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Title: Structural dependence of crystallization in glasses along the nepheline (NaAlSiO 4 ) ‐ eucryptite (LiAlSiO 4 ) join

Authors:
ORCiD logo [1];  [2];  [1];  [3];  [4]; ORCiD logo [4]; ORCiD logo [5]
  1. Materials Science and Engineering Program Washington State University Pullman Washington
  2. School of Mechanical &, Materials Engineering Washington State University Pullman Washington
  3. Pacific Northwest National Laboratory Richland Washington
  4. Department of Materials Science and Engineering Rutgers‐The State University of New Jersey Piscataway New Jersey
  5. Materials Science and Engineering Program Washington State University Pullman Washington, School of Mechanical &, Materials Engineering Washington State University Pullman Washington, Pacific Northwest National Laboratory Richland Washington
Publication Date:
Sponsoring Org.:
USDOE
OSTI Identifier:
1419091
Grant/Contract Number:  
DE‐EM0002904; DE‐EM0003207; DE‐AC05‐76RL01830
Resource Type:
Publisher's Accepted Manuscript
Journal Name:
Journal of the American Ceramic Society
Additional Journal Information:
Journal Name: Journal of the American Ceramic Society Journal Volume: 101 Journal Issue: 7; Journal ID: ISSN 0002-7820
Publisher:
Wiley-Blackwell
Country of Publication:
United States
Language:
English

Citation Formats

Marcial, José, Kabel, Joey, Saleh, Muad, Washton, Nancy, Shaharyar, Yaqoot, Goel, Ashutosh, and McCloy, John S. Structural dependence of crystallization in glasses along the nepheline (NaAlSiO 4 ) ‐ eucryptite (LiAlSiO 4 ) join. United States: N. p., 2018. Web. doi:10.1111/jace.15439.
Marcial, José, Kabel, Joey, Saleh, Muad, Washton, Nancy, Shaharyar, Yaqoot, Goel, Ashutosh, & McCloy, John S. Structural dependence of crystallization in glasses along the nepheline (NaAlSiO 4 ) ‐ eucryptite (LiAlSiO 4 ) join. United States. doi:10.1111/jace.15439.
Marcial, José, Kabel, Joey, Saleh, Muad, Washton, Nancy, Shaharyar, Yaqoot, Goel, Ashutosh, and McCloy, John S. Thu . "Structural dependence of crystallization in glasses along the nepheline (NaAlSiO 4 ) ‐ eucryptite (LiAlSiO 4 ) join". United States. doi:10.1111/jace.15439.
@article{osti_1419091,
title = {Structural dependence of crystallization in glasses along the nepheline (NaAlSiO 4 ) ‐ eucryptite (LiAlSiO 4 ) join},
author = {Marcial, José and Kabel, Joey and Saleh, Muad and Washton, Nancy and Shaharyar, Yaqoot and Goel, Ashutosh and McCloy, John S.},
abstractNote = {},
doi = {10.1111/jace.15439},
journal = {Journal of the American Ceramic Society},
number = 7,
volume = 101,
place = {United States},
year = {2018},
month = {2}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
DOI: 10.1111/jace.15439

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Cited by: 2 works
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Works referenced in this record:

Nepheline crystallization in boron-rich alumino-silicate glasses as investigated by multi-nuclear NMR, Raman, & Mössbauer spectroscopies
journal, February 2015


Solid-state nuclear magnetic resonance investigation of cation siting in LiNaLSX zeolites
journal, December 1998


Phase Equilibria in the System Lithium Metasilicate-beta-Eucryptite
journal, January 1954


High-resolution 23Na, 27Al and 29Si NMR spectroscopy of framework Aluminosilicate glasses
journal, August 1987

  • Oestrike, Richard; Yang, Wang-hong; Kirkpatrick, R. James
  • Geochimica et Cosmochimica Acta, Vol. 51, Issue 8
  • DOI: 10.1016/0016-7037(87)90269-9

Glass-Ceramics by Photosensitive Processes
journal, August 2015

  • Borrelli, Nicholas F.
  • International Journal of Applied Glass Science, Vol. 6, Issue 3
  • DOI: 10.1111/ijag.12130

Cristobalite-Related Phases in the NaAlO2–NaAlSiO4 System. II. A Commensurately Modulated Cubic Structure
journal, October 1998

  • Withers, R. L.; Thompson, J. G.; Melnitchenko, A.
  • Acta Crystallographica Section B Structural Science, Vol. 54, Issue 5
  • DOI: 10.1107/S0108768197019939

Characterisation of sodium cations in dehydrated zeolite NaX by 23Na NMR spectroscopy
journal, November 1996


Magic angle spinning NMR observation of sodium site exchange in nepheline at 500° C
journal, November 1989

  • Stebbins, Jonathan F.; Farnan, Ian; Williams, Evan H.
  • Physics and Chemistry of Minerals, Vol. 16, Issue 8
  • DOI: 10.1007/BF00209699

Radiation effects and tolerance mechanism in β-eucryptite
journal, January 2013

  • Narayanan, Badri; Reimanis, Ivar E.; Huang, Hanchen
  • Journal of Applied Physics, Vol. 113, Issue 3
  • DOI: 10.1063/1.4775838

Submixture model to predict nepheline precipitation in waste glasses
journal, May 2016

  • Vienna, John D.; Kroll, Jared O.; Hrma, Pavel R.
  • International Journal of Applied Glass Science, Vol. 8, Issue 2
  • DOI: 10.1111/ijag.12207

Nepheline structural and chemical dependence on melt composition
journal, February 2016

  • Marcial, José; Crum, Jarrod; Neill, Owen
  • American Mineralogist, Vol. 101, Issue 2
  • DOI: 10.2138/am-2016-5370

Insight into sodium silicate glass structural organization by multinuclear NMR combined with first-principles calculations
journal, May 2011

  • Angeli, Frédéric; Villain, Olivier; Schuller, Sophie
  • Geochimica et Cosmochimica Acta, Vol. 75, Issue 9
  • DOI: 10.1016/j.gca.2011.02.003

Lithium conductivity in glasses of the Li 2 O–Al 2 O 3 –SiO 2 system
journal, January 2015

  • Ross, Sebastian; Welsch, Anna-Maria; Behrens, Harald
  • Physical Chemistry Chemical Physics, Vol. 17, Issue 1
  • DOI: 10.1039/C4CP03609C

Site Preferences in the Mixed Cation Zeolite, Li,Na-Chabazite:  A Combined Solid-State NMR and Neutron Diffraction Study
journal, March 2000

  • Smith, Luis J.; Eckert, Hellmut; Cheetham, Anthony K.
  • Journal of the American Chemical Society, Vol. 122, Issue 8
  • DOI: 10.1021/ja992882b

Elucidating the Effect of Iron Speciation (Fe 2+ /Fe 3+ ) on Crystallization Kinetics of Sodium Aluminosilicate Glasses
journal, April 2016

  • Shaharyar, Yaqoot; Cheng, Justin Y.; Han, Edmund
  • Journal of the American Ceramic Society, Vol. 99, Issue 7
  • DOI: 10.1111/jace.14239

Control of Nepheline Crystallization in Nuclear Waste Glass
journal, November 2008

  • Fox, Kevin M.; Edwards, Thomas B.; Peeler, David K.
  • International Journal of Applied Ceramic Technology, Vol. 5, Issue 6
  • DOI: 10.1111/j.1744-7402.2008.02250.x

The mixed alkali effect in lithium-sodium aluminosilicate glasses
journal, December 1987


Advances in understanding the structure of borosilicate glasses: A Raman spectroscopy study
journal, May 2009

  • Manara, D.; Grandjean, A.; Neuville, D. R.
  • American Mineralogist, Vol. 94, Issue 5-6
  • DOI: 10.2138/am.2009.3027

Compositional and Stability Relationships Among the Lithium Aluminosilicates: Eucryptite, Spodumene, and Petalite
journal, May 1950


23Na NMR chemical shifts and local Na coordination environments in silicate crystals, melts and glasses
journal, October 1993

  • Xue, Xianyu; Stebbins, JonathanF.
  • Physics and Chemistry of Minerals, Vol. 20, Issue 5
  • DOI: 10.1007/BF00215100

Structural characterization of lithium aluminosilicate glass and glass ceramics derived from spodumene mineral
journal, April 1995


Interstitial cristobalite-type compounds (Na2O)≤0.33Na[AlSiO4]
journal, January 1986


Structure of mineral glasses—II. The SiO2NaAlSiO4 join
journal, September 1979


Inhomogeneous distribution of Na+ in alkali silicate glasses
journal, January 2011

  • Tokuda, Yomei; Oka, Takanori; Takahashi, Masahide
  • Journal of the Ceramic Society of Japan, Vol. 119, Issue 1396
  • DOI: 10.2109/jcersj2.119.909

Cristobalite-Related Phases in the NaAlO2–NaAlSiO4 System. I. Two Tetragonal and Two Orthorhombic Structures
journal, October 1998

  • Thompson, J. G.; Withers, R. L.; Melnitchenko, A.
  • Acta Crystallographica Section B Structural Science, Vol. 54, Issue 5
  • DOI: 10.1107/S0108768197019927

Characterization of Li Cations in Zeolite LiX by Solid-State NMR Spectroscopy and Neutron Diffraction
journal, August 1998

  • Feuerstein, M.; Lobo, R. F.
  • Chemistry of Materials, Vol. 10, Issue 8
  • DOI: 10.1021/cm980112d

Structural characterization of pure Na-nephelines synthesized by zeolite conversion route
journal, October 2004

  • Dimitrijevic, Radovan; Dondur, Vera; Vulic, Predrag
  • Journal of Physics and Chemistry of Solids, Vol. 65, Issue 10
  • DOI: 10.1016/j.jpcs.2004.03.005

Examination of the mixed-alkali effect in (Li,Na) disilicate glasses by nuclear magnetic resonance and conductivity measurements
journal, October 1995


Effects of cation field strength on the structure of aluminoborosilicate glasses: High-resolution 11B, 27Al and 23Na MAS NMR
journal, April 2009


Crystallization of iron-containing sodium aluminosilicate glasses in the NaAlSiO 4 -NaFeSiO 4 join : CRYSTALLIZATION NAALSIO
journal, April 2017

  • Ahmadzadeh, Mostafa; Marcial, José; McCloy, John
  • Journal of Geophysical Research: Solid Earth, Vol. 122, Issue 4
  • DOI: 10.1002/2016JB013661

Al,Si order in the crystal structure of α-eucryptite (LiAlSiO 4 )
journal, March 2001


Average and super structure of β eucryptite (LiAlSiO 4 ) Part I. Average structure*
journal, July 1972


Local cation environments in mixed alkali silicate glasses studied by multinuclear single and double resonance magic-angle spinning NMR
journal, July 1997


A Reinvestigation of Low-Carnegieite by XRD, NMR, and TEM
journal, May 1993

  • Thompson, John G.; Withers, Ray L.; Whittaker, Andrew K.
  • Journal of Solid State Chemistry, Vol. 104, Issue 1
  • DOI: 10.1006/jssc.1993.1141

Thirty-year quest for structure–nucleation relationships in oxide glasses
journal, October 2015


High-resolution aluminum-27 NMR of aluminosilicates
journal, April 1986

  • Lippmaa, E.; Samoson, A.; Magi, M.
  • Journal of the American Chemical Society, Vol. 108, Issue 8
  • DOI: 10.1021/ja00268a002

Cation Distribution in Mixed-Alkali Silicate Glasses. NMR Studies by 23 Na−{ 7 Li} and 23 Na−{ 6 Li} Spin Echo Double Resonance
journal, January 1996

  • Gee, Becky; Eckert, Hellmut
  • The Journal of Physical Chemistry, Vol. 100, Issue 9
  • DOI: 10.1021/jp9521722

Viscosity Behavior and Mixed Alkali Effect of Alkali Aluminosilicate Glass Melts
journal, January 1997

  • Kim, Ki-Dong; Lee, Seung-Heun
  • Journal of the Ceramic Society of Japan, Vol. 105, Issue 1226
  • DOI: 10.2109/jcersj.105.827

Crystal structure of hexagonal trinepheline; a new synthetic NaAlSiO 4 modification
journal, June 1998


Properties and structure of (1−x)Li2O–xNa2O–Al2O3–4SiO2 glass systems
journal, July 2007


The Crystal Chemistry of Nepheline
journal, February 2003


6Li nuclear magnetic resonance chemical shifts, coordination number and relaxation in crystalline and glassy silicates
journal, October 1995


An XRD and Electron Diffraction Study of Cristobalite-Related Phases in the NaAlO2–NaAlSiO4System
journal, June 1997

  • Thompson, John G.; Melnitchenko, Alexandra; Palethorpe, Stephen R.
  • Journal of Solid State Chemistry, Vol. 131, Issue 1
  • DOI: 10.1006/jssc.1997.7295

Structural Origin of the Thermal and Diffusion Behaviors of Lithium Aluminosilicate Crystal Polymorphs and Glasses
journal, May 2016

  • Ren, Mengguo; Du, Jincheng
  • Journal of the American Ceramic Society, Vol. 99, Issue 8
  • DOI: 10.1111/jace.14292

The thermal transformation of Na LiA zeolites. A new polymorph in the system Li2OAl2O3SiO2
journal, June 1986


Electron microscopy of Li 2 O–Al 2 O 3 –SiO 2 glass ceramics
journal, September 1982


A theoretical study of structural factors correlated with 23 Na NMR parameters
journal, August 2004

  • Liu, Yun; Tossell, John; Nekvasil, Hanna
  • American Mineralogist, Vol. 89, Issue 8-9
  • DOI: 10.2138/am-2004-8-920

Nepheline gradient solid solutions
journal, May 1995

  • Ota, Toshitaka; Yamai, Iwao; Hayashi, Takashi
  • Journal of Materials Science, Vol. 30, Issue 10
  • DOI: 10.1007/BF00362155

Temperature-induced amorphization of Na-zeolite A: A view from multi-nuclear high-resolution solid-state NMR
journal, October 2014


Percolation channels: a universal idea to describe the atomic structure and dynamics of glasses and melts
journal, November 2017


Effect of the substitution of boron for aluminium in the β-eucryptite LiAlSiO4 structure
journal, January 1994


Melt structure in the system nepheline-diopside
journal, January 1990

  • Sykes, Dan; Scarfe, Christopher M.
  • Journal of Geophysical Research, Vol. 95, Issue B10
  • DOI: 10.1029/JB095iB10p15745

The crystallisation of glasses based on the eutectic compositions in the system Li2O-Al2O3-SiO2: Part 2 Lithium metasilicate-?-eucryptite
journal, February 1970

  • Barry, T. I.; Clinton, D.; Lay, L. A.
  • Journal of Materials Science, Vol. 5, Issue 2
  • DOI: 10.1007/BF00554629

Structural Characterisation of Kaolinite:NaCl Intercalate and its Derivatives
journal, January 1992


Modulation wave approach to the structural parameterization and Rietveld refinement of low carnegieite
journal, August 1993

  • Withers, R. L.; Thompson, J. G.
  • Acta Crystallographica Section B Structural Science, Vol. 49, Issue 4
  • DOI: 10.1107/S010876819300134X

Thermochemistry of Charge-Coupled Substitutions in Silicate Glasses: The Systems M l/n n+ AlO 2 -SiO 2 (M = Li, Na, K, Rb, Cs, Mg, Ca, Sr, Ba, Pb)
journal, September 1984


Li+ ion mobility in eucryptite phases
journal, November 1988

  • Donduft, Vera; Dimitrijević, Radovan; Petranović, Nadežda
  • Journal of Materials Science, Vol. 23, Issue 11
  • DOI: 10.1007/BF01106839

The nepheline-kalsilite system; Part I, X-ray data for the crystalline phases
journal, April 1957


283. The hydrothermal chemistry of silicates. Part I. Synthetic lithium aluminosilicates
journal, January 1951

  • Barrer, R. M.; White, E. A. D.
  • Journal of the Chemical Society (Resumed)
  • DOI: 10.1039/jr9510001267

A neutron diffraction and Rietveld analysis of cooperative Li motion in beta-eucryptite
journal, July 2004

  • Sartbaeva, Asel; Redfern, Simon A. T.; Lee, William T.
  • Journal of Physics: Condensed Matter, Vol. 16, Issue 29
  • DOI: 10.1088/0953-8984/16/29/018

Molecular dynamics simulations of liquids and glasses in the system NaAlSiO 4 -SiO 2 ; methodology and melt structures
journal, June 1995


The distribution of sodium ions in aluminosilicate glasses: a high-field Na-23 MAS and 3Q MAS NMR study
journal, May 2003


29 Si and 27 Al MAS-NMR spectroscopy of β-eucryptite (LiAlSiO 4 ): The enthalpy of Si,Al ordering
journal, January 2000

  • Phillips, Brian L.; Xu, Hongwu; Heaney, Peter J.
  • American Mineralogist, Vol. 85, Issue 1
  • DOI: 10.2138/am-2000-0117

Al–O–Al and Si–O–Si sites in framework aluminosilicate glasses with Si/Al=1: quantification of framework disorder
journal, May 2000


Understanding the structural origin of crystalline phase transformations in nepheline (NaAlSiO 4 )‐based glass‐ceramics
journal, April 2017

  • Deshkar, Ambar; Marcial, José; Southern, Scott A.
  • Journal of the American Ceramic Society, Vol. 100, Issue 7
  • DOI: 10.1111/jace.14845