actuation, sensing and magnetic refrigeration. However, the poor mechanical properties of these alloys with hardly any tensile deformability seriously limit their practical application. In the present work, we developed a Ni-Fe-Mn-In microwire that exhibits both a giant, tensile superelasticity and a magnetic-field-induced first-order phase transformation. The recoverable strain of superelasticity is more than 20% in the temperature range of 233–283 K, which is the highest recoverable strain reported heretofore in Ni-Mn-based shape memory alloys (SMAs). Moreover, the present microwire exhibits a large shape memory effect with a recoverable strain of up to 13.9% under the constant tensile stress of 225 MPa. As a result of the magnetic-field-induced first-order phase transformation, a large reversible magnetocaloric effect with an isothermal entropy change ΔSm of 15.1 J kg–1 K–1 for a field change from 0.2 T to 5 T was achieved in this microwire. The realization of both magnetic-field and tensile-stress-induced transformations confers on this microwire great potential for application in miniature multi-functional devices and provides an opportunity for multi-functional property optimization under coupled multiple fields.
- Authors:
-
[1];
[1];
[2];
- Univ. of Science and Technology, Beijing (China)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities; Funds for Creative Research Groups of China
- OSTI Identifier:
- 1797818
- Grant/Contract Number:
- AC02-06CH11357; 51731005; 51822102; 52031005; 51831003; 51527801; 51921001; FRF-TP-18-008C1
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Metals
- Additional Journal Information:
- Journal Volume: 11; Journal Issue: 2; Journal ID: ISSN 2075-4701
- Publisher:
- MDPI
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; metamagnetic shape memory alloy; magnetic-field-induced phase transformation; magnetocaloric effect; magnetostructural transformation; martensitic transformation; microwire; shape memory effect; superelasticity
Citation Formats
Chen, Zhen, Cong, Daoyong, Li, Shilei, Zhang, Yin, Li, Shaohui, Cao, Yuxian, Li, Shengwei, Song, Chao, Ren, Yang, and Wang, Yandong. External-Field-Induced Phase Transformation and Associated Properties in a Ni50Mn34Fe3In13 Metamagnetic Shape Memory Wire. United States: N. p., 2021.
Web. doi:10.3390/met11020309.
Chen, Zhen, Cong, Daoyong, Li, Shilei, Zhang, Yin, Li, Shaohui, Cao, Yuxian, Li, Shengwei, Song, Chao, Ren, Yang, & Wang, Yandong. External-Field-Induced Phase Transformation and Associated Properties in a Ni50Mn34Fe3In13 Metamagnetic Shape Memory Wire. United States. https://doi.org/10.3390/met11020309
Chen, Zhen, Cong, Daoyong, Li, Shilei, Zhang, Yin, Li, Shaohui, Cao, Yuxian, Li, Shengwei, Song, Chao, Ren, Yang, and Wang, Yandong. Wed .
"External-Field-Induced Phase Transformation and Associated Properties in a Ni50Mn34Fe3In13 Metamagnetic Shape Memory Wire". United States. https://doi.org/10.3390/met11020309. https://www.osti.gov/servlets/purl/1797818.
@article{osti_1797818,
title = {External-Field-Induced Phase Transformation and Associated Properties in a Ni50Mn34Fe3In13 Metamagnetic Shape Memory Wire},
author = {Chen, Zhen and Cong, Daoyong and Li, Shilei and Zhang, Yin and Li, Shaohui and Cao, Yuxian and Li, Shengwei and Song, Chao and Ren, Yang and Wang, Yandong},
abstractNote = {Metamagnetic shape memory alloys exhibit a series of intriguing multifunctional properties and have great potential for applications in magnetic actuation, sensing and magnetic refrigeration. However, the poor mechanical properties of these alloys with hardly any tensile deformability seriously limit their practical application. In the present work, we developed a Ni-Fe-Mn-In microwire that exhibits both a giant, tensile superelasticity and a magnetic-field-induced first-order phase transformation. The recoverable strain of superelasticity is more than 20% in the temperature range of 233–283 K, which is the highest recoverable strain reported heretofore in Ni-Mn-based shape memory alloys (SMAs). Moreover, the present microwire exhibits a large shape memory effect with a recoverable strain of up to 13.9% under the constant tensile stress of 225 MPa. As a result of the magnetic-field-induced first-order phase transformation, a large reversible magnetocaloric effect with an isothermal entropy change ΔSm of 15.1 J kg–1 K–1 for a field change from 0.2 T to 5 T was achieved in this microwire. The realization of both magnetic-field and tensile-stress-induced transformations confers on this microwire great potential for application in miniature multi-functional devices and provides an opportunity for multi-functional property optimization under coupled multiple fields.},
doi = {10.3390/met11020309},
journal = {Metals},
number = 2,
volume = 11,
place = {United States},
year = {Wed Feb 10 00:00:00 EST 2021},
month = {Wed Feb 10 00:00:00 EST 2021}
}
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