Influence of Potassium Metal‐Support Interactions on Dendrite Growth

Liu, Pengcheng; Yen, Dean; Vishnugopi, Bairav S.; Kankanallu, Varun R.; Gürsoy, Doğa; Ge, Mingyuan; Watt, John; Mukherjee, Partha P.; Chen‐Wiegart, Yu‐chen Karen; Mitlin, David

doi:10.1002/ange.202300943

Title: Influence of Potassium Metal‐Support Interactions on Dendrite Growth

Journal Article · 04 April 2023 · Angewandte Chemie

DOI: https://doi.org/10.1002/ange.202300943 · OSTI ID:1975296

Liu, Pengcheng ^[1]; Yen, Dean ^[2]; Vishnugopi, Bairav S. ^[3]; Kankanallu, Varun R. ^[2]; Gürsoy, Doğa ^[4]; Ge, Mingyuan ^[5]; Watt, John ^[6]; Mukherjee, Partha P. ^[3]; Chen‐Wiegart, Yu‐chen Karen ^[7];

^[1]

Materials Science and Engineering Program &, Texas Materials Institute (TMI) The University of Texas at Austin Austin TX 78712-1591 USA
Department of Materials Science and Chemical Engineering Stony Brook University Stony Brook NY 11794 USA
School of Mechanical Engineering Purdue University West Lafayette IN 47907 USA
Advanced Photon Source Argonne National Laboratory Lemont IL 60439 USA
National Synchrotron Light Source II (NSLS-II) Brookhaven National Laboratory Upton NY 11973-5000 USA
Center for Integrated Nanotechnologies Los Alamos National Laboratory Los Alamos NM 87545 USA
Department of Materials Science and Chemical Engineering Stony Brook University Stony Brook NY 11794 USA, National Synchrotron Light Source II (NSLS-II) Brookhaven National Laboratory Upton NY 11973-5000 USA

Abstract Combined synchrotron X‐ray nanotomography imaging, cryogenic electron microscopy (cryo‐EM) and modeling elucidate how potassium (K) metal‐support energetics influence electrodeposit microstructure. Three model supports are employed: O‐functionalized carbon cloth (potassiophilic, fully‐wetted), non‐functionalized cloth and Cu foil (potassiophobic, nonwetted). Nanotomography and focused ion beam (cryo‐FIB) cross‐sections yield complementary three‐dimensional (3D) maps of cycled electrodeposits. Electrodeposit on potassiophobic support is a triphasic sponge, with fibrous dendrites covered by solid electrolyte interphase (SEI) and interspersed with nanopores (sub‐10 nm to 100 nm scale). Lage cracks and voids are also a key feature. On potassiophilic support, the deposit is dense and pore‐free, with uniform surface and SEI morphology. Mesoscale modeling captures the critical role of substrate‐metal interaction on K metal film nucleation and growth, as well as the associated stress state.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0012704; SC0023260

OSTI ID:: 1975296

Journal Information:: Angewandte Chemie, Journal Name: Angewandte Chemie Journal Issue: 23 Vol. 135; ISSN 0044-8249

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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