Localized corrosion: Passive film breakdown vs. Pit growth stability, Part VI: Pit dissolution kinetics of different alloys and a model for pitting and repassivation potentials
Abstract
Here, the pitting resistance of SS316L, SS304, SS430, and pure Fe was studied in chloride-containing solution. Among these alloys, SS316L exhibits the highest pit initiation rate, but also the highest pitting potential. To explain this phenomenon, the maximum pit dissolution current density (idiss,max) of the alloys in saturated pit solution was measured using one-dimensional artificial pit electrodes. A lower idiss,max was found to correlate with higher pitting and repassivation potentials. Based on a recently proposed pitting framework, a conceptual model for pitting and repassivation potentials was established, based on which the effect of idiss,max on pitting resistance was discussed.
- Authors:
-
[1];
- The Ohio State Univ., Columbus, OH (United States)
- The Ohio State Univ., Columbus, OH (United States); Fudan Univ., Shanghai (China)
- Publication Date:
- Research Org.:
- The Ohio State Univ., Columbus, OH (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1852324
- Alternate Identifier(s):
- OSTI ID: 1775709
- Grant/Contract Number:
- SC0016584
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Corrosion Science
- Additional Journal Information:
- Journal Volume: 182; Journal Issue: C; Journal ID: ISSN 0010-938X
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 42 ENGINEERING; pit growth stability; pit dissolution kinetics; pitting potential; repassivation potential; one-dimensional artificial pit electrode
Citation Formats
Li, Tianshu, Wu, Jun, and Frankel, G. S. Localized corrosion: Passive film breakdown vs. Pit growth stability, Part VI: Pit dissolution kinetics of different alloys and a model for pitting and repassivation potentials. United States: N. p., 2021.
Web. doi:10.1016/j.corsci.2021.109277.
Li, Tianshu, Wu, Jun, & Frankel, G. S. Localized corrosion: Passive film breakdown vs. Pit growth stability, Part VI: Pit dissolution kinetics of different alloys and a model for pitting and repassivation potentials. United States. https://doi.org/10.1016/j.corsci.2021.109277
Li, Tianshu, Wu, Jun, and Frankel, G. S. Wed .
"Localized corrosion: Passive film breakdown vs. Pit growth stability, Part VI: Pit dissolution kinetics of different alloys and a model for pitting and repassivation potentials". United States. https://doi.org/10.1016/j.corsci.2021.109277. https://www.osti.gov/servlets/purl/1852324.
@article{osti_1852324,
title = {Localized corrosion: Passive film breakdown vs. Pit growth stability, Part VI: Pit dissolution kinetics of different alloys and a model for pitting and repassivation potentials},
author = {Li, Tianshu and Wu, Jun and Frankel, G. S.},
abstractNote = {Here, the pitting resistance of SS316L, SS304, SS430, and pure Fe was studied in chloride-containing solution. Among these alloys, SS316L exhibits the highest pit initiation rate, but also the highest pitting potential. To explain this phenomenon, the maximum pit dissolution current density (idiss,max) of the alloys in saturated pit solution was measured using one-dimensional artificial pit electrodes. A lower idiss,max was found to correlate with higher pitting and repassivation potentials. Based on a recently proposed pitting framework, a conceptual model for pitting and repassivation potentials was established, based on which the effect of idiss,max on pitting resistance was discussed.},
doi = {10.1016/j.corsci.2021.109277},
journal = {Corrosion Science},
number = C,
volume = 182,
place = {United States},
year = {Wed Jan 27 00:00:00 EST 2021},
month = {Wed Jan 27 00:00:00 EST 2021}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Passive films on stainless steels—chemistry, structure and growth
journal, April 2003
- Olsson, C. -O. A.; Landolt, D.
- Electrochimica Acta, Vol. 48, Issue 9
2001 W.R. Whitney Award Lecture: Understanding the Corrosion of Stainless Steel
journal, December 2001
- Newman, R. C.
- CORROSION, Vol. 57, Issue 12
Electrochemical behavior and compositions of passive films formed on the constituent phases of duplex stainless steel without coupling
journal, August 2015
- Wang, Yi; Cheng, Xuequn; Li, Xiaogang
- Electrochemistry Communications, Vol. 57
X-Ray Photoelectron Spectroscopy and Scanning Tunneling Microscopy Study of Passive Films Formed on (100) Fe-18Cr-13Ni Single-Crystal Surfaces
journal, January 1998
- Maurice, V.
- Journal of The Electrochemical Society, Vol. 145, Issue 3
Localized Corrosion: Passive Film Breakdown vs Pit Growth Stability: Part V. Validation of a New Framework for Pit Growth Stability Using One-Dimensional Artificial Pit Electrodes
journal, January 2019
- Li, Tianshu; Scully, J. R.; Frankel, G. S.
- Journal of The Electrochemical Society, Vol. 166, Issue 11
Localized Corrosion: Passive Film Breakdown vs. Pit Growth Stability: Part IV. The Role of Salt Film in Pit Growth: A Mathematical Framework
journal, January 2019
- Li, Tianshu; Scully, J. R.; Frankel, G. S.
- Journal of The Electrochemical Society, Vol. 166, Issue 6
Influence of Nitrogen on Electrochemical Passivation of High-Nickel Stainless Steels and Thin Molybdenum-Nickel Films
journal, January 1996
- Halada, G. P.; Kim, D.; Clayton, C. R.
- CORROSION, Vol. 52, Issue 1
A Point Defect Model for Anodic Passive Films
journal, January 1981
- Chao, C. Y.
- Journal of The Electrochemical Society, Vol. 128, Issue 6
The role of alloyed molybdenum in the inhibition of pitting corrosion in stainless steels
journal, March 2001
- Ilevbare, G. O.; Burstein, G. T.
- Corrosion Science, Vol. 43, Issue 3
Cryo-based structural characterization and growth model of salt film on metal
journal, September 2020
- Li, Tianshu; Perea, D. E.; Schreiber, D. K.
- Corrosion Science, Vol. 174
The influence of nitrogen and molybdenum on passive films formed on the austenoferritic stainless steel 2205 studied by AES and XPS
journal, March 1995
- Olsson, Claes-Olof A.
- Corrosion Science, Vol. 37, Issue 3
Perspective—Localized Corrosion: Passive Film Breakdown vs Pit Growth Stability
journal, January 2017
- Frankel, G. S.; Li, Tianshu; Scully, J. R.
- Journal of The Electrochemical Society, Vol. 164, Issue 4
The Role of Oxide Films on TiS and Ti 4 C 2 S 2 Inclusions in the Pitting Corrosion Resistance of Stainless Steels
journal, January 2013
- Shimahashi, Naoya; Muto, Izumi; Sugawara, Yu
- Journal of The Electrochemical Society, Vol. 160, Issue 6
Unmasking chloride attack on the passive film of metals
journal, July 2018
- Zhang, B.; Wang, J.; Wu, B.
- Nature Communications, Vol. 9, Issue 1
Transport Processes and the Mechanism of Pitting of Metals
journal, January 1976
- Galvele, Jose R.
- Journal of The Electrochemical Society, Vol. 123, Issue 4
An investigation on the continuous and uniform thin membrane passive film formed on sputtered nanocrystalline stainless steel
journal, March 2016
- Li, Tianshu; Liu, Li; Zhang, Bin
- Corrosion Science, Vol. 104
The dissolution and passivation kinetics of stainless alloys containing molybdenum—II. Dissolution kinetics in artificial pits
journal, January 1985
- Newman, R. C.
- Corrosion Science, Vol. 25, Issue 5
Passive behavior of a bulk nanostructured 316L austenitic stainless steel consisting of nanometer-sized grains with embedded nano-twin bundles
journal, August 2014
- Li, Tianshu; Liu, Li; Zhang, Bin
- Corrosion Science, Vol. 85
Pitting Corrosion of Metals
journal, January 1998
- Frankel, G. S.
- Journal of The Electrochemical Society, Vol. 145, Issue 6
An XPS and electrochemical study of the influence of molybdenum and nitrogen on the passivity of austenitic stainless steel
journal, January 1990
- Willenbruch, R. D.; Clayton, C. R.; Oversluizen, M.
- Corrosion Science, Vol. 31, p. 179-190
Technical Note: Syringe Cell for Electrochemical Testing
journal, May 2018
- Panindre, A. M.; Chang, K. H.; Weirich, T.
- Corrosion, Vol. 74, Issue 8
Composition changes around sulphide inclusions in stainless steels, and implications for the initiation of pitting corrosion
journal, November 2010
- Williams, David E.; Kilburn, Matt R.; Cliff, John
- Corrosion Science, Vol. 52, Issue 11
Adsorption of sulfate and chloride ions on aluminum
journal, June 1998
- Kolics, A.; Polkinghorne, J. C.; Wieckowski, A.
- Electrochimica Acta, Vol. 43, Issue 18
Angle-resolved XPS analysis of molybdenum and tungsten in passive films on stainless steel PVD alloys
journal, January 2002
- Olsson, C. -O. A.; Mathieu, H. -J.; Landolt, D.
- Surface and Interface Analysis, Vol. 34, Issue 1
Localized corrosion behavior of a single-phase non-equimolar high entropy alloy
journal, May 2019
- Li, Tianshu; Swanson, Orion J.; Frankel, G. S.
- Electrochimica Acta, Vol. 306
Identification of Mo(V) commonly observed in passive films formed on stainless steels
journal, February 1998
- Kim, Dongil; Kagwade, S. V.; Clayton, C. R.
- Surface and Interface Analysis, Vol. 26, Issue 2
Chloride Ingress into Aluminum Prior to Pitting Corrosion An Investigation by XANES and XPS
journal, January 2000
- Yu, S. Y.; O'Grady, W. E.; Ramaker, D. E.
- Journal of The Electrochemical Society, Vol. 147, Issue 8
Localized corrosion (pitting): A model of passivity breakdown including the role of the oxide layer nanostructure
journal, September 2008
- Marcus, P.; Maurice, V.; Strehblow, H. -H.
- Corrosion Science, Vol. 50, Issue 9
Resistance for Flow of Current to a Disk
journal, January 1966
- Newman, John
- Journal of The Electrochemical Society, Vol. 113, Issue 5
Pitting Corrosion of Very Clean Type 304 Stainless Steel
journal, February 2014
- Jun, Jiheon; Holguin, K.; Frankel, G. S.
- CORROSION, Vol. 70, Issue 2
The nucleation, growth and stability of micropits in stainless steel
journal, July 1994
- Williams, David E.; Stewart, John; Balkwill, Peter H.
- Corrosion Science, Vol. 36, Issue 7
NanoSIMS investigation of passive oxide films on high-Cr cast iron
journal, February 2013
- Salasi, M.; Stachowiak, G. B.; Stachowiak, G. W.
- Corrosion Science, Vol. 67
Surface science approach of corrosion phenomena
journal, January 1998
- Marcus, P.
- Electrochimica Acta, Vol. 43, Issue 1-2
Localized Corrosion: Passive Film Breakdown vs Pit Growth Stability: Part II. A Model for Critical Pitting Temperature
journal, January 2018
- Li, Tianshu; Scully, J. R.; Frankel, G. S.
- Journal of The Electrochemical Society, Vol. 165, Issue 9
Mass transfer and electrochemical kinetic interactions in localized pitting corrosion
journal, June 1986
- Gaudet, G. T.; Mo, W. T.; Hatton, T. A.
- AIChE Journal, Vol. 32, Issue 6
DFT-Based Calculation of Dissolution Activation Energy and Kinetics of Ni–Cr Alloys
journal, October 2020
- Ke, Huibin; Taylor, Christopher D.
- Journal of The Electrochemical Society, Vol. 167, Issue 13
Corrosion and repassivation of Super 13Cr stainless steel in artificial 1D pit electrodes at elevated temperature
journal, August 2020
- Jun, Jiheon; Li, Tianshu; Frankel, G. S.
- Corrosion Science, Vol. 173
On some fundamental factors in the effect of alloying elements on passivation of alloys
journal, December 1994
- Marcus, P.
- Corrosion Science, Vol. 36, Issue 12
Localized Corrosion: Passive Film Breakdown vs. Pit Growth Stability: Part III. A Unifying Set of Principal Parameters and Criteria for Pit Stabilization and Salt Film Formation
journal, January 2018
- Li, Tianshu; Scully, J. R.; Frankel, G. S.
- Journal of The Electrochemical Society, Vol. 165, Issue 11
Chloride Ion Interactions with Oxide-Covered Aluminum Leading to Pitting Corrosion: A Review
journal, January 2014
- Natishan, P. M.; O’Grady, W. E.
- Journal of The Electrochemical Society, Vol. 161, Issue 9
Localised dissolution kinetics, salt films and pitting potentials
journal, October 1997
- Laycock, N. J.; Newman, R. C.
- Corrosion Science, Vol. 39, Issue 10-11
Understanding localized corrosion
journal, October 2008
- Frankel, G. S.; Sridhar, N.
- Materials Today, Vol. 11, Issue 10
Inclusions in Stainless Steels − A Review
journal, August 2017
- Park, Joo Hyun; Kang, Youngjo
- steel research international, Vol. 88, Issue 12
Integrated computational materials engineering of corrosion resistant alloys
journal, February 2018
- Taylor, Christopher D.; Lu, Pin; Saal, James
- npj Materials Degradation, Vol. 2, Issue 1
XPS and STM Investigation of the Passive Film Formed on Cr(110) Single-Crystal Surfaces
journal, January 1994
- Maurice, V.
- Journal of The Electrochemical Society, Vol. 141, Issue 11
Bond-order bond energy model for alloys
journal, October 2019
- Oberdorfer, Christian; Windl, Wolfgang
- Acta Materialia, Vol. 179
Chloride Uptake by Oxide Covered Aluminum as Determined by X-Ray Photoelectron and X-Ray Absorption Spectroscopy
journal, January 1999
- Natishan, P. M.
- Journal of The Electrochemical Society, Vol. 146, Issue 5
Stochastic Models of Pitting Corrosion of Stainless Steels: I . Modeling of the Initiation and Growth of Pits at Constant Potential
journal, August 1985
- Williams, D. E.; Westcott, C.; Fleischmann, M.
- Journal of The Electrochemical Society, Vol. 132, Issue 8
Growth of single corrosion pit in sputtered nanocrystalline stainless steel film
journal, October 2016
- Li, Tianshu; Liu, Li; Zhang, Bin
- Corrosion Science, Vol. 111
Metastable Pitting of Stainless Steel
journal, July 1987
- Frankel, G. S.; Stockert, L.; Hunkeler, F.
- CORROSION, Vol. 43, Issue 7