Controlling electrochemical growth of metallic zinc electrodes: Toward affordable rechargeable energy storage systems
Abstract
Scalable approaches for precisely manipulating the growth of crystals are of broad-based science and technological interest. New research interests have reemerged in a subgroup of these phenomena—electrochemical growth of metals in battery anodes. In this Review, the geometry of the building blocks and their mode of assembly are defined as key descriptors to categorize deposition morphologies. To control Zn electrodeposit morphology, we consider fundamental electrokinetic principles and the associated critical issues. It is found that the solid-electrolyte interphase (SEI) formed on Zn has a similarly strong influence as for alkali metals at low current regimes, characterized by a moss-like morphology. Another key conclusion is that the unique crystal structure of Zn, featuring high anisotropy facets resulting from the hexagonal close-packed lattice with a c/a ratio of 1.85, imposes predominant influences on its growth. In our view, precisely regulating the SEI and the crystallographic features of the Zn offers exciting opportunities that will drive transformative progress.
- Authors:
-
- Department of Materials Science and Engineering, Cornell University, Ithaca, NY 14853, USA.
- Department of Materials Science and Engineering, Cornell University, Ithaca, NY 14853, USA., Robert Frederick Smith School of Chemical and Biomolecular Engineering, Cornell University, Ithaca, NY 14853, USA.
- Publication Date:
- Research Org.:
- State Univ. of New York (SUNY), Stony Brook, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1755995
- Alternate Identifier(s):
- OSTI ID: 1816783
- Grant/Contract Number:
- SC0012673
- Resource Type:
- Published Article
- Journal Name:
- Science Advances
- Additional Journal Information:
- Journal Name: Science Advances Journal Volume: 7 Journal Issue: 2; Journal ID: ISSN 2375-2548
- Publisher:
- American Association for the Advancement of Science (AAAS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING
Citation Formats
Zheng, Jingxu, and Archer, Lynden A. Controlling electrochemical growth of metallic zinc electrodes: Toward affordable rechargeable energy storage systems. United States: N. p., 2021.
Web. doi:10.1126/sciadv.abe0219.
Zheng, Jingxu, & Archer, Lynden A. Controlling electrochemical growth of metallic zinc electrodes: Toward affordable rechargeable energy storage systems. United States. https://doi.org/10.1126/sciadv.abe0219
Zheng, Jingxu, and Archer, Lynden A. Fri .
"Controlling electrochemical growth of metallic zinc electrodes: Toward affordable rechargeable energy storage systems". United States. https://doi.org/10.1126/sciadv.abe0219.
@article{osti_1755995,
title = {Controlling electrochemical growth of metallic zinc electrodes: Toward affordable rechargeable energy storage systems},
author = {Zheng, Jingxu and Archer, Lynden A.},
abstractNote = {Scalable approaches for precisely manipulating the growth of crystals are of broad-based science and technological interest. New research interests have reemerged in a subgroup of these phenomena—electrochemical growth of metals in battery anodes. In this Review, the geometry of the building blocks and their mode of assembly are defined as key descriptors to categorize deposition morphologies. To control Zn electrodeposit morphology, we consider fundamental electrokinetic principles and the associated critical issues. It is found that the solid-electrolyte interphase (SEI) formed on Zn has a similarly strong influence as for alkali metals at low current regimes, characterized by a moss-like morphology. Another key conclusion is that the unique crystal structure of Zn, featuring high anisotropy facets resulting from the hexagonal close-packed lattice with a c/a ratio of 1.85, imposes predominant influences on its growth. In our view, precisely regulating the SEI and the crystallographic features of the Zn offers exciting opportunities that will drive transformative progress.},
doi = {10.1126/sciadv.abe0219},
journal = {Science Advances},
number = 2,
volume = 7,
place = {United States},
year = {Fri Jan 08 00:00:00 EST 2021},
month = {Fri Jan 08 00:00:00 EST 2021}
}
https://doi.org/10.1126/sciadv.abe0219
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