Phase stabilization and oxidation of a continuous composition spread multi-principal element (AlFeNiTiVZr)1-xCrx alloy
Abstract
Multi-Principal Element Alloys (MPEA) have been hypothesized to maintain a stable single alloy phase and resist corrosion at high temperatures, which are desirable in various functional applications, including material of turbine blades. However, studies into oxidation resistant alloys have been constrained to individual MPEA systems or a limited selection of compositions within those systems. Here, High-Throughput Experimental (HTE) techniques were utilized to rapidly assess phase stability and resistance to oxidation of an (AlFeNiTiVZr)1-xCrx continuous composition spread (CCS) thin-film alloy system. High-throughput synchrotron diffraction and Raman spectroscopy were used to identify phases, especially high symmetry structures and oxides, as a function of annealing time and composition. The formation of two distinct phase regions, R1 and R2, across the CCS was observed. One of these phase regions, R2, exhibited a stable high symmetry BCC-like phase at Cr concentrations greater than 25.4 at%, and grew a passivating mixed metal surface oxide; whereas, the R1 phase region, decomposed on oxidation to multiple oxides and reacted with the substrate to form silicides. The passivating mixed metal oxide layer appears to prevent destabilization of the (AlFeNiTiVZr)1-xCrx MPEA BCC solid solution. Furthermore, at longer annealing times the passivating phase was seen only above 29.2 at% Cr. Highmore »
- Authors:
-
[1];
[3];
- Univ. of South Carolina, Columbia, SC (United States); Univ. of South Carolina, Columbia, SC (United States). SmartState Center for the Strategic Approaches to the Generation of Electricity
- AccuStrata Inc., Rockville, MD (United States)
- SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource (SSRL)
- Univ. of Maryland, College Park, MD (United States)
- National Inst. of Standards and Technology (NIST), Gaithersburg, MD (United States)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1774933
- Grant/Contract Number:
- AC02-76SF00515
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Alloys and Compounds
- Additional Journal Information:
- Journal Volume: 861; Journal ID: ISSN 0925-8388
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Metals and alloys; thin films; optical spectroscopy; x-ray diffraction; phase transitions; oxidation
Citation Formats
Ruiz-Yi, Benjamin, Williams, Travis, Bunn, Jonathan Kenneth, Ren, Fang, Hasan, Naila Al, Takeuchi, Ichiro, Hattrick-Simpers, Jason, and Mehta, Apurva. Phase stabilization and oxidation of a continuous composition spread multi-principal element (AlFeNiTiVZr)1-xCrx alloy. United States: N. p., 2020.
Web. doi:10.1016/j.jallcom.2020.158565.
Ruiz-Yi, Benjamin, Williams, Travis, Bunn, Jonathan Kenneth, Ren, Fang, Hasan, Naila Al, Takeuchi, Ichiro, Hattrick-Simpers, Jason, & Mehta, Apurva. Phase stabilization and oxidation of a continuous composition spread multi-principal element (AlFeNiTiVZr)1-xCrx alloy. United States. https://doi.org/10.1016/j.jallcom.2020.158565
Ruiz-Yi, Benjamin, Williams, Travis, Bunn, Jonathan Kenneth, Ren, Fang, Hasan, Naila Al, Takeuchi, Ichiro, Hattrick-Simpers, Jason, and Mehta, Apurva. Wed .
"Phase stabilization and oxidation of a continuous composition spread multi-principal element (AlFeNiTiVZr)1-xCrx alloy". United States. https://doi.org/10.1016/j.jallcom.2020.158565. https://www.osti.gov/servlets/purl/1774933.
@article{osti_1774933,
title = {Phase stabilization and oxidation of a continuous composition spread multi-principal element (AlFeNiTiVZr)1-xCrx alloy},
author = {Ruiz-Yi, Benjamin and Williams, Travis and Bunn, Jonathan Kenneth and Ren, Fang and Hasan, Naila Al and Takeuchi, Ichiro and Hattrick-Simpers, Jason and Mehta, Apurva},
abstractNote = {Multi-Principal Element Alloys (MPEA) have been hypothesized to maintain a stable single alloy phase and resist corrosion at high temperatures, which are desirable in various functional applications, including material of turbine blades. However, studies into oxidation resistant alloys have been constrained to individual MPEA systems or a limited selection of compositions within those systems. Here, High-Throughput Experimental (HTE) techniques were utilized to rapidly assess phase stability and resistance to oxidation of an (AlFeNiTiVZr)1-xCrx continuous composition spread (CCS) thin-film alloy system. High-throughput synchrotron diffraction and Raman spectroscopy were used to identify phases, especially high symmetry structures and oxides, as a function of annealing time and composition. The formation of two distinct phase regions, R1 and R2, across the CCS was observed. One of these phase regions, R2, exhibited a stable high symmetry BCC-like phase at Cr concentrations greater than 25.4 at%, and grew a passivating mixed metal surface oxide; whereas, the R1 phase region, decomposed on oxidation to multiple oxides and reacted with the substrate to form silicides. The passivating mixed metal oxide layer appears to prevent destabilization of the (AlFeNiTiVZr)1-xCrx MPEA BCC solid solution. Furthermore, at longer annealing times the passivating phase was seen only above 29.2 at% Cr. High Cr-doped (AlFeNiTiVZr)1-xCrx appear to be a good candidate for high temperature, oxidation-resistant structural alloys.},
doi = {10.1016/j.jallcom.2020.158565},
journal = {Journal of Alloys and Compounds},
number = ,
volume = 861,
place = {United States},
year = {Wed Dec 30 00:00:00 EST 2020},
month = {Wed Dec 30 00:00:00 EST 2020}
}
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Works referenced in this record:
Development of multifunctional thin films using high-throughput experimentation methods
journal, October 2008
- Ludwig, Alfred; Zarnetta, Robert; Hamann, Sven
- International Journal of Materials Research, Vol. 99, Issue 10
Phase equilibria, microstructure, and high temperature oxidation resistance of novel refractory high-entropy alloys
journal, March 2015
- Gorr, B.; Azim, M.; Christ, H. -J.
- Journal of Alloys and Compounds, Vol. 624
A Semi-Empirical Model for Tilted-Gun Planar Magnetron Sputtering Accounting for Chimney Shadowing
journal, December 2014
- Bunn, J. K.; Metting, C. J.; Hattrick-Simpers, J.
- JOM, Vol. 67, Issue 1
In situ Raman spectroscopy of alumina-supported metal oxide catalysts
journal, June 1992
- Vuurman, Michael A.; Wachs, Israel E.
- The Journal of Physical Chemistry, Vol. 96, Issue 12
Raman spectroscopic studies of Ni–W oxide thin films
journal, March 2001
- Lee, S; Chong, Hyeonsik M.; Park, Nam-Gyu
- Solid State Ionics, Vol. 140, Issue 1-2, p. 135-139
Phonon properties in narrow gap FeSi and FeSb2 single crystals
journal, April 2008
- Racu, A. -M.; Menzel, D.; Schoenes, J.
- Journal of Applied Physics, Vol. 103, Issue 7
Rapid structural mapping of ternary metallic alloy systems using the combinatorial approach and cluster analysis
journal, July 2007
- Long, C. J.; Hattrick-Simpers, J.; Murakami, M.
- Review of Scientific Instruments, Vol. 78, Issue 7
Oxidation of CoCrFeMnNi High Entropy Alloys
journal, June 2015
- Holcomb, Gordon R.; Tylczak, Joseph; Carney, Casey
- JOM, Vol. 67, Issue 10
Combinatorial Approach to Turbine Bond Coat Discovery
journal, May 2013
- Metting, Christopher Jason; Bunn, Jonathan Kenneth; Underwood, Ellen
- ACS Combinatorial Science, Vol. 15, Issue 8
Multi-Principal-Element Alloys with Improved Oxidation and Wear Resistance for Thermal Spray Coating
journal, February 2004
- Huang, P. -K.; Yeh, J. -W.; Shun, T. -T.
- Advanced Engineering Materials, Vol. 6, Issue 12
The single-crystal Raman spectra of nearly opaque materials. Iron(III) oxide and chromium(III) oxide
journal, January 1970
- Beattie, I. R.; Gilson, T. R.
- Journal of the Chemical Society A: Inorganic, Physical, Theoretical
Identification of iron oxide phases in thin films grown on Al2O3(0001) by Raman spectroscopy and X-ray diffraction
journal, April 2010
- Lübbe, Maike; Gigler, Alexander M.; Stark, Robert W.
- Surface Science, Vol. 604, Issue 7-8
On Raman spectroscopy of zirconium oxide films
journal, August 1997
- Barberis, P.; Merle-Méjean, T.; Quintard, P.
- Journal of Nuclear Materials, Vol. 246, Issue 2-3
The Power of High-Throughput Experimentation in Homogeneous Catalysis Research for Fine Chemicals
journal, March 2003
- Vries, Johannes G. de; Vries, André H. M. de
- European Journal of Organic Chemistry, Vol. 2003, Issue 5
Applications of high throughput (combinatorial) methodologies to electronic, magnetic, optical, and energy-related materials
journal, June 2013
- Green, Martin L.; Takeuchi, Ichiro; Hattrick-Simpers, Jason R.
- Journal of Applied Physics, Vol. 113, Issue 23
Raman spectroscopic and photoluminescence investigations on laser surface modified α-Al2O3 coatings
journal, April 2003
- Krishnan, R.; Kesavamoorthy, R.; Dash, S.
- Scripta Materialia, Vol. 48, Issue 8
Wear resistance and high-temperature compression strength of Fcc CuCoNiCrAl0.5Fe alloy with boron addition
journal, May 2004
- Hsu, Chin-You; Yeh, Jien-Wei; Chen, Swe-Kai
- Metallurgical and Materials Transactions A, Vol. 35, Issue 5
Effect of valence electron concentration on stability of fcc or bcc phase in high entropy alloys
journal, May 2011
- Guo, Sheng; Ng, Chun; Lu, Jian
- Journal of Applied Physics, Vol. 109, Issue 10
High-throughput methods using composition and structure spread libraries
journal, May 2016
- Kitchin, John R.; Gellman, Andrew J.
- AIChE Journal, Vol. 62, Issue 11
Crystallographic disorder and electron-phonon coupling in single crystals: Raman spectroscopy study
journal, September 2007
- Racu, A. -M.; Menzel, D.; Schoenes, J.
- Physical Review B, Vol. 76, Issue 11
Experimental and theoretical studies of the low-temperature growth of chromia and alumina
journal, September 1999
- Ashenford, D. E.; Long, F.; Hagston, W. E.
- Surface and Coatings Technology, Vol. 116-119
Epitaxial growth of CrO2 thin films by chemical-vapor deposition from a Cr8O21 precursor
journal, January 2001
- Ivanov, P. G.; Watts, S. M.; Lind, D. M.
- Journal of Applied Physics, Vol. 89, Issue 2
High-throughput synchrotron X-ray diffraction for combinatorial phase mapping
journal, October 2014
- Gregoire, J. M.; Van Campen, D. G.; Miller, C. E.
- Journal of Synchrotron Radiation, Vol. 21, Issue 6
Chromium Volatilization Rates from Cr2O3 Scales into Flowing Gases Containing Water Vapor
journal, November 2006
- Young, D. J.; Pint, B. A.
- Oxidation of Metals, Vol. 66, Issue 3-4
Microstructure and Mechanical Properties of New AlCo x CrFeMo 0.5 Ni High-Entropy Alloys
journal, February 2010
- Hsu, Chin-You; Wang, Woei-Ren; Tang, Wei-Yeh
- Advanced Engineering Materials, Vol. 12, Issue 1-2
Surface Phases of TiO 2 Nanoparticles Studied by UV Raman Spectroscopy and FT-IR Spectroscopy
journal, April 2008
- Su, Weiguang; Zhang, Jing; Feng, Zhaochi
- The Journal of Physical Chemistry C, Vol. 112, Issue 20
Effects of Mn, Ti and V on the microstructure and properties of AlCrFeCoNiCu high entropy alloy
journal, December 2008
- Li, B. S.; Wang, Y. P.; Ren, M. X.
- Materials Science and Engineering: A, Vol. 498, Issue 1-2
Excitation Frequency Dependence and Fluorescence in the Raman Spectra of Al 2 O 3
journal, June 1997
- Aminzadeh, A.
- Applied Spectroscopy, Vol. 51, Issue 6
Rapid Identification of Areas of Interest in Thin Film Materials Libraries by Combining Electrical, Optical, X-ray Diffraction, and Mechanical High-Throughput Measurements: A Case Study for the System Ni–Al
journal, November 2014
- Thienhaus, S.; Naujoks, D.; Pfetzing-Micklich, J.
- ACS Combinatorial Science, Vol. 16, Issue 12
Raman spectroscopy of ferromagnetic
journal, July 1999
- Iliev, M. N.; Litvinchuk, A. P.; Lee, H. -G.
- Physical Review B, Vol. 60, Issue 1
An XPS study of CrOx on a thin alumina film and in alumina supported catalysts
journal, November 2005
- Sainio, J.; Aronniemi, M.; Pakarinen, O.
- Applied Surface Science, Vol. 252, Issue 4
High-throughput characterization of early oxidation across AlxFeyNi1−x−y composition space
journal, February 2015
- Payne, Matthew A.; Miller, James B.; Gellman, Andrew J.
- Corrosion Science, Vol. 91
Nanostructured High-Entropy Alloys with Multiple Principal Elements: Novel Alloy Design Concepts and Outcomes
journal, May 2004
- Yeh, J.-W.; Chen, S.-K.; Lin, S.-J.
- Advanced Engineering Materials, Vol. 6, Issue 5, p. 299-303
Combinatorial approaches as effective tools in the study of phase diagrams and composition–structure–property relationships
journal, July 2006
- Zhao, J.
- Progress in Materials Science, Vol. 51, Issue 5
Raman spectra of amorphous Al2O3 and Al2O3/MoO3 obtained by visible and infrared excitation
journal, January 1991
- Mortensen, A.; Christensen, D. H.; Nielsen, O. Faurskov
- Journal of Raman Spectroscopy, Vol. 22, Issue 1
A critical review of high entropy alloys and related concepts
journal, January 2017
- Miracle, D. B.; Senkov, O. N.
- Acta Materialia, Vol. 122
High-Throughput Catalytic Science: Parallel Analysis of Transients in Catalytic Reactions
journal, March 2003
- Hendershot, Reed J.; Fanson, Paul T.; Snively, Christopher M.
- Angewandte Chemie International Edition, Vol. 42, Issue 10
On the elemental effect of AlCoCrCuFeNi high-entropy alloy system
journal, January 2007
- Tung, Chung-Chin; Yeh, Jien-Wei; Shun, Tao-tsung
- Materials Letters, Vol. 61, Issue 1
Thin film of aluminum oxide through pulsed laser deposition: a micro-Raman study
journal, January 2001
- Misra, A.; Bist, H. D.; Navati, M. S.
- Materials Science and Engineering: B, Vol. 79, Issue 1
The structure of surface rhenium oxide on alumina from laser raman spectroscopy and x-ray absorption near-edge spectroscopy
journal, July 1988
- Hardcastle, Franklin D.; Wachs, Israel E.; Horsley, John A.
- Journal of Molecular Catalysis, Vol. 46, Issue 1-3
Combinatorial and High-Throughput Screening of Materials Libraries: Review of State of the Art
journal, August 2011
- Potyrailo, Radislav; Rajan, Krishna; Stoewe, Klaus
- ACS Combinatorial Science, Vol. 13, Issue 6
Developing a Raman Spectrokinetic Approach To Gain Insights into the Structure–Reactivity Relationship of Supported Metal Oxide Catalysts
journal, August 2018
- Moncada, Jorge; Adams, William R.; Thakur, Raj
- ACS Catalysis, Vol. 8, Issue 10
Microstructures and compressive properties of multicomponent AlCoCrFeNiMox alloys
journal, October 2010
- Zhu, J. M.; Fu, H. M.; Zhang, H. F.
- Materials Science and Engineering: A, Vol. 527, Issue 26
The Different Roles of Entropy and Solubility in High Entropy Alloy Stability
journal, August 2016
- Ruiz-Yi, Benjamin; Bunn, Jonathan Kenneth; Stasak, Drew
- ACS Combinatorial Science, Vol. 18, Issue 9
On microstructure and mechanical performance of AlCoCrFeMo0.5Nix high-entropy alloys
journal, January 2013
- Juan, Chien-Chang; Hsu, Chin-You; Tsai, Che-Wei
- Intermetallics, Vol. 32
Chromium oxides thin films prepared and coated in situ with gold by pulsed laser deposition
journal, April 2005
- Stanoi, D.; Socol, G.; Grigorescu, C.
- Materials Science and Engineering: B, Vol. 118, Issue 1-3
Thermal Stability and Performance of NbSiTaTiZr High-Entropy Alloy Barrier for Copper Metallization
journal, January 2011
- Tsai, Ming-Hung; Wang, Chun-Wen; Tsai, Che-Wei
- Journal of The Electrochemical Society, Vol. 158, Issue 11
Oxidation behavior of arc melted AlCoCrFeNi multi-component high-entropy alloys
journal, July 2016
- Butler, Todd M.; Weaver, Mark L.
- Journal of Alloys and Compounds, Vol. 674
Assessment of a High-Throughput Methodology for the Study of Alloy Oxidation using Al x Fe y Ni 1– x – y Composition Gradient Thin Films
journal, June 2016
- Payne, Matthew A.; Miller, James B.; Oliveros, Martin E.
- ACS Combinatorial Science, Vol. 18, Issue 7
On-the-Fly Data Assessment for High-Throughput X-ray Diffraction Measurements
journal, May 2017
- Ren, Fang; Pandolfi, Ronald; Van Campen, Douglas
- ACS Combinatorial Science, Vol. 19, Issue 6
A high-throughput investigation of Fe–Cr–Al as a novel high-temperature coating for nuclear cladding materials
journal, June 2015
- Bunn, Jonathan Kenneth; Fang, Randy L.; Albing, Mark R.
- Nanotechnology, Vol. 26, Issue 27
Catalyst design: knowledge extraction from high-throughput experimentation
journal, May 2003
- Caruthers, J. M.; Lauterbach, J. A.; Thomson, K. T.
- Journal of Catalysis, Vol. 216, Issue 1-2
Effects of Temperature on the Raman Spectra and Dispersed Oxides
journal, June 2001
- Xie, Shuibo; Iglesia, Enrique; Bell, Alexis T.
- The Journal of Physical Chemistry B, Vol. 105, Issue 22