Design rules for liquid crystalline electrolytes for enabling dendrite-free lithium metal batteries
Abstract
Significance Lithium metal anodes offer a promising approach to improve the energy density of batteries to enable electrification of transportation. Dendrite suppression plagues the safety and cycle life of lithium metal anodes. In this work, we perform a comprehensive analysis of the use of liquid crystalline electrolytes in lithium metal anodes. We report theoretical demonstration of spontaneous stabilization of metal-electrode position using a liquid crystalline electrolyte due to the energy that arises when the molecules of the liquid crystal reorient. Building on this, we develop a comprehensive set of molecular-level design rules that will pave the way toward the realization of this new class of electrolytes for practical lithium metal batteries.
- Authors:
-
[1];
[1];
[2]
- Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, PA 15213,
- Department of Mechanical Engineering, Carnegie Mellon University, Pittsburgh, PA 15213,, Department of Physics, Carnegie Mellon University, Pittsburgh, PA 15213
- Publication Date:
- Sponsoring Org.:
- USDOE Advanced Research Projects Agency - Energy (ARPA-E)
- OSTI Identifier:
- 1671829
- Grant/Contract Number:
- AR0000774
- Resource Type:
- Published Article
- Journal Name:
- Proceedings of the National Academy of Sciences of the United States of America
- Additional Journal Information:
- Journal Name: Proceedings of the National Academy of Sciences of the United States of America Journal Volume: 117 Journal Issue: 43; Journal ID: ISSN 0027-8424
- Publisher:
- Proceedings of the National Academy of Sciences
- Country of Publication:
- United States
- Language:
- English
Citation Formats
Ahmad, Zeeshan, Hong, Zijian, and Viswanathan, Venkatasubramanian. Design rules for liquid crystalline electrolytes for enabling dendrite-free lithium metal batteries. United States: N. p., 2020.
Web. doi:10.1073/pnas.2008841117.
Ahmad, Zeeshan, Hong, Zijian, & Viswanathan, Venkatasubramanian. Design rules for liquid crystalline electrolytes for enabling dendrite-free lithium metal batteries. United States. https://doi.org/10.1073/pnas.2008841117
Ahmad, Zeeshan, Hong, Zijian, and Viswanathan, Venkatasubramanian. Fri .
"Design rules for liquid crystalline electrolytes for enabling dendrite-free lithium metal batteries". United States. https://doi.org/10.1073/pnas.2008841117.
@article{osti_1671829,
title = {Design rules for liquid crystalline electrolytes for enabling dendrite-free lithium metal batteries},
author = {Ahmad, Zeeshan and Hong, Zijian and Viswanathan, Venkatasubramanian},
abstractNote = {Significance Lithium metal anodes offer a promising approach to improve the energy density of batteries to enable electrification of transportation. Dendrite suppression plagues the safety and cycle life of lithium metal anodes. In this work, we perform a comprehensive analysis of the use of liquid crystalline electrolytes in lithium metal anodes. We report theoretical demonstration of spontaneous stabilization of metal-electrode position using a liquid crystalline electrolyte due to the energy that arises when the molecules of the liquid crystal reorient. Building on this, we develop a comprehensive set of molecular-level design rules that will pave the way toward the realization of this new class of electrolytes for practical lithium metal batteries.},
doi = {10.1073/pnas.2008841117},
journal = {Proceedings of the National Academy of Sciences of the United States of America},
number = 43,
volume = 117,
place = {United States},
year = {Fri Oct 09 00:00:00 EDT 2020},
month = {Fri Oct 09 00:00:00 EDT 2020}
}
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