Tunable magnetic order in low-symmetry SeO3 ligand linked TM3(SeO3)3H2O (TM=Mn , Co, and Ni) compounds
Abstract
The ability to design crystal lattices with specific sublattice geometries has long been sought after especially in the context of harnessing magnetic frustration to elicit emergent physics. One approach which has seen some success recently is to design magnetic sublattices chemically through the use of nonmagnetic linker ligands as scaffolding for the magnetic ions. In this work we report the magnetic properties of one such family of materials, the transition metal (TM) selenite hydrates with chemical formula TM3(SeO3)3H2O. These materials link highly distorted TMO6 octahedra via nonmagnetic [SeO3]2+ linkers. Studying members with TM = Mn, Co, and Ni we use magnetic susceptibility and neutron powder diffraction to identify antiferromagnetic order in all three compounds with moderate frustration indexes. A comparison of the magnetic structures suggests that while the overall structure of the SeO3 scaffolding remains unchanged the TM effects changes in the magnetic properties through tuning the internal bonding parameters and the single-ion physics. Changing from Mn to Co is found to be particularly consequential manifesting changes in both the ordered-moment direction and in the direction of the ordering vector. Field-dependent measurements of the susceptibility and heat capacity reveal metamagnetic transitions in both Mn3(SeO3)3H2O and Co3(SeO3)3H2O indicating nearby magnetic groundmore »
- Authors:
-
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1731072
- Alternate Identifier(s):
- OSTI ID: 1600066
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review Materials
- Additional Journal Information:
- Journal Volume: 4; Journal Issue: 2; Journal ID: ISSN 2475-9953
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; magnetism; metamagnetism; crystal structures; crystal growth; density functional theory; neutron diffraction
Citation Formats
Taddei, Keith, Sanjeewa, Liurukara D., Xing, Jie, Zhang, Qiang, Parker, David S., Podlesnyak, Andrey A., Dela Cruz, Clarina R., and Sefat, Athena Safa. Tunable magnetic order in low-symmetry SeO3 ligand linked TM3(SeO3)3H2O (TM=Mn , Co, and Ni) compounds. United States: N. p., 2020.
Web. doi:10.1103/physrevmaterials.4.024410.
Taddei, Keith, Sanjeewa, Liurukara D., Xing, Jie, Zhang, Qiang, Parker, David S., Podlesnyak, Andrey A., Dela Cruz, Clarina R., & Sefat, Athena Safa. Tunable magnetic order in low-symmetry SeO3 ligand linked TM3(SeO3)3H2O (TM=Mn , Co, and Ni) compounds. United States. https://doi.org/10.1103/physrevmaterials.4.024410
Taddei, Keith, Sanjeewa, Liurukara D., Xing, Jie, Zhang, Qiang, Parker, David S., Podlesnyak, Andrey A., Dela Cruz, Clarina R., and Sefat, Athena Safa. Tue .
"Tunable magnetic order in low-symmetry SeO3 ligand linked TM3(SeO3)3H2O (TM=Mn , Co, and Ni) compounds". United States. https://doi.org/10.1103/physrevmaterials.4.024410. https://www.osti.gov/servlets/purl/1731072.
@article{osti_1731072,
title = {Tunable magnetic order in low-symmetry SeO3 ligand linked TM3(SeO3)3H2O (TM=Mn , Co, and Ni) compounds},
author = {Taddei, Keith and Sanjeewa, Liurukara D. and Xing, Jie and Zhang, Qiang and Parker, David S. and Podlesnyak, Andrey A. and Dela Cruz, Clarina R. and Sefat, Athena Safa},
abstractNote = {The ability to design crystal lattices with specific sublattice geometries has long been sought after especially in the context of harnessing magnetic frustration to elicit emergent physics. One approach which has seen some success recently is to design magnetic sublattices chemically through the use of nonmagnetic linker ligands as scaffolding for the magnetic ions. In this work we report the magnetic properties of one such family of materials, the transition metal (TM) selenite hydrates with chemical formula TM3(SeO3)3H2O. These materials link highly distorted TMO6 octahedra via nonmagnetic [SeO3]2+ linkers. Studying members with TM = Mn, Co, and Ni we use magnetic susceptibility and neutron powder diffraction to identify antiferromagnetic order in all three compounds with moderate frustration indexes. A comparison of the magnetic structures suggests that while the overall structure of the SeO3 scaffolding remains unchanged the TM effects changes in the magnetic properties through tuning the internal bonding parameters and the single-ion physics. Changing from Mn to Co is found to be particularly consequential manifesting changes in both the ordered-moment direction and in the direction of the ordering vector. Field-dependent measurements of the susceptibility and heat capacity reveal metamagnetic transitions in both Mn3(SeO3)3H2O and Co3(SeO3)3H2O indicating nearby magnetic ground states accessible under relatively small applied fields. Density functional theory calculations broadly confirm these results, showing both a sensitivity of the magnetic structure to the TM and its local environment. Although no spin liquid behavior is achieved, these results suggest the fruitfulness of such synthesis philosophies and encourage future work to engender higher frustration in these materials via doping, field, pressure, or larger linker ligands.},
doi = {10.1103/physrevmaterials.4.024410},
journal = {Physical Review Materials},
number = 2,
volume = 4,
place = {United States},
year = {Tue Feb 18 00:00:00 EST 2020},
month = {Tue Feb 18 00:00:00 EST 2020}
}
Web of Science
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