Environmental influence on cracking and debonding of electrically conductive adhesives
Abstract
Electrically conductive adhesives (ECAs) are starting to replace metallic solders in recent designs of photovoltaic (PV) modules. This transition represents a significant material change, and a proper understanding of the durability and reliability of the new interconnect needs to be established. This paper presents our continued work on developing a degradation model for ECA interconnects in PV modules. Here, we characterize the fracture mechanics properties of an epoxy-based ECA, for both critical and subcritical, mode I and mode II loading conditions. Emphasis is on the influence of different environmental conditions such as temperature and humidity. We use the Finite Element Method to account for residual stresses, induced by temperature changes and moisture absorption, and correct the apparent fracture toughness. We found that high moisture levels not only can weaken the fracture resistance of the ECA interconnect, but can also promote subcritical debonding at significantly lower driving forces than in dry environments.
- Authors:
-
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Publication Date:
- Research Org.:
- National Renewable Energy Lab. (NREL), Golden, CO (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
- OSTI Identifier:
- 1726036
- Alternate Identifier(s):
- OSTI ID: 1809265
- Report Number(s):
- NREL/JA-5K00-78264
Journal ID: ISSN 0013-7944; MainId:32181;UUID:137e5713-f3af-4356-b312-3f4bc74a1b31;MainAdminID:18839
- Grant/Contract Number:
- AC36-08GO28308
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Engineering Fracture Mechanics
- Additional Journal Information:
- Journal Volume: 241; Journal ID: ISSN 0013-7944
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 42 ENGINEERING; electrically conductive adhesives; fracture properties; subcritical debonding; mode I; mode II; photovoltaics
Citation Formats
Springer, Martin, and Bosco, N. Environmental influence on cracking and debonding of electrically conductive adhesives. United States: N. p., 2020.
Web. doi:10.1016/j.engfracmech.2020.107398.
Springer, Martin, & Bosco, N. Environmental influence on cracking and debonding of electrically conductive adhesives. United States. https://doi.org/10.1016/j.engfracmech.2020.107398
Springer, Martin, and Bosco, N. Wed .
"Environmental influence on cracking and debonding of electrically conductive adhesives". United States. https://doi.org/10.1016/j.engfracmech.2020.107398. https://www.osti.gov/servlets/purl/1726036.
@article{osti_1726036,
title = {Environmental influence on cracking and debonding of electrically conductive adhesives},
author = {Springer, Martin and Bosco, N.},
abstractNote = {Electrically conductive adhesives (ECAs) are starting to replace metallic solders in recent designs of photovoltaic (PV) modules. This transition represents a significant material change, and a proper understanding of the durability and reliability of the new interconnect needs to be established. This paper presents our continued work on developing a degradation model for ECA interconnects in PV modules. Here, we characterize the fracture mechanics properties of an epoxy-based ECA, for both critical and subcritical, mode I and mode II loading conditions. Emphasis is on the influence of different environmental conditions such as temperature and humidity. We use the Finite Element Method to account for residual stresses, induced by temperature changes and moisture absorption, and correct the apparent fracture toughness. We found that high moisture levels not only can weaken the fracture resistance of the ECA interconnect, but can also promote subcritical debonding at significantly lower driving forces than in dry environments.},
doi = {10.1016/j.engfracmech.2020.107398},
journal = {Engineering Fracture Mechanics},
number = ,
volume = 241,
place = {United States},
year = {Wed Nov 11 00:00:00 EST 2020},
month = {Wed Nov 11 00:00:00 EST 2020}
}
Works referenced in this record:
Evaluation of the accuracy of the four-point bend end-notched flexure test for mode II delamination toughness determination
journal, August 2000
- Schuecker, Clara; Davidson, Barry D.
- Composites Science and Technology, Vol. 60, Issue 11
Subcritical debonding of FRP-to-concrete bonded interface under synergistic effect of load, moisture, and temperature
journal, January 2016
- Amidi, Shahrooz; Wang, Jialai
- Mechanics of Materials, Vol. 92
Adhesion and debonding of multi-layer thin film structures
journal, August 1998
- Dauskardt, R. H.; Lane, M.; Ma, Q.
- Engineering Fracture Mechanics, Vol. 61, Issue 1
Virtual crack closure technique: History, approach, and applications
journal, March 2004
- Krueger, Ronald
- Applied Mechanics Reviews, Vol. 57, Issue 2
Designing for time-dependent crack growth in adhesive joints
journal, July 1995
- Plausinis, D.; Spelt, J. K.
- International Journal of Adhesion and Adhesives, Vol. 15, Issue 3
Correction method for evaluation of interfacial fracture toughness of DCB, ENF and MMB specimens with residual thermal stresses
journal, March 2008
- Yokozeki, Tomohiro; Ogasawara, Toshio; Aoki, Takahira
- Composites Science and Technology, Vol. 68, Issue 3-4
Moisture-assisted subcritical debonding of a polymer/metal interface
journal, February 2002
- Kook, Seung-Yeop; Dauskardt, Reinhold H.
- Journal of Applied Physics, Vol. 91, Issue 3
Moisture assisted crack growth in ceramics
journal, June 1968
- Wiederhorn, S. M.
- International Journal of Fracture Mechanics, Vol. 4, Issue 2
Effects of Mode Ratio, Ply Orientation and Precracking on the Delamination Toughness of a Laminated Composite
journal, February 1996
- Polaha, J. J.; Davidson, B. D.; Hudson, R. C.
- Journal of Reinforced Plastics and Composites, Vol. 15, Issue 2
Defining Threshold Values of Encapsulant and Backsheet Adhesion for PV Module Reliability
journal, November 2017
- Bosco, Nick; Eafanti, Joshua; Kurtz, Sarah
- IEEE Journal of Photovoltaics, Vol. 7, Issue 6
Adhesion and debonding kinetics of photovoltaic encapsulation in moist environments: Adhesion and debonding kinetics of photovoltaic encapsulation
journal, July 2015
- Novoa, Fernando D.; Miller, David C.; Dauskardt, Reinhold H.
- Progress in Photovoltaics: Research and Applications, Vol. 24, Issue 2
Energy release rate analysis for adhesive and laminate double cantilever beam specimens emphasizing the effect of residual stresses
journal, February 2000
- Nairn, John A.
- International Journal of Adhesion and Adhesives, Vol. 20, Issue 1
Linear viscoelastic characterization of electrically conductive adhesives used as interconnect in photovoltaic modules
journal, March 2020
- Springer, Martin; Bosco, Nick
- Progress in Photovoltaics: Research and Applications, Vol. 28, Issue 7
Environment-Assisted Subcritical Debonding of Epoxy-Concrete Interface
journal, October 2012
- Zhang, Chao; Wang, Jialai; Fridley, Kenneth J.
- Journal of Composites for Construction, Vol. 16, Issue 5
Environmental Influence on Module Delamination Rate
journal, March 2019
- Bosco, Nick; Tracy, Jared; Dauskardt, Reinhold
- IEEE Journal of Photovoltaics, Vol. 9, Issue 2
Environmentally assisted debonding of copper/barrier interfaces
journal, March 2012
- Birringer, Ryan P.; Shaviv, Roey; Besser, Paul R.
- Acta Materialia, Vol. 60, Issue 5
A four-point bending technique for studying subcritical crack growth in thin films and at interfaces
journal, March 1997
- Ma, Qing
- Journal of Materials Research, Vol. 12, Issue 3
Climate specific thermomechanical fatigue of flat plate photovoltaic module solder joints
journal, July 2016
- Bosco, Nick; Silverman, Timothy J.; Kurtz, Sarah
- Microelectronics Reliability, Vol. 62
Mode II fracture toughness evaluation using four point bend, end notched flexure test
journal, August 1999
- Martin, R. H.; Davidson, B. D.
- Plastics, Rubber and Composites, Vol. 28, Issue 8