Why does B 2 O 3 suppress nepheline (NaAlSiO 4 ) crystallization in sodium aluminosilicate glasses?

Deshkar, Ambar; Gulbiten, Ozgur; Youngman, Randall E.; Mauro, John C.; Goel, Ashutosh

doi:10.1039/D0CP00172D

Title: Why does B ₂ O ₃ suppress nepheline (NaAlSiO ₄ ) crystallization in sodium aluminosilicate glasses?

Abstract

Addition of B ₂ O ₃ in aluminosilicate glasses leads to structural changes that cause increase in liquidus viscosity and thereby suppresses crystallization.

Authors:

^[1];

^[2];

^[2]; Mauro, John C. ^[3];

^[1]

Department of Materials Science and Engineering, Rutgers, The State University of New Jersey, Piscataway, USA
Science and Technology Division, Corning Incorporated, Corning, USA
Department of Materials Science and Engineering, The Pennsylvania State University, University Park, USA

Publication Date:: Wed Apr 29 00:00:00 EDT 2020

Sponsoring Org.:: USDOE

OSTI Identifier:: 1616488

Grant/Contract Number:: 89304018CEM000006; EM0003207

Resource Type:: Publisher's Accepted Manuscript

Journal Name:: Physical Chemistry Chemical Physics. PCCP

Additional Journal Information:: Journal Name: Physical Chemistry Chemical Physics. PCCP Journal Volume: 22 Journal Issue: 16; Journal ID: ISSN 1463-9076

Publisher:: Royal Society of Chemistry (RSC)

Country of Publication:: United Kingdom

Language:: English

Citation Formats


                    Deshkar, Ambar, Gulbiten, Ozgur, Youngman, Randall E., Mauro, John C., and Goel, Ashutosh. Why does B 2 O 3 suppress nepheline (NaAlSiO 4 ) crystallization in sodium aluminosilicate glasses?.  United Kingdom: N. p., 2020. 
Web.  doi:10.1039/D0CP00172D.

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                    Deshkar, Ambar, Gulbiten, Ozgur, Youngman, Randall E., Mauro, John C., & Goel, Ashutosh. Why does B 2 O 3 suppress nepheline (NaAlSiO 4 ) crystallization in sodium aluminosilicate glasses?.  United Kingdom.  https://doi.org/10.1039/D0CP00172D

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                    Deshkar, Ambar, Gulbiten, Ozgur, Youngman, Randall E., Mauro, John C., and Goel, Ashutosh. Wed .  
"Why does B 2 O 3 suppress nepheline (NaAlSiO 4 ) crystallization in sodium aluminosilicate glasses?".  United Kingdom.  https://doi.org/10.1039/D0CP00172D.

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@article{osti_1616488,

  title        = {Why does B 2 O 3 suppress nepheline (NaAlSiO 4 ) crystallization in sodium aluminosilicate glasses?},

  author       = {Deshkar, Ambar and Gulbiten, Ozgur and Youngman, Randall E. and Mauro, John C. and Goel, Ashutosh},

  abstractNote = {Addition of B 2 O 3 in aluminosilicate glasses leads to structural changes that cause increase in liquidus viscosity and thereby suppresses crystallization.},

  doi          = {10.1039/D0CP00172D},

  journal      = {Physical Chemistry Chemical Physics. PCCP},

  number       = 16,

  volume       = 22,

  place        = {United Kingdom},

  year         = {Wed Apr 29 00:00:00 EDT 2020},

  month        = {Wed Apr 29 00:00:00 EDT 2020}

}

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The effects of compositional variations on properties of a multi-component glass system Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-CaO-K{sub 2}O-Na{sub 2}O-SiO{sub 2}

Conference Yan, Q ; Perez-Cardenas, F C ; Guo, W ; ...

The authors have examined the six component system of Al{sub 2}O{sub 3}-B{sub 2}O{sub 3}-CaO-K{sub 2}O-Na{sub 2}O-SiO{sub 2} by investigating the effects of Na{sub 2}O substitution for CaO, CaO substitution for SiO{sub 2}, and Al{sub 2}O{sub 3} substitution for B{sub 2}O{sub 3} on melt viscosity, melt conductivity, and liquidus temperature. These compositional studies show that for the Na-Ca exchange, the melt conductivity increases by a factor of 140 while the melt viscosity decreases by less than a factor of 1.6; for the Ca-Si exchange, the melt viscosity decreases by a factor of 20 while the melt conductivity increases by less thanmore »« less

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Title: Why does B 2 O 3 suppress nepheline (NaAlSiO 4 ) crystallization in sodium aluminosilicate glasses?

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Nepheline crystallization in boron-rich alumino-silicate glasses as investigated by multi-nuclear NMR, Raman, & Mössbauer spectroscopies journal, February 2015

Network polymerization and cation coordination environments in boron-bearing rhyolitic melts: Insights from 17O, 11B, and 27Al solid-state NMR of sodium aluminoborosilicate glasses with varying boron content journal, January 2020

The role of Al3+ on rheology and structural changes in sodium silicate and aluminosilicate glasses and melts journal, February 2014

Na K-edge XANES spectra of minerals and glasses [Na K-edge XANES spectra of minerals and glasses] journal, October 2004

Viscosity and liquidus‐based predictor of glass‐forming ability of oxide glasses journal, September 2019

Quantitative Design of Glassy Materials Using Temperature-Dependent Constraint Theory journal, September 2010

Cristobalite-Related Phases in the NaAlO2–NaAlSiO4 System. II. A Commensurately Modulated Cubic Structure journal, October 1998

Modelling one- and two-dimensional solid-state NMR spectra: Modelling 1D and 2D solid-state NMR spectra journal, December 2001

Energy barriers to viscous flow and the prediction of glass transition temperatures of molten silicates journal, June 1998

Crystal growth kinetics exhibit a fragility-dependent decoupling from viscosity journal, January 2008

Magic angle spinning NMR observation of sodium site exchange in nepheline at 500° C journal, November 1989

Composition dependence of glass transition temperature and fragility. I. A topological model incorporating temperature-dependent constraints journal, March 2009

A Raman spectroscopic study of glasses along the joins silica-calcium aluminate, silica-sodium aluminate, and silica-potassium aluminate journal, November 1982

Topological Disorder and Reactivity of Borosilicate Glasses: Quantum Chemical Calculations and 17 O and 11 B NMR Study journal, December 2001

ZFiltering in MQMAS NMR journal, November 1996

Submixture model to predict nepheline precipitation in waste glasses journal, May 2016

Nepheline structural and chemical dependence on melt composition journal, February 2016

The effect of Na/Si on the structure of sodium silicate and aluminosilicate glasses quenched from melts at high pressure: A multi-nuclear (Al-27, Na-23, O-17) 1D and 2D solid-state NMR study journal, May 2006

Elucidating the Effect of Iron Speciation (Fe 2+ /Fe 3+ ) on Crystallization Kinetics of Sodium Aluminosilicate Glasses journal, April 2016

Crystal data for the low-temperature form of carnegieite NaAlSiO 4 journal, February 1981

Control of Nepheline Crystallization in Nuclear Waste Glass journal, November 2008

The influence of Si,B substitution and of the nature of network-modifying cations on the properties and structure of borosilicate glasses and melts journal, November 2008

Raman spectral studies of borate glasses journal, June 1993

Thermodynamic assessment of the Na2O-Al2O3-SiO2-B2O3 pseudo-binary and -ternary systems journal, January 2019

Advances in understanding the structure of borosilicate glasses: A Raman spectroscopy study journal, May 2009

Nepheline Crystallization in Nuclear Waste Glasses: Progress Toward Acceptance of High-Alumina Formulations journal, August 2011

23Na NMR chemical shifts and local Na coordination environments in silicate crystals, melts and glasses journal, October 1993

Crystallization in glass-forming liquids: Effects of fragility and glass transition temperature journal, November 2015

Structural and Chemical Approach toward Understanding the Aqueous Corrosion of Sodium Aluminoborate Glasses journal, November 2018

23Na NMR Spectroscopy of Solids: Interpretation of Quadrupole Interaction Parameters and Chemical Shifts journal, February 1994

Boron-speciation and aluminosilicate crystallization in alkali boroaluminosilicate glasses along the NaAl1-xBxSiO4 and LiAl1-xBxSiO4 joins journal, February 2019

Viscosity of a standard soda-lime-silica glass journal, September 1964

Effects of cation field strength on the structure of aluminoborosilicate glasses: High-resolution 11B, 27Al and 23Na MAS NMR journal, April 2009

Structure of borosilicate glasses and melts: A revision of the Yun, Bray and Dell model journal, December 2009

On the Temperature Dependence of Cooperative Relaxation Properties in Glass‐Forming Liquids journal, July 1965

Viscosity, structure and mixing in (Ca, Na) silicate melts journal, May 2006

Structure and mechanical properties of compressed sodium aluminosilicate glasses: Role of non-bridging oxygens journal, June 2016

Relaxation in glassforming liquids and amorphous solids journal, September 2000

Bond-valence parameters obtained from a systematic analysis of the Inorganic Crystal Structure Database journal, August 1985

Structural dependence of crystallization in glasses along the nepheline (NaAlSiO 4 ) ‐ eucryptite (LiAlSiO 4 ) join journal, February 2018

Boron Coordination in Rapidly Cooled and in Annealed Aluminum Borosilicate Glass Fibers journal, March 1985

The binary system; na 2 Al 2 Si 2 O 8 (nephelite, carnegieite); CaAl 2 Si 2 O 8 (anorthite) journal, June 1912

Temperature effects on non-bridging oxygen and aluminum coordination number in calcium aluminosilicate glasses and melts journal, February 2008

Raman spectroscopic study of structural changes induced by micro-indentation in low alkali borosilicate glasses journal, October 2014

An insight into the corrosion of alkali aluminoborosilicate glasses in acidic environments journal, January 2020

Planar rings in glasses journal, November 1982

Crystal nucleation and growth in glass-forming melts: Experiment and theory journal, January 2008

Al and Sr environment in tectosilicate glasses and melts: Viscosity, Raman and NMR investigation journal, June 2017

Preparation of nepheline glass–ceramics for dental applications journal, December 2008

Microstructure and modification in borate and tellurite glasses journal, December 1995

Composition–structure–property relationships in boroaluminosilicate glasses journal, April 2012

Raman investigation of ring configurations in vitreous silica journal, July 1981

Exafs and xanes study of the local coordination environment of sodium in a series of silica-rich glasses and selected minerals within the Na2OAl2O3SiO2 system journal, November 1985

High temperature viscosity of calcium-magnesium-aluminosilicate glass from synthetic sand journal, November 2016

Effects of Al2O3, B2O3, Na2O, and SiO2 on nepheline formation in borosilicate glasses: chemical and physical correlations journal, December 2003

Percolation channels: a universal idea to describe the atomic structure and dynamics of glasses and melts journal, November 2017

Quantitative links between microscopic properties and viscosity of liquids in the system SiO2–Na2O journal, April 2001

Structural Characterisation of Kaolinite:NaCl Intercalate and its Derivatives journal, January 1992

Preparation of nepheline glass-ceramics and their application as dental porcelain journal, May 1994

Dynamics of Na in sodium aluminosilicate glasses and liquids journal, December 1996

Viscosity, fragility, and configurational entropy of melts along the join SiO 2 -NaAlSiO 4 journal, October 1997

Crystallization in glass-forming liquids: Effects of decoupling of diffusion and viscosity on crystal growth journal, December 2015

A review of the structures of oxide glasses by Raman spectroscopy journal, January 2015

Viscous flow of medieval cathedral glass journal, August 2017

Understanding the structural drivers governing glass–water interactions in borosilicate based model bioactive glasses journal, January 2018

The distribution of sodium ions in aluminosilicate glasses: a high-field Na-23 MAS and 3Q MAS NMR study journal, May 2003

Composition-structure-property relationships in Li2O–Al2O3–B2O3 glasses journal, December 2018

Viscosity of glass-forming liquids journal, November 2009

Does viscosity describe the kinetic barrier for crystal growth from the liquidus to the glass transition? journal, November 2010

NMR Study of a Rare-Earth Aluminoborosilicate Glass with Varying CaO-to-Na2O Ratio journal, December 2007

Understanding the structural origin of crystalline phase transformations in nepheline (NaAlSiO 4 )‐based glass‐ceramics journal, April 2017

Experimental determination of the effect of the ratio of B/Al on glass dissolution along the nepheline (NaAlSiO4)–malinkoite (NaBSiO4) join journal, May 2010

Title: Why does B ₂ O ₃ suppress nepheline (NaAlSiO ₄ ) crystallization in sodium aluminosilicate glasses?

Nepheline crystallization in boron-rich alumino-silicate glasses as investigated by multi-nuclear NMR, Raman, & Mössbauer spectroscopies
journal, February 2015

Network polymerization and cation coordination environments in boron-bearing rhyolitic melts: Insights from 17O, 11B, and 27Al solid-state NMR of sodium aluminoborosilicate glasses with varying boron content
journal, January 2020

The role of Al3+ on rheology and structural changes in sodium silicate and aluminosilicate glasses and melts
journal, February 2014

Na K-edge XANES spectra of minerals and glasses [Na K-edge XANES spectra of minerals and glasses]
journal, October 2004

Viscosity and liquidus‐based predictor of glass‐forming ability of oxide glasses
journal, September 2019

Quantitative Design of Glassy Materials Using Temperature-Dependent Constraint Theory
journal, September 2010

Cristobalite-Related Phases in the NaAlO2–NaAlSiO4 System. II. A Commensurately Modulated Cubic Structure
journal, October 1998

Modelling one- and two-dimensional solid-state NMR spectra: Modelling 1D and 2D solid-state NMR spectra
journal, December 2001

Energy barriers to viscous flow and the prediction of glass transition temperatures of molten silicates
journal, June 1998

Crystal growth kinetics exhibit a fragility-dependent decoupling from viscosity
journal, January 2008

Magic angle spinning NMR observation of sodium site exchange in nepheline at 500° C
journal, November 1989

Composition dependence of glass transition temperature and fragility. I. A topological model incorporating temperature-dependent constraints
journal, March 2009

A Raman spectroscopic study of glasses along the joins silica-calcium aluminate, silica-sodium aluminate, and silica-potassium aluminate
journal, November 1982

Topological Disorder and Reactivity of Borosilicate Glasses: Quantum Chemical Calculations and ¹⁷ O and ¹¹ B NMR Study
journal, December 2001

ZFiltering in MQMAS NMR
journal, November 1996

Submixture model to predict nepheline precipitation in waste glasses
journal, May 2016

Nepheline structural and chemical dependence on melt composition
journal, February 2016

The effect of Na/Si on the structure of sodium silicate and aluminosilicate glasses quenched from melts at high pressure: A multi-nuclear (Al-27, Na-23, O-17) 1D and 2D solid-state NMR study
journal, May 2006

Elucidating the Effect of Iron Speciation (Fe ²⁺ /Fe ³⁺ ) on Crystallization Kinetics of Sodium Aluminosilicate Glasses
journal, April 2016

Crystal data for the low-temperature form of carnegieite NaAlSiO ₄
journal, February 1981

Control of Nepheline Crystallization in Nuclear Waste Glass
journal, November 2008

The influence of Si,B substitution and of the nature of network-modifying cations on the properties and structure of borosilicate glasses and melts
journal, November 2008

Raman spectral studies of borate glasses
journal, June 1993

Thermodynamic assessment of the Na2O-Al2O3-SiO2-B2O3 pseudo-binary and -ternary systems
journal, January 2019

Advances in understanding the structure of borosilicate glasses: A Raman spectroscopy study
journal, May 2009

Nepheline Crystallization in Nuclear Waste Glasses: Progress Toward Acceptance of High-Alumina Formulations
journal, August 2011

23Na NMR chemical shifts and local Na coordination environments in silicate crystals, melts and glasses
journal, October 1993

Crystallization in glass-forming liquids: Effects of fragility and glass transition temperature
journal, November 2015

Structural and Chemical Approach toward Understanding the Aqueous Corrosion of Sodium Aluminoborate Glasses
journal, November 2018

23Na NMR Spectroscopy of Solids: Interpretation of Quadrupole Interaction Parameters and Chemical Shifts
journal, February 1994

Boron-speciation and aluminosilicate crystallization in alkali boroaluminosilicate glasses along the NaAl1-xBxSiO4 and LiAl1-xBxSiO4 joins
journal, February 2019

Viscosity of a standard soda-lime-silica glass
journal, September 1964

Effects of cation field strength on the structure of aluminoborosilicate glasses: High-resolution 11B, 27Al and 23Na MAS NMR
journal, April 2009

Structure of borosilicate glasses and melts: A revision of the Yun, Bray and Dell model
journal, December 2009

On the Temperature Dependence of Cooperative Relaxation Properties in Glass‐Forming Liquids
journal, July 1965

Viscosity, structure and mixing in (Ca, Na) silicate melts
journal, May 2006

Structure and mechanical properties of compressed sodium aluminosilicate glasses: Role of non-bridging oxygens
journal, June 2016

Relaxation in glassforming liquids and amorphous solids
journal, September 2000

Bond-valence parameters obtained from a systematic analysis of the Inorganic Crystal Structure Database
journal, August 1985

Structural dependence of crystallization in glasses along the nepheline (NaAlSiO ₄ ) ‐ eucryptite (LiAlSiO ₄ ) join
journal, February 2018

Boron Coordination in Rapidly Cooled and in Annealed Aluminum Borosilicate Glass Fibers
journal, March 1985

The binary system; na 2 Al 2 Si 2 O 8 (nephelite, carnegieite); CaAl 2 Si 2 O 8 (anorthite)
journal, June 1912

Temperature effects on non-bridging oxygen and aluminum coordination number in calcium aluminosilicate glasses and melts
journal, February 2008

Raman spectroscopic study of structural changes induced by micro-indentation in low alkali borosilicate glasses
journal, October 2014

An insight into the corrosion of alkali aluminoborosilicate glasses in acidic environments
journal, January 2020

Planar rings in glasses
journal, November 1982

Crystal nucleation and growth in glass-forming melts: Experiment and theory
journal, January 2008

Al and Sr environment in tectosilicate glasses and melts: Viscosity, Raman and NMR investigation
journal, June 2017

Preparation of nepheline glass–ceramics for dental applications
journal, December 2008

Microstructure and modification in borate and tellurite glasses
journal, December 1995

Composition–structure–property relationships in boroaluminosilicate glasses
journal, April 2012

Raman investigation of ring configurations in vitreous silica
journal, July 1981

Exafs and xanes study of the local coordination environment of sodium in a series of silica-rich glasses and selected minerals within the Na2OAl2O3SiO2 system
journal, November 1985

High temperature viscosity of calcium-magnesium-aluminosilicate glass from synthetic sand
journal, November 2016

Effects of Al2O3, B2O3, Na2O, and SiO2 on nepheline formation in borosilicate glasses: chemical and physical correlations
journal, December 2003

Percolation channels: a universal idea to describe the atomic structure and dynamics of glasses and melts
journal, November 2017

Quantitative links between microscopic properties and viscosity of liquids in the system SiO2–Na2O
journal, April 2001

Structural Characterisation of Kaolinite:NaCl Intercalate and its Derivatives
journal, January 1992

Preparation of nepheline glass-ceramics and their application as dental porcelain
journal, May 1994

Dynamics of Na in sodium aluminosilicate glasses and liquids
journal, December 1996

Viscosity, fragility, and configurational entropy of melts along the join SiO ₂ -NaAlSiO ₄
journal, October 1997

Crystallization in glass-forming liquids: Effects of decoupling of diffusion and viscosity on crystal growth
journal, December 2015

A review of the structures of oxide glasses by Raman spectroscopy
journal, January 2015

Viscous flow of medieval cathedral glass
journal, August 2017

Understanding the structural drivers governing glass–water interactions in borosilicate based model bioactive glasses
journal, January 2018

The distribution of sodium ions in aluminosilicate glasses: a high-field Na-23 MAS and 3Q MAS NMR study
journal, May 2003

Composition-structure-property relationships in Li2O–Al2O3–B2O3 glasses
journal, December 2018

Viscosity of glass-forming liquids
journal, November 2009

Does viscosity describe the kinetic barrier for crystal growth from the liquidus to the glass transition?
journal, November 2010

NMR Study of a Rare-Earth Aluminoborosilicate Glass with Varying CaO-to-Na2O Ratio
journal, December 2007

Understanding the structural origin of crystalline phase transformations in nepheline (NaAlSiO ₄ )‐based glass‐ceramics
journal, April 2017

Experimental determination of the effect of the ratio of B/Al on glass dissolution along the nepheline (NaAlSiO4)–malinkoite (NaBSiO4) join
journal, May 2010