Localized Corrosion: Passive Film Breakdown vs Pit Growth Stability: Part V. Validation of a New Framework for Pit Growth Stability Using One-Dimensional Artificial Pit Electrodes

Li, Tianshu; Scully, J. R.; Frankel, G. S.

doi:10.1149/2.0431911jes

Title: Localized Corrosion: Passive Film Breakdown vs Pit Growth Stability: Part V. Validation of a New Framework for Pit Growth Stability Using One-Dimensional Artificial Pit Electrodes

Abstract

Experimental evidence is provided to support the validity of a new framework for pit growth stability established in previous papers in this series. Downward potential scans from the diffusion-controlled condition were performed on SS316L one-dimensional (1D) artificial pit electrodes in 0.6 M NaCl. The variation of the critical pit surface potential for salt film formation with pit depth was in agreement with the theoretical prediction of the new framework. Using pits of different depths, the maximum pit dissolution current density, i_diss,max, was obtained as a function of maximum pit surface potential, E_max, at fixed pit surface metal cation concentrations, C_surf, equal to the saturation concentration, C_sat, and 70%C_sat. The apparent Tafel slope of the pit dissolution kinetics determined using the downward potential scan of a 1D pit in the charge-transfer-controlled region, where C_surf changes continuously during the scan, was smaller than the Tafel slope for i_diss,max(E_max) at a fixed C_surf, indicating that C_surf is a key parameter for pit dissolution. The critical concentration for pit stability/repassivation was found to be approximately 43% of C_sat. Charge-transfer-controlled 1D pit growth was shown to be a transient state, which will spontaneously transition to diffusion-controlled growth in accordance with the predictions of the newmore » framework.« less

Authors:

;

Publication Date:: Tue Jan 01 00:00:00 EST 2019

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Center for Performance and Design of Nuclear Waste Forms and Containers (WastePD); The Ohio State Univ., Columbus, OH (United States); Univ. of Virginia, Charlottesville, VA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1524476

Alternate Identifier(s):: OSTI ID: 1601002

Grant/Contract Number:: SC0016584

Resource Type:: Published Article

Journal Name:: Journal of the Electrochemical Society

Additional Journal Information:: Journal Name: Journal of the Electrochemical Society Journal Volume: 166 Journal Issue: 11; Journal ID: ISSN 0013-4651

Publisher:: IOP Publishing - The Electrochemical Society

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; Corrosion; Pit dissolution kinetics; Pit growth stability; Pitting Corrosion

Citation Formats


                    Li, Tianshu, Scully, J. R., and Frankel, G. S. Localized Corrosion: Passive Film Breakdown vs Pit Growth Stability: Part V. Validation of a New Framework for Pit Growth Stability Using One-Dimensional Artificial Pit Electrodes.  United States: N. p., 2019. 
Web.  doi:10.1149/2.0431911jes.

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                    Li, Tianshu, Scully, J. R., & Frankel, G. S. Localized Corrosion: Passive Film Breakdown vs Pit Growth Stability: Part V. Validation of a New Framework for Pit Growth Stability Using One-Dimensional Artificial Pit Electrodes.  United States.  https://doi.org/10.1149/2.0431911jes

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                    Li, Tianshu, Scully, J. R., and Frankel, G. S. Tue .  
"Localized Corrosion: Passive Film Breakdown vs Pit Growth Stability: Part V. Validation of a New Framework for Pit Growth Stability Using One-Dimensional Artificial Pit Electrodes".  United States.  https://doi.org/10.1149/2.0431911jes.

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@article{osti_1524476,

  title        = {Localized Corrosion: Passive Film Breakdown vs Pit Growth Stability: Part V. Validation of a New Framework for Pit Growth Stability Using One-Dimensional Artificial Pit Electrodes},

  author       = {Li, Tianshu and Scully, J. R. and Frankel, G. S.},

  abstractNote = {Experimental evidence is provided to support the validity of a new framework for pit growth stability established in previous papers in this series. Downward potential scans from the diffusion-controlled condition were performed on SS316L one-dimensional (1D) artificial pit electrodes in 0.6 M NaCl. The variation of the critical pit surface potential for salt film formation with pit depth was in agreement with the theoretical prediction of the new framework. Using pits of different depths, the maximum pit dissolution current density, idiss,max, was obtained as a function of maximum pit surface potential, Emax, at fixed pit surface metal cation concentrations, Csurf, equal to the saturation concentration, Csat, and 70%Csat. The apparent Tafel slope of the pit dissolution kinetics determined using the downward potential scan of a 1D pit in the charge-transfer-controlled region, where Csurf changes continuously during the scan, was smaller than the Tafel slope for idiss,max(Emax) at a fixed Csurf, indicating that Csurf is a key parameter for pit dissolution. The critical concentration for pit stability/repassivation was found to be approximately 43% of Csat. Charge-transfer-controlled 1D pit growth was shown to be a transient state, which will spontaneously transition to diffusion-controlled growth in accordance with the predictions of the new framework.},

  doi          = {10.1149/2.0431911jes},

  journal      = {Journal of the Electrochemical Society},

  number       = 11,

  volume       = 166,

  place        = {United States},

  year         = {Tue Jan 01 00:00:00 EST 2019},

  month        = {Tue Jan 01 00:00:00 EST 2019}

}

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Works referenced in this record:

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Transport and Reaction during Pitting Corrosion of Ni in 0.5M NaCl
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Localized Corrosion: Passive Film Breakdown vs. Pit Growth Stability: Part IV. The Role of Salt Film in Pit Growth: A Mathematical Framework
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Works referencing / citing this record:

The Contrast between the Pitting Corrosion of 316 SS in NaCl and NaBr Solutions: Part II. Morphology, Chemistry, and Stabilization of the Pits
journal, January 2019

Pahlavan, Sohrab; Moayed, Mohammad Hadi; Mirjalili, Mostafa
Journal of The Electrochemical Society, Vol. 166, Issue 12
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Localized corrosion and stress corrosion cracking of stainless steels in halides other than chlorides solutions: a review
journal, February 2020

Kappes, Mariano A.
Corrosion Reviews, Vol. 38, Issue 1
DOI: 10.1515/corrrev-2019-0061

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Title: Localized Corrosion: Passive Film Breakdown vs Pit Growth Stability: Part V. Validation of a New Framework for Pit Growth Stability Using One-Dimensional Artificial Pit Electrodes

Abstract

Citation Formats

On a Recent Quantitative Framework Examining the Critical Factors for Localized Corrosion and Its Impact on the Galvele Pit Stability Criterion journal, January 2017

Resistance for Flow of Current to a Disk journal, January 1966

Transport and Reaction during Pitting Corrosion of Ni in 0.5M NaCl journal, January 1991

On the Mechanism of Localized Corrosion of Iron and Stainless Steel journal, January 1972

Localized Corrosion: Passive Film Breakdown vs. Pit Growth Stability: Part IV. The Role of Salt Film in Pit Growth: A Mathematical Framework journal, January 2019

An alternative method to determine critical pitting temperature of stainless steels in ferric chloride solution journal, January 1994

Effects of environmental factors on key kinetic parameters relevant to pitting corrosion journal, March 2015

Geometric Evolution of Flux from a Corroding One-Dimensional Pit and Its Implications on the Evaluation of Kinetic Parameters for Pit Stability journal, January 2016

Localized Corrosion: Passive Film Breakdown vs Pit Growth Stability: Part II. A Model for Critical Pitting Temperature journal, January 2018

Temperature dependence of pitting potentials for austenitic stainless steels above their critical pitting temperature journal, June 1998

Perspective—Localized Corrosion: Passive Film Breakdown vs Pit Growth Stability journal, January 2017

Mass transfer and electrochemical kinetic interactions in localized pitting corrosion journal, June 1986

Modelling pitting corrosion of stainless steel in atmospheric exposures to chloride containing environments journal, June 2014

Metastable Pitting and the Critical Pitting Temperature journal, January 1998

Initiation of Corrosion Pits at Inclusions on 304 Stainless Steel journal, January 1995

One-Dimensional Pit Experiments and Modeling to Determine Critical Factors for Pit Stability and Repassivation journal, January 2016

Transport Processes and the Mechanism of Pitting of Metals journal, January 1976

Localized Corrosion: Passive Film Breakdown vs. Pit Growth Stability: Part III. A Unifying Set of Principal Parameters and Criteria for Pit Stabilization and Salt Film Formation journal, January 2018

The dissolution and passivation kinetics of stainless alloys containing molybdenum—II. Dissolution kinetics in artificial pits journal, January 1985

Localised dissolution kinetics, salt films and pitting potentials journal, October 1997

Electrodissolution Kinetics of Iron in Chloride Solutions journal, January 1978

Metastable Pitting of Aluminum and Criteria for the Transition to Stable Pit Growth journal, January 1994

Applicability of Repassivation Potential for Long-Term Prediction of Localized Corrosion of Alloy 825 and Type 316L Stainless Steel journal, November 1993

Pitting Corrosion of Metals journal, January 1998

Long-Term Prediction of Localized Corrosion of Alloy 825 in High-Level Nuclear Waste Repository Environments journal, February 1996

Growth of single corrosion pit in sputtered nanocrystalline stainless steel film journal, October 2016

The influence of chloride ions on the kinetics of iron dissolution journal, June 1973

Metastable Pitting of Stainless Steel journal, July 1987

On the Mechanism of Localized Corrosion of Iron and Stainless Steel journal, January 1972

The Contrast between the Pitting Corrosion of 316 SS in NaCl and NaBr Solutions: Part II. Morphology, Chemistry, and Stabilization of the Pits journal, January 2019

Localized corrosion and stress corrosion cracking of stainless steels in halides other than chlorides solutions: a review journal, February 2020

On a Recent Quantitative Framework Examining the Critical Factors for Localized Corrosion and Its Impact on the Galvele Pit Stability Criterion
journal, January 2017

Resistance for Flow of Current to a Disk
journal, January 1966

Transport and Reaction during Pitting Corrosion of Ni in 0.5M NaCl
journal, January 1991

On the Mechanism of Localized Corrosion of Iron and Stainless Steel
journal, January 1972

Localized Corrosion: Passive Film Breakdown vs. Pit Growth Stability: Part IV. The Role of Salt Film in Pit Growth: A Mathematical Framework
journal, January 2019

An alternative method to determine critical pitting temperature of stainless steels in ferric chloride solution
journal, January 1994

Effects of environmental factors on key kinetic parameters relevant to pitting corrosion
journal, March 2015

Geometric Evolution of Flux from a Corroding One-Dimensional Pit and Its Implications on the Evaluation of Kinetic Parameters for Pit Stability
journal, January 2016

Localized Corrosion: Passive Film Breakdown vs Pit Growth Stability: Part II. A Model for Critical Pitting Temperature
journal, January 2018

Temperature dependence of pitting potentials for austenitic stainless steels above their critical pitting temperature
journal, June 1998

Perspective—Localized Corrosion: Passive Film Breakdown vs Pit Growth Stability
journal, January 2017

Mass transfer and electrochemical kinetic interactions in localized pitting corrosion
journal, June 1986

Modelling pitting corrosion of stainless steel in atmospheric exposures to chloride containing environments
journal, June 2014

Metastable Pitting and the Critical Pitting Temperature
journal, January 1998

Initiation of Corrosion Pits at Inclusions on 304 Stainless Steel
journal, January 1995

One-Dimensional Pit Experiments and Modeling to Determine Critical Factors for Pit Stability and Repassivation
journal, January 2016

Transport Processes and the Mechanism of Pitting of Metals
journal, January 1976

Localized Corrosion: Passive Film Breakdown vs. Pit Growth Stability: Part III. A Unifying Set of Principal Parameters and Criteria for Pit Stabilization and Salt Film Formation
journal, January 2018

The dissolution and passivation kinetics of stainless alloys containing molybdenum—II. Dissolution kinetics in artificial pits
journal, January 1985

Localised dissolution kinetics, salt films and pitting potentials
journal, October 1997

Electrodissolution Kinetics of Iron in Chloride Solutions
journal, January 1978

Metastable Pitting of Aluminum and Criteria for the Transition to Stable Pit Growth
journal, January 1994

Applicability of Repassivation Potential for Long-Term Prediction of Localized Corrosion of Alloy 825 and Type 316L Stainless Steel
journal, November 1993

Pitting Corrosion of Metals
journal, January 1998

Long-Term Prediction of Localized Corrosion of Alloy 825 in High-Level Nuclear Waste Repository Environments
journal, February 1996

Growth of single corrosion pit in sputtered nanocrystalline stainless steel film
journal, October 2016

The influence of chloride ions on the kinetics of iron dissolution
journal, June 1973

Metastable Pitting of Stainless Steel
journal, July 1987

On the Mechanism of Localized Corrosion of Iron and Stainless Steel
journal, January 1972

The Contrast between the Pitting Corrosion of 316 SS in NaCl and NaBr Solutions: Part II. Morphology, Chemistry, and Stabilization of the Pits
journal, January 2019

Localized corrosion and stress corrosion cracking of stainless steels in halides other than chlorides solutions: a review
journal, February 2020