Enhanced negative thermal expansion of boron-doped Fe43Mn28Ga28.97B0.03 alloy

Sun, X. M.; Cong, D. Y.; Ren, Y.; Brown, D. E.; Gallington, L. C.; Li, R. G.; Cao, Y. X.; Chen, Z.; Li, S. H.; Nie, Z. H.; Liu, Z. A.; Wang, Y. D.

doi:10.1016/j.jallcom.2020.157572

Title: Enhanced negative thermal expansion of boron-doped Fe₄₃Mn₂₈Ga_28.97B_0.03 alloy

Abstract

Enhanced negative thermal expansion (NTE) properties are achieved by introducing a little amount of boron in the Fe₄₃Mn₂₈Ga_28.97B_0.03 alloy. As a result, this alloy shows a giant NTE coefficient of alpha(1) = -79.7 x 10^-6 K^-1 in a wide temperature range from 277 K to 136 K. Compared to the NTE characteristics in Fe₄₃Mn₂₈Ga₂₉, the NTE operation temperature window has expanded by 74% with the corresponding coefficient of thermal expansion increased by 57% within the NTE temperature window for the boron-doped Fe₄₃Mn₂₈Ga28.97B0.03. Additionally, in-situ synchrotron high-energy X-ray diffraction results suggest that by boron substitution, the large unit cell volume change across martensitic transformation and the wide phase transition temperature interval are responsible for the pronounced NTE behavior in Fe₄₃Mn₂₈Ga_28.97B_0.03. Moreover, for the Fe₄₃Mn₂₈Ga_28.97B_0.03 NTE material, the compressive strength and strain are significantly improved compared with that of Fe₄₃Mn₂₈Ga₂₉. The present study indicates that Fe₄₃Mn₂₈Ga_28.97B_0.03 with enhanced NTE across martensitic transformation may be used for practical application as thermal-expansion compensators.

Authors:

Sun, X. M. ^[1]; Cong, D. Y. ^[2]; Ren, Y. ^[3]; Brown, D. E. ^[4]; Gallington, L. C. ^[3]; Li, R. G. ^[2]; Cao, Y. X. ^[2]; Chen, Z. ^[2]; Li, S. H. ^[2]; Nie, Z. H. ^[5]; Liu, Z. A. ^[6]; Wang, Y. D. ^[2]

Univ. of Science and Technology Beijing (China). Beijing Advanced Innovation Center for Materials Genome Engineering, State Key Lab. for Advanced Metals and Materials; Chinese Academy of Sciences (CAS), Beijing (China). Inst. of Process Engineering, State Key Lab. of Multi-Phase Complex Systems
Univ. of Science and Technology Beijing (China). Beijing Advanced Innovation Center for Materials Genome Engineering, State Key Lab. for Advanced Metals and Materials
Argonne National Lab. (ANL), Argonne, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States); Northern Illinois Univ., DeKalb, IL (United States)
Beijing Inst. of Technology (China)
Qufu Normal Univ. (China). Experimental Teaching and Equipment Management Center

Publication Date:: Mon Oct 12 00:00:00 EDT 2020

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division; National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities

OSTI Identifier:: 1785099

Grant/Contract Number:: AC02-06CH11357; 51731005; 51822102; 51671180; FRF-TP-18-008C1

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Alloys and Compounds

Additional Journal Information:: Journal Volume: 857; Journal ID: ISSN 0925-8388

Publisher:: Elsevier

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; Chemical substitution; Magnetic functional materials; Martensitic transformation; Negative thermal expansion

Citation Formats


                    Sun, X. M., Cong, D. Y., Ren, Y., Brown, D. E., Gallington, L. C., Li, R. G., Cao, Y. X., Chen, Z., Li, S. H., Nie, Z. H., Liu, Z. A., and Wang, Y. D. Enhanced negative thermal expansion of boron-doped Fe43Mn28Ga28.97B0.03 alloy.  United States: N. p., 2020. 
Web.  doi:10.1016/j.jallcom.2020.157572.

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                    Sun, X. M., Cong, D. Y., Ren, Y., Brown, D. E., Gallington, L. C., Li, R. G., Cao, Y. X., Chen, Z., Li, S. H., Nie, Z. H., Liu, Z. A., & Wang, Y. D. Enhanced negative thermal expansion of boron-doped Fe43Mn28Ga28.97B0.03 alloy.  United States.  https://doi.org/10.1016/j.jallcom.2020.157572

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                    Sun, X. M., Cong, D. Y., Ren, Y., Brown, D. E., Gallington, L. C., Li, R. G., Cao, Y. X., Chen, Z., Li, S. H., Nie, Z. H., Liu, Z. A., and Wang, Y. D. Mon .  
"Enhanced negative thermal expansion of boron-doped Fe43Mn28Ga28.97B0.03 alloy".  United States.  https://doi.org/10.1016/j.jallcom.2020.157572.  https://www.osti.gov/servlets/purl/1785099.

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@article{osti_1785099,

  title        = {Enhanced negative thermal expansion of boron-doped Fe43Mn28Ga28.97B0.03 alloy},

  author       = {Sun, X. M. and Cong, D. Y. and Ren, Y. and Brown, D. E. and Gallington, L. C. and Li, R. G. and Cao, Y. X. and Chen, Z. and Li, S. H. and Nie, Z. H. and Liu, Z. A. and Wang, Y. D.},

  abstractNote = {Enhanced negative thermal expansion (NTE) properties are achieved by introducing a little amount of boron in the Fe43Mn28Ga28.97B0.03 alloy. As a result, this alloy shows a giant NTE coefficient of alpha(1) = -79.7 x 10-6 K-1 in a wide temperature range from 277 K to 136 K. Compared to the NTE characteristics in Fe43Mn28Ga29, the NTE operation temperature window has expanded by 74% with the corresponding coefficient of thermal expansion increased by 57% within the NTE temperature window for the boron-doped Fe43Mn28Ga28.97B0.03. Additionally, in-situ synchrotron high-energy X-ray diffraction results suggest that by boron substitution, the large unit cell volume change across martensitic transformation and the wide phase transition temperature interval are responsible for the pronounced NTE behavior in Fe43Mn28Ga28.97B0.03. Moreover, for the Fe43Mn28Ga28.97B0.03 NTE material, the compressive strength and strain are significantly improved compared with that of Fe43Mn28Ga29. The present study indicates that Fe43Mn28Ga28.97B0.03 with enhanced NTE across martensitic transformation may be used for practical application as thermal-expansion compensators.},

  doi          = {10.1016/j.jallcom.2020.157572},

  journal      = {Journal of Alloys and Compounds},

  number       = ,

  volume       = 857,

  place        = {United States},

  year         = {Mon Oct 12 00:00:00 EDT 2020},

  month        = {Mon Oct 12 00:00:00 EDT 2020}

}

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Title: Enhanced negative thermal expansion of boron-doped Fe43Mn28Ga28.97B0.03 alloy

Abstract

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Title: Enhanced negative thermal expansion of boron-doped Fe₄₃Mn₂₈Ga_28.97B_0.03 alloy

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Structure, Magnetism, and Tunable Negative Thermal Expansion in (Hf,Nb)Fe ₂ Alloys
journal, August 2017

Giant Negative Thermal Expansion in Bonded MnCoGe-Based Compounds with Ni ₂ In-Type Hexagonal Structure
journal, January 2015

Effect of boron on the martensitic transformation and magnetic properties of Ni50Mn36.5Sb13.5−xBx alloys
journal, September 2010

Local Lattice Distortion in the Giant Negative Thermal Expansion Material ${Mn}_{3} {Cu}_{1 - x} {Ge}_{x} N$
journal, November 2008

Magnetoelastic and pressure effects at the antiferro–ferromagnetic transition in Hf _{1− x} Ta _x Fe _{2− y} alloys
journal, December 1996

Magnetic properties and structural transformations in Ni–Co–Mn–Sn multifunctional alloys
journal, August 2012

Thermal expansion anomalies and spontaneous magnetostriction in R2Fe17Cx intermetallic compounds
journal, December 1991

Thermal expansion anomaly and Invar effect of Mn1−xCoxB
journal, February 1992

Large magnetic entropy change and enhanced mechanical properties of Ni–Mn–Sn–C alloys
journal, March 2014

Thermal expansion of the magnetically ordering intermetallics RTMg (R = Eu, Gd and T = Ag, Au)
journal, November 2007

Magnetic-field-induced strain-glass-to-martensite transition in a Fe-Mn-Ga alloy
journal, January 2020

Mechanically induced demagnetization and remanent magnetization rotation in Ni–Mn–Ga (–B) magnetic shape memory alloy
journal, September 2014

Negative Thermal Expansion from 0.3 to 1050 Kelvin in ZrW2O8
journal, April 1996

Colossal negative thermal expansion with an extended temperature interval covering room temperature in fine-powdered Mn _0.98 CoGe
journal, December 2016

Boron’s effect on martensitic transformation and magnetocaloric effect in Ni43Mn46Sn11Bx alloys
journal, March 2008

Negative thermal expansion in Ge-free antiperovskite manganese nitrides: Tin-doping effect
journal, January 2008

Pronounced Negative Thermal Expansion from a Simple Structure: Cubic ScF ₃
journal, November 2010

Large reversible entropy change at the inverse magnetocaloric effect in Ni-Co-Mn-Ga-In magnetic shape memory alloys
journal, June 2013

Adjustable Zero Thermal Expansion in Antiperovskite Manganese Nitride
journal, September 2011

Zero Thermal Expansion in PbTiO ₃ -Based Perovskites
journal, January 2008

Connection of giant volume magnetostriction and colossal magnetoresistance in La0.8Ba0.2MnO3
journal, May 2004

Negative thermal expansion materials: technological key for control of thermal expansion
journal, February 2012

Negative thermal expansion in functional materials: controllable thermal expansion by chemical modifications
journal, January 2015

The comparison of direct and indirect methods for determining the magnetocaloric parameters in the Heusler alloy Ni ₅₀ Mn _34.8 In _14.2 B
journal, May 2012

Critical magnetic behavior of ferromagnetic CdCr $_{2}$ S $_{4}$
journal, October 2013

Colossal negative thermal expansion induced by magnetic phase competition on frustrated lattices in Laves phase compound (Hf,Ta) ${Fe}_{2}$
journal, June 2016

Magnetically driven negative thermal expansion in antiperovskite Ga _1- _x Mn _x N _0.8 Mn ₃ (0.1 ≤ x ≤ 0.3)
journal, November 2015

Negative thermal expansion and spontaneous magnetostriction of Tb2Fe16.5Cr0.5 compound
journal, June 2005

Nature of low-temperature phase transitions in CaMn7O12
journal, October 2005

Giant Negative Thermal Expansion in NaZn ₁₃ -Type La(Fe, Si, Co) ₁₃ Compounds
journal, July 2013

Colossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer
journal, June 2011

Magnetic, transport, and magnetocaloric properties of boron doped Ni-Mn-In alloys
journal, May 2015

Enhanced cyclability of elastocaloric effect in boron-microalloyed Ni-Mn-In magnetic shape memory alloys
journal, April 2017

Manipulating the stability of crystallographic and magnetic sub-lattices: A first-order magnetoelastic transformation in transition metal based Laves phase
journal, August 2018

Large Magnetostriction and Negative Thermal Expansion in the Frustrated Antiferromagnet ${ZnCr}_{2} {Se}_{4}$
journal, April 2007

Effects of the substitution of gallium with boron on the physical and mechanical properties of Ni–Mn–Ga shape memory alloys
journal, July 2014