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Title: Photoionization studies of benzene-argon complexes with synchrotron VUV radiation

Abstract

Penning ionization of benzene-argon complexes of states corresponding to the two states of (3p)5(4s)1 of argon for which j = 1, at 11.8282 and 11.6237 eV, was studied using synchrotron radiation. Photoion yield curves for complex ions, (C6H6)nArm+, where n = 1, 2 and m = 1–3, for species less than m/e 200 were determined. For n = 1, the peaks are narrow (0.03 eV) and red-shifted (0.06 eV) by essentially the same amounts for all values of m. For n = 2, the peaks are wider (0.22 eV) and blue-shifted (0.07 eV) also for all values of m. In addition, the dissociation energies of C6H6Ar and C6H6Ar+ were measured to be 0.89 ± 0.07 and 1.37 ± 0.08 kcal mol–1 (i.e., 0.039 ± 0.003 and 0.059 ± 0.0035 eV).

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3]
+ Show Author Affiliations
  1. National Synchrotron Radiation Research Center, Hsinchu (Taiwan)
  2. Univ. of New Mexico, Albuquerque, NM (United States)
  3. Brookhaven National Lab. (BNL), Upton, NY (United States)
Publication Date:
Research Org.:
Brookhaven National Lab. (BNL), Upton, NY (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; Ministry of Science and Technology of Taiwan
OSTI Identifier:
1614697
Report Number(s):
BNL-213830-2020-JAAM
Journal ID: ISSN 2158-3226; TRN: US2104966
Grant/Contract Number:  
AC02-76CH00016; SC0012704; 108-2113-M-213-003
Resource Type:
Accepted Manuscript
Journal Name:
AIP Advances
Additional Journal Information:
Journal Volume: 9; Journal Issue: 12; Journal ID: ISSN 2158-3226
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; penning ionization; synchrotron radiation; atomic and molecular clusters; heterocyclic compounds; Rydberg states; dissociation energy; photoionization

Citation Formats

Cheng, Bing-Ming, Walters, Edward A., and Grover, J. Robb. Photoionization studies of benzene-argon complexes with synchrotron VUV radiation. United States: N. p., 2019. Web. doi:10.1063/1.5127120.
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Cheng, Bing-Ming, Walters, Edward A., & Grover, J. Robb. Photoionization studies of benzene-argon complexes with synchrotron VUV radiation. United States. https://doi.org/10.1063/1.5127120
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Cheng, Bing-Ming, Walters, Edward A., and Grover, J. Robb. Tue . "Photoionization studies of benzene-argon complexes with synchrotron VUV radiation". United States. https://doi.org/10.1063/1.5127120. https://www.osti.gov/servlets/purl/1614697.
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@article{osti_1614697,
title = {Photoionization studies of benzene-argon complexes with synchrotron VUV radiation},
author = {Cheng, Bing-Ming and Walters, Edward A. and Grover, J. Robb},
abstractNote = {Penning ionization of benzene-argon complexes of states corresponding to the two states of (3p)5(4s)1 of argon for which j = 1, at 11.8282 and 11.6237 eV, was studied using synchrotron radiation. Photoion yield curves for complex ions, (C6H6)nArm+, where n = 1, 2 and m = 1–3, for species less than m/e 200 were determined. For n = 1, the peaks are narrow (0.03 eV) and red-shifted (0.06 eV) by essentially the same amounts for all values of m. For n = 2, the peaks are wider (0.22 eV) and blue-shifted (0.07 eV) also for all values of m. In addition, the dissociation energies of C6H6Ar and C6H6Ar+ were measured to be 0.89 ± 0.07 and 1.37 ± 0.08 kcal mol–1 (i.e., 0.039 ± 0.003 and 0.059 ± 0.0035 eV).},
doi = {10.1063/1.5127120},
journal = {AIP Advances},
number = 12,
volume = 9,
place = {United States},
year = {Tue Dec 03 00:00:00 EST 2019},
month = {Tue Dec 03 00:00:00 EST 2019}
}
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https://doi.org/10.1063/1.5127120
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