Stress‐Induced Domain Wall Motion in a Ferroelastic Mn 3+ Spin Crossover Complex
Abstract
Domain wall motion is detected for the first time during the transition to a ferroelastic and spin state ordered phase of a spin crossover complex. Single-crystal X-ray diffraction and resonant ultrasound spectroscopy (RUS) revealed two distinct symmetry-breaking phase transitions in the mononuclear Mn3+ compound [Mn(3,5-diBr-sal2(323))]BPh4, 1. The first at 250 K, involves the space group change Cc→Pc and is thermodynamically continuous, while the second, Pc→P1 at 85 K, is discontinuous and related to spin crossover and spin state ordering. Furthermore, we found that stress-induced domain wall mobility was interpreted on the basis of a steep increase in acoustic loss immediately below the the Pc-P1 transition
- Authors:
-
[1];
[2];
[3];
[4];
[5];
[6];
[7];
[2];
[8];
[1]
- School of ChemistryUniversity College Dublin Belfield Dublin 4 Ireland
- Univ RennesCNRS, IPR (Institut de Physique de Rennes)—UMR 6251 35000 Rennes France
- School of ChemistryUniversity College Dublin Belfield Dublin 4 Ireland, Current address: Technische Universität Kaiserslautern Kaiserslautern Germany
- Department of PhysicsAuburn University Auburn AL 36849 USA, Current address: National High Magnetic Field Lab at Florida State University Tallahassee FL USA
- National High Magnetic Field LaboratoryLos Alamos National Laboratory Los Alamos NM 87545 USA, Current address: Idaho National Laboratory Idaho Falls ID USA
- Centre for Nanostructured MediaSchool of Mathematics and PhysicsQueen's University of Belfast Belfast BT7 1NN, Northern Ireland UK
- National High Magnetic Field LaboratoryLos Alamos National Laboratory Los Alamos NM 87545 USA
- Department of Earth SciencesUniversity of Cambridge Downing Street Cambridge CB2 3EQ UK
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE; USDOE Office of Science (SC). Basic Energy Sciences (BES); Science Foundation Ireland (SFI); Irish Research Council; National Science Foundation (NSF); Natural Environment Research Council; Engineering and Physical Sciences Research Council; Augustinus Fonden; Reinholdt W. Jorckog Hustrus Fond
- OSTI Identifier:
- 1632247
- Alternate Identifier(s):
- OSTI ID: 1632248; OSTI ID: 1669090
- Report Number(s):
- LA-UR-20-23341
Journal ID: ISSN 1433-7851
- Grant/Contract Number:
- DE SC0019330; 89233218CNA000001; 12/IP/1703; GOIPG/2016/73; 18-0338; 17-3813; 18-JI-0573; NE/B505738/1; NE/F17081/1; EP/I036079/1; DMR-115749; SC0019330
- Resource Type:
- Published Article
- Journal Name:
- Angewandte Chemie (International Edition)
- Additional Journal Information:
- Journal Name: Angewandte Chemie (International Edition) Journal Volume: 59 Journal Issue: 32; Journal ID: ISSN 1433-7851
- Publisher:
- Wiley
- Country of Publication:
- Germany
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; High magnetic field science; domain wall; ferroelastic materials; manganese(III); spin crossover; structural phase transition
Citation Formats
Jakobsen, Vibe B., Trzop, Elzbieta, Gavin, Laurence C., Dobbelaar, Emiel, Chikara, Shalinee, Ding, Xiaxin, Esien, Kane, Müller‐Bunz, Helge, Felton, Solveig, Zapf, Vivien S., Collet, Eric, Carpenter, Michael A., and Morgan, Grace G. Stress‐Induced Domain Wall Motion in a Ferroelastic Mn 3+ Spin Crossover Complex. Germany: N. p., 2020.
Web. doi:10.1002/anie.202003041.
Jakobsen, Vibe B., Trzop, Elzbieta, Gavin, Laurence C., Dobbelaar, Emiel, Chikara, Shalinee, Ding, Xiaxin, Esien, Kane, Müller‐Bunz, Helge, Felton, Solveig, Zapf, Vivien S., Collet, Eric, Carpenter, Michael A., & Morgan, Grace G. Stress‐Induced Domain Wall Motion in a Ferroelastic Mn 3+ Spin Crossover Complex. Germany. https://doi.org/10.1002/anie.202003041
Jakobsen, Vibe B., Trzop, Elzbieta, Gavin, Laurence C., Dobbelaar, Emiel, Chikara, Shalinee, Ding, Xiaxin, Esien, Kane, Müller‐Bunz, Helge, Felton, Solveig, Zapf, Vivien S., Collet, Eric, Carpenter, Michael A., and Morgan, Grace G. Mon .
"Stress‐Induced Domain Wall Motion in a Ferroelastic Mn 3+ Spin Crossover Complex". Germany. https://doi.org/10.1002/anie.202003041.
@article{osti_1632247,
title = {Stress‐Induced Domain Wall Motion in a Ferroelastic Mn 3+ Spin Crossover Complex},
author = {Jakobsen, Vibe B. and Trzop, Elzbieta and Gavin, Laurence C. and Dobbelaar, Emiel and Chikara, Shalinee and Ding, Xiaxin and Esien, Kane and Müller‐Bunz, Helge and Felton, Solveig and Zapf, Vivien S. and Collet, Eric and Carpenter, Michael A. and Morgan, Grace G.},
abstractNote = {Domain wall motion is detected for the first time during the transition to a ferroelastic and spin state ordered phase of a spin crossover complex. Single-crystal X-ray diffraction and resonant ultrasound spectroscopy (RUS) revealed two distinct symmetry-breaking phase transitions in the mononuclear Mn3+ compound [Mn(3,5-diBr-sal2(323))]BPh4, 1. The first at 250 K, involves the space group change Cc→Pc and is thermodynamically continuous, while the second, Pc→P1 at 85 K, is discontinuous and related to spin crossover and spin state ordering. Furthermore, we found that stress-induced domain wall mobility was interpreted on the basis of a steep increase in acoustic loss immediately below the the Pc-P1 transition},
doi = {10.1002/anie.202003041},
journal = {Angewandte Chemie (International Edition)},
number = 32,
volume = 59,
place = {Germany},
year = {Mon Jun 08 00:00:00 EDT 2020},
month = {Mon Jun 08 00:00:00 EDT 2020}
}
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Figures / Tables:
Figure 1: a) Plot of χMT versus T for complex 1 in cooling (blue curve) and heating (red curve) modes between 4 and 300 K measured at 0.1 T. Inset: 8 K wide hysteretic transition. b) Heat capacity, Cp, versus T of a single crystal of complex 1 measured bymore »
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