Mineral carbonate dissolution with increasing CO2 pressure measured by underwater laser induced breakdown spectroscopy and its application in carbon sequestration
Abstract
In this study, the ability of laser-induced breakdown spectroscopy (LIBS) to measure the in situ aqueous dissolution of various mineral carbonates with increasing CO2 pressure was examined. Dissolution experiments included four geologically common mineral carbonates (CaCO3, MgCO3, MnCO3, SrCO3) and the CO2 pressure ranged from ambient to 250 bar. The ensuing plasma emission was spectrally analyzed, and the intensities of Ca, Mg, Mn, and Sr emission lines were used to monitor the respective metal cations released to the aqueous solution. The strong emission lines of Ca (Ca II 393.36, Ca II 396.84, Ca I 422.67 nm), Mg (unresolved magnesium doublet: Mg I 383.230, Mg I 383.829 nm), Mn (unresolved manganese triplet: Mn I 403.076, Mn I 403.307, Mn I 403.449 nm), and Sr (Sr II 407.77, Sr II 421.55, Sr I 460.73 nm) were identified in the spectra. The amounts of metals released from their respective carbonates were estimated at different time intervals following the CO2 injection (5 m, 1, 2, 3, 4, 24 h) and at different pressures (50, 100, 150, 200, 250 bar) using calibration models developed at corresponding pressure settings. The results demonstrated that the pressure-induced dissolution of all carbonates was consistent with their expected and selectivemore »
- Authors:
-
- National Energy Technology Lab. (NETL), Morgantown, WV (United States)
- National Energy Technology Lab. (NETL), Pittsburgh, PA (United States)
- Publication Date:
- Research Org.:
- National Energy Technology Laboratory (NETL), Pittsburgh, PA, Morgantown, WV, and Albany, OR (United States)
- Sponsoring Org.:
- USDOE Office of Fossil Energy (FE)
- OSTI Identifier:
- 1607759
- Alternate Identifier(s):
- OSTI ID: 1691978
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Talanta
- Additional Journal Information:
- Journal Volume: 205; Journal Issue: C; Journal ID: ISSN 0039-9140
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 58 GEOSCIENCES
Citation Formats
Bhatt, Chet R., Jain, Jinesh C., Edenborn, Harry M., and McIntyre, Dustin L. Mineral carbonate dissolution with increasing CO2 pressure measured by underwater laser induced breakdown spectroscopy and its application in carbon sequestration. United States: N. p., 2019.
Web. doi:10.1016/j.talanta.2019.120170.
Bhatt, Chet R., Jain, Jinesh C., Edenborn, Harry M., & McIntyre, Dustin L. Mineral carbonate dissolution with increasing CO2 pressure measured by underwater laser induced breakdown spectroscopy and its application in carbon sequestration. United States. https://doi.org/10.1016/j.talanta.2019.120170
Bhatt, Chet R., Jain, Jinesh C., Edenborn, Harry M., and McIntyre, Dustin L. Mon .
"Mineral carbonate dissolution with increasing CO2 pressure measured by underwater laser induced breakdown spectroscopy and its application in carbon sequestration". United States. https://doi.org/10.1016/j.talanta.2019.120170. https://www.osti.gov/servlets/purl/1607759.
@article{osti_1607759,
title = {Mineral carbonate dissolution with increasing CO2 pressure measured by underwater laser induced breakdown spectroscopy and its application in carbon sequestration},
author = {Bhatt, Chet R. and Jain, Jinesh C. and Edenborn, Harry M. and McIntyre, Dustin L.},
abstractNote = {In this study, the ability of laser-induced breakdown spectroscopy (LIBS) to measure the in situ aqueous dissolution of various mineral carbonates with increasing CO2 pressure was examined. Dissolution experiments included four geologically common mineral carbonates (CaCO3, MgCO3, MnCO3, SrCO3) and the CO2 pressure ranged from ambient to 250 bar. The ensuing plasma emission was spectrally analyzed, and the intensities of Ca, Mg, Mn, and Sr emission lines were used to monitor the respective metal cations released to the aqueous solution. The strong emission lines of Ca (Ca II 393.36, Ca II 396.84, Ca I 422.67 nm), Mg (unresolved magnesium doublet: Mg I 383.230, Mg I 383.829 nm), Mn (unresolved manganese triplet: Mn I 403.076, Mn I 403.307, Mn I 403.449 nm), and Sr (Sr II 407.77, Sr II 421.55, Sr I 460.73 nm) were identified in the spectra. The amounts of metals released from their respective carbonates were estimated at different time intervals following the CO2 injection (5 m, 1, 2, 3, 4, 24 h) and at different pressures (50, 100, 150, 200, 250 bar) using calibration models developed at corresponding pressure settings. The results demonstrated that the pressure-induced dissolution of all carbonates was consistent with their expected and selective pH-dependent solubility. The dissolution rate of CaCO3, MgCO3, and SrCO3 was found to be higher than that of MnCO3. The dissolution of constituents in a Mt. Simon sandstone associated with a deep saline reservoir at elevated CO2 pressure was also studied and Ca release was quantified. The results demonstrated that real-time monitoring of carbonate dissolution by LIBS may provide a useful indirect detection system indicative of CO2 leakage from geologic carbon storage sites.},
doi = {10.1016/j.talanta.2019.120170},
journal = {Talanta},
number = C,
volume = 205,
place = {United States},
year = {Mon Jul 22 00:00:00 EDT 2019},
month = {Mon Jul 22 00:00:00 EDT 2019}
}
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Figures / Tables:
Figure 1: Aqueous stability of metal carbonates over the pH range 5 – 8, using Visual MINTEQ ver. 3.1
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Works referenced in this record:
Geologic storage of carbon dioxide as a climate change mitigation strategy: performance requirements and the implications of surface seepage
journal, November 2004
- Hepple, R. P.; Benson, S. M.
- Environmental Geology, Vol. 47, Issue 4
S TORAGE OF F OSSIL F UEL -D ERIVED C ARBON D IOXIDE B ENEATH THE S URFACE OF THE E ARTH
journal, November 2001
- Holloway, Sam
- Annual Review of Energy and the Environment, Vol. 26, Issue 1
Mineralogical Alterations During Laboratory-scale Carbon Sequestration Experiments for the Illinois Basin
journal, January 2013
- Yoksoulian, L. E.; Freiburg, J. T.; Butler, S. K.
- Energy Procedia, Vol. 37
Surface Chemistry and Dissolution Kinetics of Divalent Metal Carbonates
journal, February 2002
- Pokrovsky, O. S.; Schott, J.
- Environmental Science & Technology, Vol. 36, Issue 3
Laser-induced breakdown spectroscopy (LIBS): an overview of recent progress and future potential for biomedical applications
journal, January 2012
- Rehse, S. J.; Salimnia, H.; Miziolek, A. W.
- Journal of Medical Engineering & Technology, Vol. 36, Issue 2
Prospects for laser-induced breakdown spectroscopy for biomedical applications: a review
journal, April 2011
- Singh, Vivek Kumar; Rai, Awadhesh Kumar
- Lasers in Medical Science, Vol. 26, Issue 5
Laser-induced breakdown spectroscopy (LIBS) for food analysis: A review
journal, July 2017
- Markiewicz-Keszycka, Maria; Cama-Moncunill, Xavier; Casado-Gavalda, Maria P.
- Trends in Food Science & Technology, Vol. 65
Identification of meat species by using laser-induced breakdown spectroscopy
journal, September 2016
- Bilge, Gonca; Velioglu, Hasan Murat; Sezer, Banu
- Meat Science, Vol. 119
Feasibility of laser-induced breakdown spectroscopy (LIBS) as an at-line validation tool for calcium determination in infant formula
journal, August 2017
- Cama-Moncunill, Xavier; Markiewicz-Keszycka, Maria; Dixit, Yash
- Food Control, Vol. 78
Laser-induced breakdown spectroscopy for space exploration applications: Influence of the ambient pressure on the calibration curves prepared from soil and clay samples
journal, April 2005
- Sallé, Béatrice; Cremers, David A.; Maurice, Sylvestre
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 60, Issue 4
Characterization of Laser-Induced Breakdown Spectroscopy (LIBS) for Application to Space Exploration
journal, March 2000
- Knight, Andrew K.; Scherbarth, Nancy L.; Cremers, David A.
- Applied Spectroscopy, Vol. 54, Issue 3
Laser-Induced Breakdown Spectroscopy of High-Pressure Bulk Aqueous Solutions
journal, July 2006
- Lawrence-Snyder, Marion; Scaffidi, Jon; Angel, S. Michael
- Applied Spectroscopy, Vol. 60, Issue 7
Underwater measurements using laser induced breakdown spectroscopy
journal, January 2016
- Angel, S. Michael; Bonvallet, Joseph; Lawrence-Snyder, Marion
- Journal of Analytical Atomic Spectrometry, Vol. 31, Issue 1
Investigating the CO2 pressure effect on underwater laser-induced plasma emission of Eu and Yb
journal, November 2018
- Bhatt, Chet R.; Jain, Jinesh C.; McIntyre, Dustin L.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 149
Quantification of dissolved metals in high-pressure CO2-water solutions by underwater laser-induced breakdown spectroscopy
journal, December 2018
- Goueguel, Christian L.; Bhatt, Chet R.; Jain, Jinesh C.
- Optics & Laser Technology, Vol. 108
High resolution applications of laser-induced breakdown spectroscopy for environmental and forensic applications
journal, December 2007
- Martin, Madhavi Z.; Labbé, Nicole; André, Nicolas
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 62, Issue 12
Geological Applications of Laser-Induced Breakdown Spectroscopy
journal, August 2014
- McMillan, Nancy J.; Rees, Shannon; Kochelek, Kristen
- Geostandards and Geoanalytical Research, Vol. 38, Issue 3
Determination of Rare Earth Elements in Geological Samples Using Laser-Induced Breakdown Spectroscopy (LIBS)
journal, October 2017
- Bhatt, Chet R.; Jain, Jinesh C.; Goueguel, Christian L.
- Applied Spectroscopy, Vol. 72, Issue 1
Univariate and multivariate analyses of rare earth elements by laser-induced breakdown spectroscopy
journal, January 2017
- Bhatt, Chet R.; Yueh, Fang Y.; Singh, Jagdish P.
- Applied Optics, Vol. 56, Issue 8
Laser-induced breakdown spectroscopy (LIBS) – an emerging field-portable sensor technology for real-time, in-situ geochemical and environmental analysis
journal, February 2005
- Harmon, Russell. S.; De Lucia, Frank C.; Miziolek, Andrzej W.
- Geochemistry: Exploration, Environment, Analysis, Vol. 5, Issue 1
Detection of Metals in the Environment Using a Portable Laser-Induced Breakdown Spectroscopy Instrument
journal, February 1996
- Yamamoto, Karen Y.; Cremers, David A.; Ferris, Monty J.
- Applied Spectroscopy, Vol. 50, Issue 2, p. 222-233
Ultraviolet laser filaments for remote laser-induced breakdown spectroscopy (LIBS) analysis: applications in cultural heritage monitoring
journal, January 2006
- Tzortzakis, Stelios; Anglos, Demetrios; Gray, David
- Optics Letters, Vol. 31, Issue 8
Analysis of charcoal blast furnace slags by laser-induced breakdown spectroscopy
journal, January 2017
- Bhatt, Chet R.; Goueguel, Christian L.; Jain, Jinesh C.
- Applied Optics, Vol. 56, Issue 28
Laser-Induced Breakdown Spectroscopy (LIBS) of a High-Pressure CO 2 –Water Mixture: Application to Carbon Sequestration
journal, September 2014
- Goueguel, Christian; McIntyre, Dustin L.; Singh, Jagdish P.
- Applied Spectroscopy, Vol. 68, Issue 9
Detection of carbon content in a high-temperature and high-pressure environment using laser-induced breakdown spectroscopy
journal, April 2002
- Noda, M.; Deguchi, Y.; Iwasaki, S.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 57, Issue 4
Laser-induced breakdown spectroscopy of bulk aqueous solutions at oceanic pressures: evaluation of key measurement parameters
journal, January 2007
- Michel, Anna P. M.; Lawrence-Snyder, Marion; Angel, S. Michael
- Applied Optics, Vol. 46, Issue 13
Laser induced breakdown spectroscopy inside liquids: Processes and analytical aspects
journal, November 2014
- Lazic, V.; Jovićević, S.
- Spectrochimica Acta Part B: Atomic Spectroscopy, Vol. 101
In situ measurements of calcium carbonate dissolution under rising CO 2 pressure using underwater laser-induced breakdown spectroscopy
journal, January 2016
- Goueguel, Christian L.; Jain, Jinesh C.; McIntyre, Dustin L.
- Journal of Analytical Atomic Spectrometry, Vol. 31, Issue 7
Influence of CO_2 pressure on the emission spectra and plasma parameters in underwater laser-induced breakdown spectroscopy
journal, January 2016
- Goueguel, Christian L.; McIntyre, Dustin L.; Jain, Jinesh C.
- Optics Letters, Vol. 41, Issue 23
Double pulse laser-induced breakdown spectroscopy of bulk aqueous solutions at oceanic pressures: interrelationship of gate delay, pulse energies, interpulse delay, and pressure
journal, January 2008
- Michel, Anna P. M.; Chave, Alan D.
- Applied Optics, Vol. 47, Issue 31
Study of pressure effects on laser induced plasma in bulk seawater
journal, January 2014
- Hou, Huaming; Tian, Ye; Li, Ying
- J. Anal. At. Spectrom., Vol. 29, Issue 1
Quantification of Brittle Deformation in Burial Compaction, Frio and Mount Simon Formation Sandstones
journal, November 2003
- Makowitz, A.; Milliken, K. L.
- Journal of Sedimentary Research, Vol. 73, Issue 6
Management and dewatering of brines extracted from geologic carbon storage sites
journal, August 2017
- Arena, Jason T.; Jain, Jinesh C.; Lopano, Christina L.
- International Journal of Greenhouse Gas Control, Vol. 63
Works referencing / citing this record:
Modeling of CO 2 storage as hydrate in vacated natural gas hydrate formation
journal, September 2019
- Ahmad, Sheraz; Li, Yiming; Li, Xiangfang
- International Journal of Energy Research, Vol. 44, Issue 1
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