4D Printing of Stretchable Supercapacitors via Hybrid Composite Materials
Abstract
Stretchable supercapacitors (SCs) have attracted significant attention in developing power-independent stretchable electronic systems due to their intrinsic energy storage function and unique mechanical properties. Most current SCs are generally limited by their low stretchability, complicated fabrication process, and insufficient performance and robustness. This study presents a facile method to fabricate arbitrary-shaped stretchable electrodes via 4D printing of conductive composite from reduced graphene oxide, carbon nanotube, and poly(3,4-ethylenedioxythiophene) polystyrene sulfonate. The electrode patterns of an arbitrary shape can be deposited onto prestretched substrates by aerosol-jet printing, then self-organized origami (ridge) patterns are generated after releasing the substrates from holding stretchers due to the mismatched strains. The stretchable electrodes demonstrate superior mechanical robustness and stretchability without sacrificing its outstanding electrochemical performance. The symmetric SC prototype possesses a gravimetric capacitance of ≈21.7 F g-1 at a current density of 0.5 A g-1 and a capacitance retention of ≈85.8% from 0.5 to 5 A g-1. A SC array with arbitrary-shaped electrodes is also fabricated and connected in series to power light-emitting diode patterns for large-scale applications. Finally, the proposed method paves avenues for scalable manufacturing of future energy-storage devices with controlled extensibility and high electrochemical performance.
- Authors:
-
[3];
[2];
[4]
- Michigan State Univ., East Lansing, MI (United States); Duke Univ., Durham, NC (United States)
- Duke Univ., Durham, NC (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Michigan State Univ., East Lansing, MI (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE; National Science Foundation (NSF); USDA
- OSTI Identifier:
- 1756230
- Grant/Contract Number:
- AC05-00OR22725; ECCS-2024649; ECCS-1344745
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Materials Technologies
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 1; Journal ID: ISSN 2365-709X
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 4D printing; aerosol-jet printing; hybrid composites; self-organized origami; stretchable supercapacitors
Citation Formats
Zhou, Yihao, Parker, Charles B., Joshi, Pooran, Naskar, Amit K., Glass, Jeffrey T., and Cao, Changyong. 4D Printing of Stretchable Supercapacitors via Hybrid Composite Materials. United States: N. p., 2020.
Web. doi:10.1002/admt.202001055.
Zhou, Yihao, Parker, Charles B., Joshi, Pooran, Naskar, Amit K., Glass, Jeffrey T., & Cao, Changyong. 4D Printing of Stretchable Supercapacitors via Hybrid Composite Materials. United States. https://doi.org/10.1002/admt.202001055
Zhou, Yihao, Parker, Charles B., Joshi, Pooran, Naskar, Amit K., Glass, Jeffrey T., and Cao, Changyong. Sun .
"4D Printing of Stretchable Supercapacitors via Hybrid Composite Materials". United States. https://doi.org/10.1002/admt.202001055. https://www.osti.gov/servlets/purl/1756230.
@article{osti_1756230,
title = {4D Printing of Stretchable Supercapacitors via Hybrid Composite Materials},
author = {Zhou, Yihao and Parker, Charles B. and Joshi, Pooran and Naskar, Amit K. and Glass, Jeffrey T. and Cao, Changyong},
abstractNote = {Stretchable supercapacitors (SCs) have attracted significant attention in developing power-independent stretchable electronic systems due to their intrinsic energy storage function and unique mechanical properties. Most current SCs are generally limited by their low stretchability, complicated fabrication process, and insufficient performance and robustness. This study presents a facile method to fabricate arbitrary-shaped stretchable electrodes via 4D printing of conductive composite from reduced graphene oxide, carbon nanotube, and poly(3,4-ethylenedioxythiophene) polystyrene sulfonate. The electrode patterns of an arbitrary shape can be deposited onto prestretched substrates by aerosol-jet printing, then self-organized origami (ridge) patterns are generated after releasing the substrates from holding stretchers due to the mismatched strains. The stretchable electrodes demonstrate superior mechanical robustness and stretchability without sacrificing its outstanding electrochemical performance. The symmetric SC prototype possesses a gravimetric capacitance of ≈21.7 F g-1 at a current density of 0.5 A g-1 and a capacitance retention of ≈85.8% from 0.5 to 5 A g-1. A SC array with arbitrary-shaped electrodes is also fabricated and connected in series to power light-emitting diode patterns for large-scale applications. Finally, the proposed method paves avenues for scalable manufacturing of future energy-storage devices with controlled extensibility and high electrochemical performance.},
doi = {10.1002/admt.202001055},
journal = {Advanced Materials Technologies},
number = 1,
volume = 6,
place = {United States},
year = {Sun Dec 06 00:00:00 EST 2020},
month = {Sun Dec 06 00:00:00 EST 2020}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Stretchable and Foldable Silicon Integrated Circuits
journal, April 2008
- Kim, D.-H.; Ahn, J.-H.; Choi, W. M.
- Science, Vol. 320, Issue 5875, p. 507-511
Flexible, Stretchable, Transparent Carbon Nanotube Thin Film Loudspeakers
journal, December 2008
- Xiao, Lin; Chen, Zhuo; Feng, Chen
- Nano Letters, Vol. 8, Issue 12
Stretchable Graphene Transistors with Printed Dielectrics and Gate Electrodes
journal, November 2011
- Lee, Seoung-Ki; Kim, Beom Joon; Jang, Houk
- Nano Letters, Vol. 11, Issue 11
Highly sensitive flexible pressure sensors with microstructured rubber dielectric layers
journal, September 2010
- Mannsfeld, Stefan C. B.; Tee, Benjamin C-K.; Stoltenberg, Randall M.
- Nature Materials, Vol. 9, Issue 10, p. 859-864
Skin-like pressure and strain sensors based on transparent elastic films of carbon nanotubes
journal, October 2011
- Lipomi, Darren J.; Vosgueritchian, Michael; Tee, Benjamin C-K.
- Nature Nanotechnology, Vol. 6, Issue 12, p. 788-792
Tunable Nanowrinkles on Shape Memory Polymer Sheets
journal, November 2009
- Fu, Chi-Cheng; Grimes, Anthony; Long, Maureen
- Advanced Materials, Vol. 21, Issue 44, p. 4472-4476
Epidermal Electronics
journal, August 2011
- Kim, D.-H.; Lu, N.; Ma, R.
- Science, Vol. 333, Issue 6044, p. 838-843
Materials for stretchable electronics
journal, March 2012
- Wagner, Sigurd; Bauer, Siegfried
- MRS Bulletin, Vol. 37, Issue 3
Materials and Mechanics for Stretchable Electronics
journal, March 2010
- Rogers, J. A.; Someya, T.; Huang, Y.
- Science, Vol. 327, Issue 5973, p. 1603-1607
Ultrathin and lightweight organic solar cells with high flexibility
journal, January 2012
- Kaltenbrunner, Martin; White, Matthew S.; Głowacki, Eric D.
- Nature Communications, Vol. 3, Issue 1
A Stretchable Form of Single-Crystal Silicon for High-Performance Electronics on Rubber Substrates
journal, January 2006
- Khang, Dahl-Young; Jiang, Hanqing; Huang, Young
- Science, Vol. 311, Issue 5758, p. 208-212
Stretchable, Transparent, Ionic Conductors
journal, August 2013
- Keplinger, C.; Sun, J. -Y.; Foo, C. C.
- Science, Vol. 341, Issue 6149
Stretchable Organic Solar Cells
journal, February 2011
- Lipomi, Darren J.; Tee, Benjamin C. -K.; Vosgueritchian, Michael
- Advanced Materials, Vol. 23, Issue 15
Stretchable batteries with self-similar serpentine interconnects and integrated wireless recharging systems
journal, February 2013
- Xu, Sheng; Zhang, Yihui; Cho, Jiung
- Nature Communications, Vol. 4, Issue 1
Origami lithium-ion batteries
journal, January 2014
- Song, Zeming; Ma, Teng; Tang, Rui
- Nature Communications, Vol. 5, Issue 1
Dynamic and Galvanic Stability of Stretchable Supercapacitors
journal, February 2012
- Li, Xin; Gu, Taoli; Wei, Bingqing
- Nano Letters, Vol. 12, Issue 12
Stretchable, Porous, and Conductive Energy Textiles
journal, February 2010
- Hu, Liangbing; Pasta, Mauro; La Mantia, Fabio
- Nano Letters, Vol. 10, Issue 2, p. 708-714
A Highly Stretchable, Fiber-Shaped Supercapacitor
journal, November 2013
- Yang, Zhibin; Deng, Jue; Chen, Xuli
- Angewandte Chemie International Edition, Vol. 52, Issue 50
Flexible energy storage devices based on nanocomposite paper
journal, August 2007
- Pushparaj, Victor L.; Shaijumon, Manikoth M.; Kumar, Ashavani
- Proceedings of the National Academy of Sciences, Vol. 104, Issue 34, p. 13574-13577
Graphene-Based Supercapacitor with an Ultrahigh Energy Density
journal, December 2010
- Liu, Chenguang; Yu, Zhenning; Neff, David
- Nano Letters, Vol. 10, Issue 12
Carbon-Based Supercapacitors Produced by Activation of Graphene
journal, May 2011
- Zhu, Y.; Murali, S.; Stoller, M. D.
- Science, Vol. 332, Issue 6037, p. 1537-1541
Graphene Double-Layer Capacitor with ac Line-Filtering Performance
journal, September 2010
- Miller, J. R.; Outlaw, R. A.; Holloway, B. C.
- Science, Vol. 329, Issue 5999
An Intrinsically Stretchable and Compressible Supercapacitor Containing a Polyacrylamide Hydrogel Electrolyte
journal, June 2017
- Huang, Yan; Zhong, Ming; Shi, Fukuan
- Angewandte Chemie International Edition, Vol. 56, Issue 31
A self-healable and highly stretchable supercapacitor based on a dual crosslinked polyelectrolyte
journal, December 2015
- Huang, Yan; Zhong, Ming; Huang, Yang
- Nature Communications, Vol. 6, Issue 1
Ultrastretchable and superior healable supercapacitors based on a double cross-linked hydrogel electrolyte
journal, February 2019
- Li, Huili; Lv, Tian; Sun, Huanhuan
- Nature Communications, Vol. 10, Issue 1
Graphene supercapacitor electrodes fabricated by inkjet printing and thermal reduction of graphene oxide
journal, April 2011
- Le, Linh T.; Ervin, Matthew H.; Qiu, Hongwei
- Electrochemistry Communications, Vol. 13, Issue 4
Efficient Inkjet Printing of Graphene
journal, May 2013
- Li, Jiantong; Ye, Fei; Vaziri, Sam
- Advanced Materials, Vol. 25, Issue 29
Graphene-based conducting inks for direct inkjet printing of flexible conductive patterns and their applications in electric circuits and chemical sensors
journal, March 2011
- Huang, Lu; Huang, Yi; Liang, Jiajie
- Nano Research, Vol. 4, Issue 7
Inkjet-Printed Graphene Electronics
journal, March 2012
- Torrisi, Felice; Hasan, Tawfique; Wu, Weiping
- ACS Nano, Vol. 6, Issue 4
Inkjet Printing of Electrically Conductive Patterns of Carbon Nanotubes
journal, August 2006
- Kordás, Krisztián; Mustonen, Tero; Tóth, Géza
- Small, Vol. 2, Issue 8-9
Tunable lotus-leaf and rose-petal effects via graphene paper origami
journal, September 2015
- Cao, Changyong; Feng, Yaying; Zang, Jianfeng
- Extreme Mechanics Letters, Vol. 4
Stretchable and High-Performance Supercapacitors with Crumpled Graphene Papers
journal, October 2014
- Zang, Jianfeng; Cao, Changyong; Feng, Yaying
- Scientific Reports, Vol. 4, Issue 1
Micro-Supercapacitors Based on Interdigital Electrodes of Reduced Graphene Oxide and Carbon Nanotube Composites with Ultrahigh Power Handling Performance
journal, June 2012
- Beidaghi, Majid; Wang, Chunlei
- Advanced Functional Materials, Vol. 22, Issue 21
Highly Stretchable Supercapacitors via Crumpled Vertically Aligned Carbon Nanotube Forests
journal, April 2019
- Cao, Changyong; Zhou, Yihao; Ubnoske, Stephen
- Advanced Energy Materials, Vol. 9, Issue 22
Robust and High-Performance Electrodes via Crumpled Au-CNT Forests for Stretchable Supercapacitors
journal, May 2020
- Zhou, Yihao; Cao, Changyong; Cao, Yunteng
- Matter, Vol. 2, Issue 5
Recent Advances in Stretchable Supercapacitors Enabled by Low-Dimensional Nanomaterials
journal, November 2018
- Cao, Changyong; Chu, Yihang; Zhou, Yihao
- Small, Vol. 14, Issue 52
Preparation and characterization of graphene oxide paper
journal, July 2007
- Dikin, Dmitriy A.; Stankovich, Sasha; Zimney, Eric J.
- Nature, Vol. 448, Issue 7152, p. 457-460
Liquid-Mediated Dense Integration of Graphene Materials for Compact Capacitive Energy Storage
journal, August 2013
- Yang, X.; Cheng, C.; Wang, Y.
- Science, Vol. 341, Issue 6145
High Energy Density Supercapacitor Based on a Hybrid Carbon Nanotube-Reduced Graphite Oxide Architecture
journal, February 2012
- Jha, Neetu; Ramesh, Palanisamy; Bekyarova, Elena
- Advanced Energy Materials, Vol. 2, Issue 4
Multifunctionality and control of the crumpling and unfolding of large-area graphene
journal, January 2013
- Zang, Jianfeng; Ryu, Seunghwa; Pugno, Nicola
- Nature Materials, Vol. 12, Issue 4
Harnessing Localized Ridges for High-Aspect-Ratio Hierarchical Patterns with Dynamic Tunability and Multifunctionality
journal, December 2013
- Cao, Changyong; Chan, Hon Fai; Zang, Jianfeng
- Advanced Materials, Vol. 26, Issue 11
Self-assembled reduced graphene oxide/carbon nanotube thin films as electrodes for supercapacitors
journal, January 2012
- Huang, Zhen-Dong; Zhang, Biao; Oh, Sei-Woon
- Journal of Materials Chemistry, Vol. 22, Issue 8
Fully undoped and soluble oligo(3,4-ethylenedioxythiophene)s: spectroscopic study and electrochemical characterization
journal, January 2001
- Tran-Van, François; Garreau, Sébastien; Louarn, Guy
- Journal of Materials Chemistry, Vol. 11, Issue 5
Synthesis of graphene-based nanosheets via chemical reduction of exfoliated graphite oxide
journal, June 2007
- Stankovich, Sasha; Dikin, Dmitriy A.; Piner, Richard D.
- Carbon, Vol. 45, Issue 7, p. 1558-1565
Characterisation of carbonaceous materials using Raman spectroscopy: a comparison of carbon nanotube filters, single- and multi-walled nanotubes, graphitised porous carbon and graphite: Characterisation of carbonaceous materials using Raman spectroscopy
journal, December 2008
- Heise, H. M.; Kuckuk, R.; Ojha, A. K.
- Journal of Raman Spectroscopy, Vol. 40, Issue 3
High-efficiency ITO-free polymer solar cells using highly conductive PEDOT:PSS/surfactant bilayer transparent anodes
journal, January 2013
- Zhang, Wenfeng; Zhao, Baofeng; He, Zhicai
- Energy & Environmental Science, Vol. 6, Issue 6
Effect of different gel electrolytes on graphene-based solid-state supercapacitors
journal, January 2014
- Chen, Qiao; Li, Xinming; Zang, Xiaobei
- RSC Adv., Vol. 4, Issue 68
Printing of graphene supercapacitors with enhanced capacitances induced by a leavening agent
journal, April 2020
- Pham, Minh-Hao; Khazaeli, Ali; Godbille-Cardona, Gabrielle
- Journal of Energy Storage, Vol. 28
Highly concentrated graphene oxide ink for facile 3D printing of supercapacitors
journal, June 2019
- Ling, Shangwen; Kang, Wenbin; Tao, Shanwen
- Nano Materials Science, Vol. 1, Issue 2
Fully Packaged Carbon Nanotube Supercapacitors by Direct Ink Writing on Flexible Substrates
journal, August 2017
- Chen, Bolin; Jiang, Yizhou; Tang, Xiaohui
- ACS Applied Materials & Interfaces, Vol. 9, Issue 34
Inkjet printing of single-walled carbon nanotube/RuO2 nanowire supercapacitors on cloth fabrics and flexible substrates
journal, July 2010
- Chen, Pochiang; Chen, Haitian; Qiu, Jing
- Nano Research, Vol. 3, Issue 8
Screen-Printable Thin Film Supercapacitor Device Utilizing Graphene/Polyaniline Inks
journal, May 2013
- Xu, Yanfei; Schwab, Matthias Georg; Strudwick, Andrew James
- Advanced Energy Materials, Vol. 3, Issue 8
Direct Ink Writing of Wearable Thermoresponsive Supercapacitors with rGO/CNT Composite Electrodes
journal, October 2019
- Jiang, Yizhou; Cheng, Meng; Shahbazian‐Yassar, Reza
- Advanced Materials Technologies, Vol. 4, Issue 12
Laser‐Induced Graphene Composites for Printed, Stretchable, and Wearable Electronics
journal, May 2019
- Tehrani, Farshad; Beltrán‐Gastélum, Mara; Sheth, Karan
- Advanced Materials Technologies, Vol. 4, Issue 8