High-pressure compressibility and vibrational properties of (Ca,Mn)CO3

Liu, Jin; Caracas, Razvan; Fan, Dawei; Bobocioiu, Ema; Zhang, Dongzhou; Mao, Wendy L.

doi:10.2138/am-2016-5742

Title: High-pressure compressibility and vibrational properties of (Ca,Mn)CO₃

Abstract

Knowledge of potential carbon carriers such as carbonates is critical for our understanding of the deep-carbon cycle and related geological processes within the planet. Here we investigated the high-pressure behavior of (Ca,Mn)CO₃ up to 75 GPa by synchrotron single-crystal X-ray diffraction, laser Raman spectroscopy, and theoretical calculations. MnCO₃-rich carbonate underwent a structural phase transition from the CaCO₃-I structure into the CaCO₃-VI structure at 45–48 GPa, while CaCO₃-rich carbonate transformed into CaCO₃-III and CaCO₃-VI at approximately 2 and 15 GPa, respectively. The equation of state and vibrational properties of MnCO₃-rich and CaCO₃-rich carbonates changed dramatically across the phase transition. The CaCO₃-VI-structured CaCO₃-rich and MnCO₃-rich carbonates were stable at room temperature up to at least 53 and 75 GPa, respectively. In conclusion, the addition of smaller cations (e.g., Mn²⁺, Mg²⁺, and Fe²⁺) can enlarge the stability field of the CaCO₃-I phase as well as increase the pressure of the structural transition into the CaCO₃-VI phase.

Authors:

Liu, Jin ^[1]; Caracas, Razvan ^[2]; Fan, Dawei ^[3]; Bobocioiu, Ema ^[2]; Zhang, Dongzhou ^[4]; Mao, Wendy L. ^[5]

Stanford Univ., Stanford, CA (United States)
Univ. Claude Bernard Lyon 1, Lyon Cedex (France)
Chinese Academy of Sciences, Guizhou (China)
Univ. of Hawai'i at Manoa, Honolulu, HI (United States)
Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)

Publication Date:: Thu Dec 01 00:00:00 EST 2016

Research Org.:: SLAC National Accelerator Lab., Menlo Park, CA (United States)

Sponsoring Org.:: USDOE

OSTI Identifier:: 1360964

Grant/Contract Number:: AC02-76SF00515

Resource Type:: Accepted Manuscript

Journal Name:: American Mineralogist

Additional Journal Information:: Journal Volume: 101; Journal Issue: 12; Journal ID: ISSN 0003-004X

Publisher:: Mineralogical Society of America

Country of Publication:: United States

Language:: English

Subject:: 58 GEOSCIENCES; carbonate; X-ray diffraction; raman spectroscopy; high pressure

Citation Formats


                    Liu, Jin, Caracas, Razvan, Fan, Dawei, Bobocioiu, Ema, Zhang, Dongzhou, and Mao, Wendy L. High-pressure compressibility and vibrational properties of (Ca,Mn)CO3.  United States: N. p., 2016. 
Web.  doi:10.2138/am-2016-5742.

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                    Liu, Jin, Caracas, Razvan, Fan, Dawei, Bobocioiu, Ema, Zhang, Dongzhou, & Mao, Wendy L. High-pressure compressibility and vibrational properties of (Ca,Mn)CO3.  United States.  https://doi.org/10.2138/am-2016-5742

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                    Liu, Jin, Caracas, Razvan, Fan, Dawei, Bobocioiu, Ema, Zhang, Dongzhou, and Mao, Wendy L. Thu .  
"High-pressure compressibility and vibrational properties of (Ca,Mn)CO3".  United States.  https://doi.org/10.2138/am-2016-5742.  https://www.osti.gov/servlets/purl/1360964.

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@article{osti_1360964,

  title        = {High-pressure compressibility and vibrational properties of (Ca,Mn)CO3},

  author       = {Liu, Jin and Caracas, Razvan and Fan, Dawei and Bobocioiu, Ema and Zhang, Dongzhou and Mao, Wendy L.},

  abstractNote = {Knowledge of potential carbon carriers such as carbonates is critical for our understanding of the deep-carbon cycle and related geological processes within the planet. Here we investigated the high-pressure behavior of (Ca,Mn)CO3 up to 75 GPa by synchrotron single-crystal X-ray diffraction, laser Raman spectroscopy, and theoretical calculations. MnCO3-rich carbonate underwent a structural phase transition from the CaCO3-I structure into the CaCO3-VI structure at 45–48 GPa, while CaCO3-rich carbonate transformed into CaCO3-III and CaCO3-VI at approximately 2 and 15 GPa, respectively. The equation of state and vibrational properties of MnCO3-rich and CaCO3-rich carbonates changed dramatically across the phase transition. The CaCO3-VI-structured CaCO3-rich and MnCO3-rich carbonates were stable at room temperature up to at least 53 and 75 GPa, respectively. In conclusion, the addition of smaller cations (e.g., Mn2+, Mg2+, and Fe2+) can enlarge the stability field of the CaCO3-I phase as well as increase the pressure of the structural transition into the CaCO3-VI phase.},

  doi          = {10.2138/am-2016-5742},

  journal      = {American Mineralogist},

  number       = 12,

  volume       = 101,

  place        = {United States},

  year         = {Thu Dec 01 00:00:00 EST 2016},

  month        = {Thu Dec 01 00:00:00 EST 2016}

}

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https://doi.org/10.2138/am-2016-5742

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Cited by: 24 works

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Figures / Tables:

FIGURE 1: The pressure-volume relations of MnCO₃-I and MnCO₃-II. Insert: X‑ray diffraction images collected during a rotation of 30° at 32, 47, and 67 GPa, respectively, showing the sharp diffraction peaks of MnCO3 at high pressures. The diffraction rings in the XRD patterns come from the pressure medium Ne whilemore »

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Works referencing / citing this record:

Temperature-induced amorphization in CaCO3 at high pressure and implications for recycled CaCO3 in subduction zones
journal, April 2019

Hou, Mingqiang; Zhang, Qian; Tao, Renbiao
Nature Communications, Vol. 10, Issue 1
DOI: 10.1038/s41467-019-09742-5

Phase Transition and vibration properties of MnCO ₃ at high pressure and high-temperature by Raman spectroscopy
journal, May 2018

Zhao, Chaoshuai; Li, Heping; Jiang, Jianjun
High Pressure Research, Vol. 38, Issue 3
DOI: 10.1080/08957959.2018.1476505

Phase Transition and vibration properties of MnCO₃ at high pressure and high-temperature by Raman spectroscopy
text, January 2018

Zhao, Chaoshuai; Li, Heping; Jiang, Jianjun
Taylor & Francis
DOI: 10.6084/m9.figshare.6290912

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Title: High-pressure compressibility and vibrational properties of (Ca,Mn)CO3

Abstract

Citation Formats

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Temperature-induced amorphization in CaCO3 at high pressure and implications for recycled CaCO3 in subduction zones journal, April 2019

Phase Transition and vibration properties of MnCO 3 at high pressure and high-temperature by Raman spectroscopy journal, May 2018

Phase Transition and vibration properties of MnCO3 at high pressure and high-temperature by Raman spectroscopy text, January 2018

Title: High-pressure compressibility and vibrational properties of (Ca,Mn)CO₃

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journal, April 2019

Phase Transition and vibration properties of MnCO ₃ at high pressure and high-temperature by Raman spectroscopy
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